• Title/Summary/Keyword: percolation threshold

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Conductivity stability of carbon nanofiber/unsaturated polyester nanocomposites

  • Wu, Shi-Hong;Natsuki, Toshiaki;Kurashiki, Ken;Ni, Qing-Qing;Iwamoto, Masaharu;Fujii, Yoshimichi
    • Advanced Composite Materials
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    • v.16 no.3
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    • pp.195-206
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    • 2007
  • Carbon nanofiber (CNF)/unsaturated polyester resin (UPR) was prepared by a solvent evaporation method, and the temperature dependency of electrical conductivity was investigated. The CNF/UPR composites had quite a low percolation threshold due to CNF having a larger aspect ratio and being well dispersed in the UPR matrix. The positive temperature coefficient (PTC) was found in the CNF/UPR composites and it showed stronger effect around the percolation threshold. The electrical resistance of the CNF/UPR composites decreased and had lower temperature dependency with increasing numbers of thermal cycles.

Study on the Electrical Conductivity in Polysiloxane/Metal Composite Containing Metal Oxide (금속산화물을 포함한 변성폴리실록산/금속 복합체의 전기 전도성 연구)

  • Im, Hyungu;Kim, Jooheon
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.307-312
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    • 2009
  • The block-co-polymer type thermosetting polysiloxane coordinated with metal oxide was synthesized to investigate the effect of metal oxide on the dispersity of metal powder in the polysiloxane/metal composite material. The metal powder in the polysiloxane/metal composite materials is better dispersed with metal oxide complex polysiloxane than the case without metal oxide. To understand the effect of quantities of metal oxide on the polysiloxane chain, the various polysiloxanes with different ratios of block unit were synthesized. Electrical conductivity was interpreted by percolation threshold theory to understand the dispersity of dense composite. The behavior of conductivity was in good agreement with theoretical value. The critical value was decreased as the quantities of metal oxide are increased. As a result, as the metal oxide increased on the polymer chain, the dispersity of metal filler was increased.

Simulation of Complex Permittivity of Carbon Black/Epoxy Composites at Microwave Frequency Band (마이크로파에서의 카본 블랙/에폭시 복합재료의 유전율 모사)

  • Kim J.B.;Kim T.W.;Kim C.G.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.155-160
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    • 2004
  • This paper presents a study on the permittivities of the carbon black/epoxy composite at microwave frequency. The measurements were performed at the frequency band of $1 GHz\~18GHz$. The results show that the complex permittivities of composites depend strongly on the natures and concentrations of the carbon black dispersion. The frequency spectrums of dielectric constants and ac conductivities of composites show the good conformities with descriptions of the percolation theory. The carbon black concentration dependencies do not have conformities with the descriptions of percolation theory and there is no peculiar concentration like percolation threshold, on that concentration, the conductivity of composite jumps up. A new scheme, that is a branch of Lichtenecker-Rother formula, is proposed to obtain a mixing law to describe the complex permittivities of the composites as function frequency and concentration of carbon black.

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Percolative Electrical Conductivity of Platy Alumina/Few-layer Graphene Multilayered Composites

  • Choi, Ki-Beom;Kim, Jong-Young;Lee, Sung-Min;Lee, Kyu-Hyoung;Yoon, Dae Ho
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.257-260
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    • 2017
  • In this work, we present a facile one-pot synthesis of a multilayer-structured platy alumina/few-layer graphene nanocomposite by planetary milling and hot pressing. The sintered composites have electrical conductivity exhibiting percolation behavior (threshold ~ 0.75 vol.%), which is much lower than graphene oxide/ceramic composites (> 3.0 vol.%). The conductivity data are well-described by the percolation theory, and the fitted exponent values are estimated to be 1.65 and 0.93 for t and q, respectively. The t and q values show conduction mechanisms intermediate between 2D- and 3D, which originates from quantum tunneling between nearest neighbored graphenes.

Using Practice Context Models to Knowledge Management in Proof-of-Concept Activities: A Contribution of Knowledge Networks and Percolation Theory

  • Neto, Antonio Jose Rodrigues;Borges, Maria Manuel;Roque, Licinio
    • Journal of Information Science Theory and Practice
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    • v.9 no.1
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    • pp.1-23
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    • 2021
  • This study introduces novel research using Practice Context Models supported by Knowledge Networks and Percolation Theory with the aim to contribute to knowledge management in Proof-of-Concept (PoC) activities. The authors envision this proposal as a potential instrument to identify network structures based on a percolation (propagation) threshold and to analyze the importance of nodes (e.g., practitioners, practices, competencies, movements, and scenarios) during the percolation of knowledge in PoC activities. After thirty months immersed in the natural PoC habitat, acting as observers and practitioners, and supported by an ethnographic exercise and a designer-research mindset, the authors identified the production of meaning in PoC activities occurring in a hermeneutic circle characterized by the presence of several knowledge networks; thus, discovering the 'natural knowledge' in PoC as a spectrum of cognitive development spread throughout its network, as each node could produce and disseminate certain knowledge that flows and influences other nodes. Therefore, this research presents the use of Practice Context Models 'connected' to Knowledge Networks and Percolation Theory as a potential and feasible proposal to be built using the attribution of values (weights) to the nodes (e.g., practitioners, practices, competencies, movements, scenarios, and also knowledge) in the context of PoC with the aim to allow the players (e.g., PoC practitioners) to have more flexibility in building alliances with other players (new nodes); that is, focusing on those nodes with higher value (focus on quality) in collaboration networks, i.e., alliances (connections) with the aim to contribute to knowledge management in the context of PoC.

MAGNETOREFRACTIVE EFFECT AND CUBIC NONLINEAR MAGNETOOPTICS IN MAGNETIC GRANULAR ALLOYS

  • Granovsky, A.;Inoue, M.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.16-16
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    • 2002
  • Granular metal-insulator alloys, consisting of nano-scale magnetic particles in an insulating matrix are of unique consideration for the technological application and fundamental physics. They display a wide variety of unusual both linear and nonlinear electric-transport, optical and magnetooptical properties, especially for compositions close to the percolation threshold. (omitted)

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Study on the numerical model of complex permittivity of composites based on the percolation theory (퍼콜레이션 이론에 기초한 복합재료의 복소 유전율 모델에 대한 연구)

  • Kim, Jin-Bong;Lee, Sang-Kwan;Kim, Chun-Gon
    • Composites Research
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    • v.22 no.3
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    • pp.44-54
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    • 2009
  • In this paper, we proposed a numerical model the complex permittivity for the E-glass fabric/epoxy composite laminate containing electrical conductive carbon black. The model is based on the percolation theory and for the composites over than the percolation threshold and in higher frequency band in that the AC conductivity is fully proportional to the frequency. The measurement for the complex permittivity wasperformed at the frequency band of 0.5 GHz $\sim$ 18.0 GHz using a vector network analyzer with a 7 mm coaxial air line. The proposed model is composed of the numerical equations of the scaling law used in percolation theory and constants obtained from experiments to quantify the model itself. The model describes the complex permittivity as the function of frequency and filler concentration. The model was verified by being compared with the measurements.

Improvement of Thermal and Electrical Conductivity of Epoxy/boron Nitride/silver Nanoparticle Composite (열전도도 및 전기전도도가 향상된 에폭시/보론나이트라이드/은나노입자 복합체의 제조)

  • Kim, Seungyong;Lim, Soonho
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.426-429
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    • 2017
  • In this study, we investigated the effect of BN (boron nitride) on the thermal and the electrical conductivity of composites. In case of epoxy/BN composites, the thermal conductivity was increased as the BN contents were increased. Epoxy/AgNP (Ag nanoparticle) nanocomposites exhibited a slight change of thermal conductivity and showed a electrical percolation threshold at 20 vol% of Ag nanoparticles. At the fixed Ag nanoparticle content below the electrical percolation threshold, increasing the amount of BN enhanced the electrical conductivity as well as thermal conductivity for the epoxy/AgNP/BN composites.

Effects of Morphology on the Electrical and Mechanical Properties of the Polycarbonate/Multi-Walled Carbon Nanotube Composites

  • Kum Chong-Ku;Sung Yu-Taek;Han Mi-Sun;Lee Heon-Sang;Lee Sun-Jeong;Joo Jin-Soo;Kim Woo-Nyon
    • Macromolecular Research
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    • v.14 no.4
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    • pp.456-460
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    • 2006
  • The electrical, morphological, and mechanical properties of poly carbonate (PC)/multi-walled carbon nan-otube (MWNT) composites were studied by electrical conductivity, electromagnetic interference shielding efficiency (EMI SE), scanning electron microscopy, and tensile strength measurements. In the electrical property analysis of the PC/MWNT composites, the percolation threshold of the PC/MWNT composites was observed between 1.5 and 2.5 wt% MWNT content. From the electrical conductivity and EMI SE studies, the theoretical values of the EMI SE were in good agreement with the experimental values of the EMI SE. From the morphology of the PC/MWNT composites, it was observed that MWNT is dispersed homogenously in the PC matrix. From the electrical conductivity and morphological studies, it was suggested that the percolation threshold of the PC/MWNT composites is related with the morphological results in that MWNT is apparently interconnected to form an electrical pathway. The mechanical properties of the PC/MWNT composites peaked at the MWNT content of 2.5 wt%.

Dispersity and Electro-Conductivity of PU Grafted MWCNT/PU Composite via Simple Blending Method (블렌딩을 이용한 폴리우레탄 그라프트 다중벽 탄소나노튜브/폴리우레탄 복합체의 전기 전도성 및 분산 특성)

  • Yun, Sung-Jin;Im, Hyun-Gu;Kim, Joo-Heon
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.500-504
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    • 2010
  • The PU-g-MWNTs/PU film was synthesized by simple blending method to fabricate composites which have excellent mechanical and electrical properties. PU-g-MWNTs based composite revealed much enhanced dispersity than pristine MWNTs composite because of interfacial interaction related with interfacial compatibility between polymer matrix and PU on the MWNTs surface. The electro-conductivity of composite was measured as a function of PU-g-MWNTs concentration. The results were correlated with percolation threshold theory. As a result, the critical concentration and exponent of electro-conductivity behavior was equal to 0.78 wt% and 0.945.