• Advanced Composite Materials
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• 제16권3호
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• pp.195-206
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• 2007

Carbon nanofiber (CNF)/unsaturated polyester resin (UPR) was prepared by a solvent evaporation method, and the temperature dependency of electrical conductivity was investigated. The CNF/UPR composites had quite a low percolation threshold due to CNF having a larger aspect ratio and being well dispersed in the UPR matrix. The positive temperature coefficient (PTC) was found in the CNF/UPR composites and it showed stronger effect around the percolation threshold. The electrical resistance of the CNF/UPR composites decreased and had lower temperature dependency with increasing numbers of thermal cycles.

• 공업화학
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• 제20권3호
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• pp.307-312
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• 2009

폴리실록산/금속 복합체 내에서의 금속입자의 분산성에 영향을 파악하기 위하여 금속산화물을 배위결합으로 가지고 있는 불록공중합체 형태의 변성 폴리실록산을 합성하였다. 합성된 폴리실록산과 금속입자와의 복합체 제조를 통하여 금속입자의 고분자상 분산상태를 확인하였으며 그 결과 금속산화물의 도입이 복합체 내 금속입자의 분산성에 영향을 미침을 확인하였다. 입자의 분산성과 변성폴리실록산에 도입된 금속산화물의 양적 관계 해석을 위하여 다양한 몰분율을 가지는 변성폴리실록산을 합성하였으며 복합체를 제조하였으며, 몰분율 변화에 따른 복합체에서의 분산성 향상을 파악하기 위하여 복합체의 전기전도성을 측정하여 그 결과를 percolation threshold 이론에 따라 해석하였다. 그 결과 금속산화물의 도입된 양이 많을수록 전도성의 임계농도가 낮아짐을 확인할 수 있으며 이를 통해 변성실록산 내 금속산화물의 몰분율의 증가가 입자의 분산성에 미치는 영향을 해석하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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• pp.155-160
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• 2004

This paper presents a study on the permittivities of the carbon black/epoxy composite at microwave frequency. The measurements were performed at the frequency band of $1 GHz\~18GHz$. The results show that the complex permittivities of composites depend strongly on the natures and concentrations of the carbon black dispersion. The frequency spectrums of dielectric constants and ac conductivities of composites show the good conformities with descriptions of the percolation theory. The carbon black concentration dependencies do not have conformities with the descriptions of percolation theory and there is no peculiar concentration like percolation threshold, on that concentration, the conductivity of composite jumps up. A new scheme, that is a branch of Lichtenecker-Rother formula, is proposed to obtain a mixing law to describe the complex permittivities of the composites as function frequency and concentration of carbon black.

• 한국세라믹학회지
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• 제54권3호
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• pp.257-260
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• 2017

In this work, we present a facile one-pot synthesis of a multilayer-structured platy alumina/few-layer graphene nanocomposite by planetary milling and hot pressing. The sintered composites have electrical conductivity exhibiting percolation behavior (threshold ~ 0.75 vol.%), which is much lower than graphene oxide/ceramic composites (> 3.0 vol.%). The conductivity data are well-described by the percolation theory, and the fitted exponent values are estimated to be 1.65 and 0.93 for t and q, respectively. The t and q values show conduction mechanisms intermediate between 2D- and 3D, which originates from quantum tunneling between nearest neighbored graphenes.

• Journal of Information Science Theory and Practice
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• 제9권1호
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• pp.1-23
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• 2021

This study introduces novel research using Practice Context Models supported by Knowledge Networks and Percolation Theory with the aim to contribute to knowledge management in Proof-of-Concept (PoC) activities. The authors envision this proposal as a potential instrument to identify network structures based on a percolation (propagation) threshold and to analyze the importance of nodes (e.g., practitioners, practices, competencies, movements, and scenarios) during the percolation of knowledge in PoC activities. After thirty months immersed in the natural PoC habitat, acting as observers and practitioners, and supported by an ethnographic exercise and a designer-research mindset, the authors identified the production of meaning in PoC activities occurring in a hermeneutic circle characterized by the presence of several knowledge networks; thus, discovering the 'natural knowledge' in PoC as a spectrum of cognitive development spread throughout its network, as each node could produce and disseminate certain knowledge that flows and influences other nodes. Therefore, this research presents the use of Practice Context Models 'connected' to Knowledge Networks and Percolation Theory as a potential and feasible proposal to be built using the attribution of values (weights) to the nodes (e.g., practitioners, practices, competencies, movements, scenarios, and also knowledge) in the context of PoC with the aim to allow the players (e.g., PoC practitioners) to have more flexibility in building alliances with other players (new nodes); that is, focusing on those nodes with higher value (focus on quality) in collaboration networks, i.e., alliances (connections) with the aim to contribute to knowledge management in the context of PoC.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2002년도 동계연구발표회 논문개요집
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• pp.16-16
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• 2002

Granular metal-insulator alloys, consisting of nano-scale magnetic particles in an insulating matrix are of unique consideration for the technological application and fundamental physics. They display a wide variety of unusual both linear and nonlinear electric-transport, optical and magnetooptical properties, especially for compositions close to the percolation threshold. (omitted)

• Composites Research
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• 제22권3호
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• pp.44-54
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• 2009

본 논문에서는 퍼콜레이션 이론적 관점에 기초한 복소 유전율의 수치모델을 제시하고, 전기 전도성이 뛰어난 카본 블랙을 혼합한 유리섬유/에폭시 복합재료 적층판의 복소 유전율을 이용하여 이 깃을 검증하였다. 제시된 모델은 카본 블랙의 함유율이 퍼콜레이션 임계함유율 보다 높고, 주파수가 충분히 높아서 복합재료의 교류 전기전도도가 주파수에 비례하는 구간에서의 복소 유전율을 모사한다. 복합재료의 복소 유전율은 벡터회로망분석기와 7 mm 동축관을 이용하여 $0.5\;GHz\;{\sim}18\;GHz$ 대역에서 측정되었다. 제시된 모델은 퍼콜레이션 이론에서 유용하게 사용되는 축척(눈금잡이) 법칙의 함수형태와 실험을 통하여 구한 상수들로 구성되어 있으며, 복소 유전율을 주파수와 가본 블랙의 함유율의 함수로 나타내었다. 제시된 모델은 복소 유전율을 측정결과와의 비교를 통하여 검증되었다.

• Korean Chemical Engineering Research
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• 제55권3호
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• pp.426-429
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• 2017

본 연구에서는 은나노입자 및 보론나이트라이드의 혼합이 열전도도 및 전기전도도에 미치는 효과에 대해 고찰하였다. 에폭시/보론나이트라이드 복합체의 경우 열전도도가 보론나이트라이드의 함량에 비례하여 증가하였으며 에폭시/은나노입자의 경우는 열전도도가 크게 변화 없었으며 전기전도도는 20 vol%에서 퍼콜레이션 현상을 보여주었다. 퍼콜레이션 함량 이하에서 은나노입자를 고정시키고 보론나이트라이드를 첨가하여 조사한 결과 전기전도도 및 열전도도가 크게 향상됨을 알 수 있었다.

• Macromolecular Research
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• 제14권4호
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• pp.456-460
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• 2006

The electrical, morphological, and mechanical properties of poly carbonate (PC)/multi-walled carbon nan-otube (MWNT) composites were studied by electrical conductivity, electromagnetic interference shielding efficiency (EMI SE), scanning electron microscopy, and tensile strength measurements. In the electrical property analysis of the PC/MWNT composites, the percolation threshold of the PC/MWNT composites was observed between 1.5 and 2.5 wt% MWNT content. From the electrical conductivity and EMI SE studies, the theoretical values of the EMI SE were in good agreement with the experimental values of the EMI SE. From the morphology of the PC/MWNT composites, it was observed that MWNT is dispersed homogenously in the PC matrix. From the electrical conductivity and morphological studies, it was suggested that the percolation threshold of the PC/MWNT composites is related with the morphological results in that MWNT is apparently interconnected to form an electrical pathway. The mechanical properties of the PC/MWNT composites peaked at the MWNT content of 2.5 wt%.

• 공업화학
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• 제21권5호
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• pp.500-504
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• 2010

다중벽 탄소 나노튜브(Carbon nanotube, MWNTs)의 우수한 전기적 기계적 특성과 폴리우레탄의 우수한 기계적 물성을 이용하여 우수한 전기 전도성 복합체를 제조하기 위하여 말단기가 polyurethane로 기능화 된 탄소 나노튜브(PU-g-MWNTs)를 제조하였다. 말단기에 형성된 폴리우레탄과 고분자 메트릭스 간의 상용성으로 인한 계면 접합력으로 인해 기능화된 CNT 복합체 기능화 되지 않은 CNT에 비해 우수한 분산성을 나타내었다. PU-g-MWNT/PU 복합체의 전기 전도성을 PU-g-MWNT의 농도에 따라 측정하였으며 percolation threshold 이론에 의해 해석하였다. 그 결과 PU-g-MWNT/PU 복합체의 전기전도성은 임계농도 0.78 wt%과 임계지수 0.945를 가짐을 확인하였다.