• Title/Summary/Keyword: phase transformation

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Dental Co-Cr alloys fabricated by selective laser melting: A review article (선택적 레이저 용융 방법으로 제작한 치과용 코발트 크롬 합금에 대한 문헌고찰)

  • Kang, Hyeon-Goo
    • The Journal of Korean Academy of Prosthodontics
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    • v.59 no.2
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    • pp.248-260
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    • 2021
  • Cobalt-chromium alloys are used to fabricate various dental prostheses, and have advantages of low cost and excellent mechanical properties compared to other alloys. Recently, selective laser melting, which is an additive manufacturing method, has been used to overcome the disadvantages of the conventional fabrication method. A local rapid heating and cooling process of selective laser melting induces fine microstructures, grain refinement, and reduction of porosities of the alloys. Therefore, it can improve mechanical properties compared to the alloys fabricated by the conventional method. On the other hand, layering process and rapid heating and cooling cause accumulation of a large amount of residual stresses that can adversely affect the mechanical properties. A heat treatment for removing residual stresses through recovery and recrystallization process caused complicated changes in mechanical properties induced by phase transformation, precipitate and homogenization of the microstructures. The purpose of this review was to compare the manufacturing methods of Co-Cr alloys and to investigate the characteristics of Co-Cr alloys fabricated by selective laser melting.

Effects of Surface Machining by a Lathe on Microstructure of Near Surface Layer and Corrosion Behavior of SA182 Grade 304 Stainless Steel in Simulated Primary Water

  • Zhang, Zhiming;Wang, Jianqiu;Han, En-hou;Ke, Wei
    • Corrosion Science and Technology
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    • v.18 no.1
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    • pp.1-7
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    • 2019
  • To find proper lathe machining parameters for SA182 Grade 304 stainless steel (SS), six kinds of samples with different machining surface states were prepared using a lathe. Surface morphologies and microstructures of near surface deformed layers on different samples were analysed. Surface morphologies and chemical composition of oxide films formed on different samples in simulated primary water with $100{\mu}g/L\;O_2$ at $310^{\circ}C$ were characterized. Results showed that surface roughness was mainly affected by lathe feed. Surface machining caused grain refinement at the top layer. A severely deformed layer with different thicknesses formed on all samples. In addition to high defect density caused by surface deformation, phase transformation, residual stress, and strain also affected the oxidation behaviour of SA182 Grade 304 SS in the test solution. Machining parameters used for # 4 (feed, 0.15 mm/r; back engagement, 2 mm; cutting speed, 114.86 m/min) and # 6 (feed,0.20 mm/r; back engagement, 1 mm; cutting speed, 73.01 m/min) samples were found to be proper for lathe machining of SA182 Grade 304 SS.

Effect of High-Energy Mechanical Milling Time on Microstructure and Mechanical Properties of the Nano-sized TiAl Intermetallic Compounds Fabricated by Pulse Current Activated Sintering (펄스전류 활성 소결에 의해 제조된 나노크기의 TiAl계 금속간화합물의 미세구조와 기계적 특성에 미치는 고에너지 기계적 밀링시간의 영향)

  • Kim, Ji-Young;Woo, Kee-Do;Kang, Duck-Soo;Kim, Sang-Hyuk;Park, Snag-Hoon;Zhang, Deliang
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.161-166
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    • 2011
  • The aim of this study was to determine the effect of high-energy mechanical milling (HEMM) time and sintering temperature on microstructure and mechanical properties of the TiAl composite fabricated by pulse current activated sintering. TiAl intermetallic powders were milled by HEMM for 1h, 4h, and 8h respectively. Thermal analysis was used to observe the phase transformation of the milled TiAl powders. The sintering time decreased with increase of milling time. The hardness and fracture toughness of the sintered specimens also was improved with increasing milling time. The grain size of the sintered specimens which was milled for 4h was in the range of 50~100 nm.

Adaptive Pressure Sensor with High Sensitivity and Large Bandwidth Based on Gallium Microdroplet-elastomer Composite (갈륨 미세입자 탄성 복합체 기반 고민감도와 광대역폭을 갖는 가변 강성 압력센서)

  • Simok, Lee;Sang-Hyuk, Byun;Steve, Park;Joo Yong, Sim;Jae-Woong, Jeong
    • Journal of Sensor Science and Technology
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    • v.31 no.6
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    • pp.423-427
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    • 2022
  • A pressure sensor that mimics the sensing ability of human skin has emerged as high-profile technology because it shows remarkable applications in numerous fields such as robotics, human health monitoring, and artificial prosthetics. Whereas recent pressure sensors have achieved high sensitivity similar to that of human skin, they still show limited detection bandwidth. Moreover, once these e-skin are fabricated, their sensitivity and stiffness are fixed; therefore, they can be used for only limited applications. Our study proposes a new adaptive pressure sensor built with uniform gallium microdroplet-elastomer composite. Based on the phase transition of gallium microdroplets, the proposed sensor undergoes mode transformation, enabling it to have a higher sensitivity and wider detection bandwidth compared with those of human skin. In addition, we succeeded in extending a single adaptive pressure sensor to sensor arrays based on its high uniformity, reproducibility, and large-scale manufacturability. Finally, we designed an adaptive e-skin with the sensor array and demonstrated its applications on health monitoring tasks including blood pulse and body weight measurements.

Changes in the Structural and Electrical Properties of Ti3C2Tx MXene Depending on Heat Treatment (Ti3C2Tx MXene의 열처리에 따른 구조적, 전기적 특성 변화)

  • Kim, Ja-Hyun;Noh, Jin-Seo
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.264-269
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    • 2022
  • Ti3C2Tx MXene, which is a representative of the two-dimensional MXene family, is attracting considerable attention due to its remarkable physicochemical and mechanical properties. Despite its strengths, however, it is known to be vulnerable to oxidation. Many researchers have investigated the oxidation behaviors of the material, but most researches were conducted at high temperatures above 500 ℃ in an oxidation-retarding environment. In this research, we studied changes in the structural and electrical properties of Ti3C2Tx MXene induced by low-temperature heat treatments in ambient conditions. It was found that a number of TiO2 particles were formed on the MXene surface when it was mildly heated to 200 ℃. Heating the material to higher temperatures, up to 400 ℃, the phase transformation of Ti3C2Tx MXene to TiO2 was accelerated, resulting in a TiO2/Ti3C2Tx hybrid. Consequently, the metallic nature of pure Ti3C2Tx MXene was transformed to semiconductive behavior upon heat-treating at ≥ 200 ℃. The results of this research clearly demonstrate that Ti3C2Tx MXene may be easily oxidized even at low temperatures once it is exposed to air.

A study on the zinc oxide crystalline powder synthesized by zinc chloride solution and sodium-based alkali precipitants (염화아연 수용액과 나트륨계 알칼리 침전제 종류에 따라 합성한 산화아연 결정 분말에 대한 연구)

  • Dae-Weon Kim;Dae-Hwan Jang;Bo-Ram Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.15-21
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    • 2023
  • To prepare zinc oxide powder, three types of sodium-based alkali precipitants such as NaOH, Na2CO3, NaOH/NaHCO3 were compared to the differences in the manufacturing process of zinc oxide powder from zinc precipitate products like intermediates with the consideration of thermodynamic reaction. The prepared zinc precipitate products by the reaction with the sodium-based alkali precipitant were confirmed to respectively hydroxy zinc chloride (Zn5(OH)8Cl2·H2O) and zinc carbonate hydroxide (Zn5(OH)6(CO3)2·H2O) from XRD analysis. Zinc oxide particles were compared in heat treatment at 800℃ according to sodium-based alkali precipitants. The mixed NaOH and NaHCO3 of alkali precipitant reaction was contributed to synthesize the more uniform zinc oxide particles.

Development of Diagnosis System of Mold Oscillation in a Continuous Slab Casting Machine (연속 주조기의 주형 진동 진단 시스템의 개발)

  • Choi, Jae-Chan;Lee, Sung-Jin;Cho, Kang-Hyeong;Jun, Hyeong-Il
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.5
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    • pp.84-94
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    • 1996
  • In order to prevent shell sticking by providing sufficient lubrication between the strand and the mold, the mold oscillation has been used. Now it is well known that the shape of the oscillation curve has a decisive effect on the surface quality of the cast product. Besides, oscillation parameters such as stroke and frequency are also very important. In order to guarantee that parameters which have been found to be optimal for a certain grade of steel do not change with time, periodical checks of the physical condition of the whole equipment are necessary. The portable mold oscillation analyzer with integrated computer, developed by POSCO, records the movement of the mold in every spatial direction. The system uses the gap sensors to measure the mold movement (displacement ) in the two horizontal directions according to the mold narrow and broad faces and the vertical strokes in the four corners of mold. The gap sensor is a non-contacting minute displacement measuring device using the principle of high frequency eddy current loss. The mold oscillation diagnosis system integrates the gap sensors, their converters and the industrial portable computer with plug-in data acquisition boards. The all programs, such as the fast Fourier transformation module (amplitude and phase spectrums) and harmonic analysis module, was coded by LabVIEW$^{TM}$ software as the graphical language. In an own 'expert module' which is included in the diagnosis program, one can obtain much information about the mold oscillation equipment.

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A three-region movable-boundary helical coil once-through steam generator model for dynamic simulation and controller design

  • Shifa Wu;Zehua Li;Pengfei Wang;G.H. Su;Jiashuang Wan
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.460-474
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    • 2023
  • A simple but accurate mathematical model is crucial for dynamic simulations and controller design of helical coil once-through steam generator (OTSG). This paper presents a three-region movable boundary dynamic model of the helical coil OTSG. Based on the secondary side fluid conditions, the OTSG is divided into subcooled region (two control volumes), two-phase region (two control volumes) and superheated region (three control volumes) with movable boiling boundaries between each region. The nonlinear dynamic model is derived based on mass, energy and momentum conservation equations. And the linear model is obtained by using the transfer function and state space transformation, which is a 37-order model of five input and three output. Validations are made under full-power steady-state condition and four transient conditions. Results show good agreements among the nonlinear model, linear model and the RELAP5 model, with acceptable errors. This model can be applied to dynamic simulations and controller design of helical coil OTSG with constant primary-side flow rate.

Behavior of a Shape Memory Alloy Actuator with Composite Strip and Spring (복합재료 스트립과 스프링을 갖는 형상기억합금 작동기의 거동)

  • Heo, Seok;Hwang, Do-Yeon;Choi, Jae-Won;Park, Hoon-Cheol;Goo, Nam-Seo
    • Composites Research
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    • v.22 no.2
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    • pp.37-42
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    • 2009
  • This paper presents an experimental approach to design a bending-type actuator by using a shape memory alloy wire (SMA), composite strip, and spring. The SMA wire is attached to two edges of the bent strip to apply pre-stress to the SMA wire. The spring is used to provide recovery force right after actuation of the SMA wire. To investigate thermo-mechanical characteristics of the SMA wire, a series of DSC tests have been conducted and tensile tests under various levels of pre-stress and input power have been performed. Based on the measured properties of the SMA wire, bending-type actuators are designed and tested for different combination of strip, number of springs, and input power. It has been found that a bending-type actuator with a proper combination shows fast actuation performance and low power consumption.

Undrained Shear Behavior of Cemented Sand (고결모래의 비배수 전단거동)

  • Lee, Moon Joo;Choi, Sung Kun;Hong, Sung Jin;Lee, Woo Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.3C
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    • pp.181-190
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    • 2006
  • The behavior of artificially cemented sands were investigated by undrained triaxial test of isotropically consolidated sample. The cementation were induced by gypsum that is generally used for the aitificial cementation of sands. The gypsum of 5~20%(sand weight) were included in the sand and cured in the mold under the overburden pressure 55kPa. The yielding strength and stiffness of cemented sand were increased as the degree of cementation. And the dilation of sand was restricted by the cementation bonds, but after breakage of the bonds, it was increased more abrupt than the uncemented sands. The effective stress path showed that the aspects of effective pore water pressure were changed as the degree of cementation and the relative density. The effective stress ratio of cemented sand in the phase transformation line and the failure line were changed by the cementation. Generally the behavior of cemented sand more influenced by the degree of cementation than the relative density.