• Title/Summary/Keyword: polymer pattern

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A model for the restrained shrinkage behavior of concrete bridge deck slabs reinforced with FRP bars

  • Ghatefar, Amir;ElSalakawy, Ehab;Bassuoni, Mohamed T.
    • Computers and Concrete
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    • v.20 no.2
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    • pp.215-227
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    • 2017
  • A finite element model (FEM) for predicting early-age behavior of reinforced concrete (RC) bridge deck slabs with fiber-reinforced polymer (FRP) bars is presented. In this model, the shrinkage profile of concrete accounted for the effect of surrounding conditions including air flow. The results of the model were verified against the experimental test results, published by the authors. The model was verified for cracking pattern, crack width and spacing, and reinforcement strains in the vicinity of the crack using different types and ratios of longitudinal reinforcement. The FEM was able to predict the experimental results within 6 to 10% error. The verified model was utilized to conduct a parametric study investigating the effect of four key parameters including reinforcement spacing, concrete cover, FRP bar type, and concrete compressive strength on the behavior of FRP-RC bridge deck slabs subjected to restrained shrinkage at early-age. It is concluded that a reinforcement ratio of 0.45% carbon FRP (CFRP) can control the early-age crack width and reinforcement strain in CFRP-RC members subjected to restrained shrinkage. Also, the results indicate that changing the bond-slippage characteristics (sand-coated and ribbed bars) or concrete cover had an insignificant effect on the early-age crack behavior of FRP-RC bridge deck slabs subjected to shrinkage. However, reducing bar spacing and concrete strength resulted in a decrease in crack width and reinforcement strain.

Organic Compounds Vapor Detection Properties of MWCNT/PMMA Composite Film Detector (CNT/PMMA 복합막 검출기의 유기화합물 증기의 검출 특성)

  • Lim, Young Taek;Shin, Paik-Kyun;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.11
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    • pp.727-730
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    • 2015
  • In this paper, we fabricated organic compounds detector using the MWCNT/PMMA (multi-walled carbon nanotube / polymethylmethacrylate) composite film. We used polymer film as a matrix material for the device framework, and introduced CNTs for reacting with the organic compounds resulting in changing electrical conductivity. Spray coating method was used to form the MWCNT/PMMA composite film detector, and pattern formation of the detector was done by shadow mask during the spray coating process. We investigated changes of electrical conductivity of the detector before and after the organic compounds exposure. Electrical conductivity of the detector tended to decrease after the exposure with various organic compounds such as acetone, tetrahydrofuran (THF), toluene, and dimethylformamide (DMF). Finally we conclude that organic compounds detection by the MWCNT/PMMA composite film detector was possible, and expect the feasibility of commercial MWCNT/PMMA composite film detector for various organic compounds.

A Study on the Filling Imbalance in a Geometrically Balanced Injection Mold (기하학적 균형을 갖춘 금형에서 발생하는 성형품의 충전 불균형에 관한 연구)

  • 구양;김병탁;정영득;한성렬;한규택
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.6
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    • pp.931-937
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    • 2004
  • Simultaneous filling is a goal in plastic injection mold that has multi cavities. The moldings which have not been filled at the same time have undesired faults such as dimension inaccuracy, residual stress, law mechanical strength, etc. The best way to simultaneous fill is to be injected in a geometrically balanced runner system. In a general processing, however, in balanced runner system mold, filling imbalance would be observed in cavities. These phenomena result from molten polymer's characteristics and circumstances in balanced runner. In this study, the degree of filling imbalance (DFI) was defined for showing rate of filling imbalance in geometrically balanced injection mold that has 8 cavities. Before the main experiment, an injection molding simulation was conducted to know a pattern of filling imbalance with Moldflow software. There were somewhat differences between results of experiment and simulation about the filling imbalance. The reason for the difference was that the software have not concerned about a situation in a real flow channel. It was also investigated how the injection speed affected on filling imbalance in the experiment.

Conductive Pattern of a Curved Surface Polymer Material by Laser Technique (레이저조사에 의한 굴곡면 폴리머소재의 전도성패턴 기술)

  • Yoon, Shin-Yong;Choi, Geun-Soo;Baek, Soo-Hyun;Kim, Yong;Chang, Hong-Soon
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1045-1046
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    • 2011
  • 본 논문에서는 굴곡면 커버내에 전기회로를 구현시 그 동안 포토리소그라피 공정으로 제작된 PCB를 휴대기 등 내부 케이스에 부착하여 전기회로를 구현하였으나 본 논문에서는 PCB없이 직접 케이스인 복합 폴리머소재에 레이저조사에 의해 패턴과 무전해도금으로 전기회로를 직접구현하는 기술이다. 이러한 방법은 제안한 3단계 공정기법에 의해 가능하며, 즉 사출형 복합폴리머소재제작, 소재의 레이저조사에 의한 시드패턴 구현 및 형성시드의 무전해도금에 의한 전도성패턴구현 공정을 통하여 곡면커버의 전기회로구현이 가능하다. 이에 따라 기존의 복잡한 10 단계 이상의 포토리소그라피 공정을 레이저조사에 의한 3단계 공정으로 간소화함으로서 제품의 생산성향상, 다량장비 구입절감, 작업공간축소 및 기타 소재절감 등의 경제적 효과를 얻을 수 있다. 응용분야는 2차원 평면 전기회로 외에 3차원 곡면형상의 제품인 자동차, 휴대폰, 의료기, 센서, 오토바이 등의 커버에 직접회로 응용이 가능하다. 이에 대한 타당성은 실험결과를 통하여 입증하였다.

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Release of Cytarabine from $Poly({\varepsilon}-carbobenzoxy\;L-lysine)$/Poly(ethylene oxide)/Poly({\varepsilon}-carbobenzoxy\;L-lysine)$ Block Copolymer Microspheres ($Poly({\varepsilon}-carbobenzoxy\;L-lysine)$/Poly(ethylene oxide)/$Poly({\varepsilon}-carbobenzoxy\;L-lysine)$ 블록 공중합체 미립자에서 Cytarabine의 방출특성)

  • Cho, Chong-Su;Kwon, Joong-Kuen;Jo, Byung-Wook;Lee, Kang-Choon;Sung, Yong-Kiel
    • Journal of Pharmaceutical Investigation
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    • v.22 no.4
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    • pp.323-326
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    • 1992
  • $Poly({\varepsilon}-carbobenzoxy\;L-lysine)/poly(ethylene oxide)/poly({\varepsilon}-carbobenzoxy\;L-lysine)$ (LEL) block copolymers containing $poly({\varepsilon}-carbobenzoxy\;L-lysine)$ (PCLL) as the A component and poly(ethylene oxide) (PEO) as the B component were investigated as drug delivery matrix. PCLL homopolymer and LEL block copolymer microspheres containing anticancer drug, cytarabine, were prepared by a solvent evaporation process and the release patterns of cytarabine from the microspheres were investigated in vitro. The size of PCLL homopolymer and LEL block copolymer microspheres was ranged from $0.2\;{\mu}m$ to $1\;{\mu}m$ in diameter and the shape of the microspheres was almost round. The release pattern of cytarabine from the block copolymer microspheres was dependent on the mole % of PEO of the block copolymers.

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Influence of Nanodispersed Organoclay on Rheological and Swelling Properties of Ethylene Propylene Diene Terpolymer

  • Acharya Himadri;Srivastava Suneel K.
    • Macromolecular Research
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    • v.14 no.2
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    • pp.132-139
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    • 2006
  • The dispersion of organoclay in ethylene propylene diene terpolymer (EPDM) matrix was correlated with the rheological and swelling properties of nanocomposites. X-ray diffraction pattern (XRD) and transmission electron microscopic (TEM) analysis exhibited the disordered-intercalated structure of EPDM/organoclay nanocomposite. The extent of the disordered phase increased with increasing organoclay content up to a limiting value of 3 wt% after which equilibrium tended towards intercalation. The dispersion effect of organoclay in EPDM matrix was clarified by the physicochemical properties like rheological response and swelling thermodynamics in toluene. The increase in viscoelastic properties of EPDM nanocomposite with increasing organoclay content up to 3 wt%, followed by a subsequent decrease up to 4 wt%, was correlated in terms of the disordered and ordered states of the dispersed nano-clay sheets. Swelling measurements revealed that the change in entropy of the swelling increased with the increase in disorder level but decreased with the increase in intercalation level of organoclay in the disordered-intercalated nanocomposite. The increase in solvent uptake was comparable with the free volume in EPDM matrix upon inclusion of silicate particles, whereas the inhibition in solvent uptake for higher organoclay loading was described by bridging flocculation.

5-3: [Invited] Roll-to-Roll Manufacturing of Electronics on Flexible Substrates Using Self-Aligned Imprint Lithography (SAIL)

  • Kim, Han-Jun;Almanza-Workman, Marcia;Chaiken, Alison;Elder, Richard;Garcia, Bob;Jackson, Warren;Jeans, Albert;Kwon, Oh-Seung;Luo, Hao;Mei, Ping;Perlov, Craig;Taussig, Carl;Jeffrey, Frank;Beacom, Kelly;Braymen, Steve;Hauschildt, Jason;Larson, Don
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.82-85
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    • 2008
  • We are working towards large-area arrays of thin film transistors on polymer substrates using roll-to-roll (R2R) processes exclusively. Self-aligned imprint lithography (SAIL) is an enabler to pattern and align submicron features on meter-scaled flexible substrates in the R2R environment. The progress, current status and remaining issues of this new fabrication technology are presented.

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High Efficiency AMOLED Using Hybrid of Small Molecule and Polymer Materials Patterned by Laser Transfer

  • Chin, Byung-Doo;Suh, Min-Chul;Kim, Mu-Hyun;Kang, Tae-Min;Yang, Nam-Choul;Song, Myung-Won;Lee, Seong-Taek;Kwon, Jang-Hyuk;Chung, Ho-Kyoon;Wolk, Martin B.;Bellmann, Erika;Baetzold, John P.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.163-166
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    • 2003
  • Laser-Induced Thermal Imaging (LITI) is a laser addressed patterning process and has unique advantages, such as high-resolution patterning with over-all position accuracy of the imaged stripes within 2.5 micrometer and scalability to large-size mother glass. This accuracy is accomplished using real-time error correction and a high -resolution stage control system that includes laser interferometers. Here the new concept of mixed hybrid system which complement the advantages of small molecular and polymeric materials for use as an OLED; our system can realize the easy processing of polymers and high luminance efficiency of recently developed small molecules. LITI process enables to pattern the stripes with excellent thickness uniformity and multi-stacking of various functional layers without using any type of fine metal shadow mask. In this study, we report a full-color hybrid OLED using the multi-layered structure of small molecular/polymeric species.

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Cavitation-Erosion Characteristics between Polymer Based Composites and Metals under the Various Condition of Fluid Systems (유체 환경하에서의 고분자 기지 복합재료와 금속재의 캐비테이션 침식 특성)

  • Kim, Yun-Hae;Son, Young-Jun;Eum, Soo-Hyun;Lee, Jung-Ju
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.3
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    • pp.363-371
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    • 2003
  • This study is mainly concerned with phenomenon of cavitation-erosion on the several materials and corrosive liquids which were applied with vibrator(suggested by ASTM G 32, 20KHz, 50$mu extrm{m}$). The maximum erosion rate by cavitation erosion in both of distilled water and sea water appeared to be proportioned to their hardness and tensile strength. Cavitation weight loss and rate of cast iron in sea water condition were greater(approximately 3 times) than that in distilled water condition, however in case of stainless steel and brass the cavitation weight loss of composite materials were not so different in both of their conditions. Cavitation weight loss of composite materials were shown as below on this test, Duratough DL : Weight loss in sea-water condition were greater (approximately 2.3 times) than it's distilled water condition. The main tendency of cavitation erosion for metals appeared that small damaged holes causing by cavitation erosion was observed with radial pattern. On the other hand, the tendency for composites appeared that small damaged holes were observed randomly.

Acoustic emission monitoring of damage progression in CFRP retrofitted RC beams

  • Nair, Archana;Cai, C.S.;Pan, Fang;Kong, Xuan
    • Structural Monitoring and Maintenance
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    • v.1 no.1
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    • pp.111-130
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    • 2014
  • The increased use of carbon fiber reinforced polymer (CFRP) in retrofitting reinforced concrete (RC) members has led to the need to develop non-destructive techniques that can monitor and characterize the unique damage mechanisms exhibited by such structural systems. This paper presented the damage characterization results of six CFRP retrofitted RC beam specimens tested in the laboratory and monitored using acoustic emission (AE). The focus of this study was to continuously monitor the change in AE parameters and analyze them both qualitatively and quantitatively, when brittle failure modes such as debonding occur in these beams. Although deterioration of structural integrity was traceable and can be quantified by monitoring the AE data, individual failure mode characteristics could not be identified due to the complexity of the system failure modes. In all, AE was an effective non-destructive monitoring tool that can trace the failure progression in RC beams retrofitted with CFRP. It would be advantageous to isolate signals originating from the CFRP and concrete, leading to a more clear understanding of the progression of the brittle damage mechanism involved in such a structural system. For practical applications, future studies should focus on spectral analysis of AE data from broadband sensors and automated pattern recognition tools to classify and better correlate AE parameters to failure modes observed.