• Title/Summary/Keyword: oxide removal

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Nickel Supported Adsorbent for Removing Carbon Monoxide (일산화탄소 제거를 위한 니켈 담지 흡착제 제조)

  • Son, Jung-hwa;Kim, Young-ho;Yoon, Songhun;Park, Yong-Ki;Lee, Chul Wee
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.868-874
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    • 2008
  • The Ni based adsorbent was prepared by co-precipitation method and its performance for removing carbon monoxide was investigated. Here, silica, aluminium silicate and ${\gamma}$-alumina were used for carriers of catalyst. $Ni(NO_3)_2{\cdot}6H_2O$ and $Ni(CH_3COO)_2{\cdot}4H_2O$ were utilized for Ni precursors. Precipitants were urea and citric acid. After precipitation of Ni salt on the carrier and following reduction using $H_2$ gas, adsorbent was prepared and its performance was analyzed based on EDS, TPR and XRD experiments. In accordance with change of precipitation agents, Ni salts on carrier, carriers and reduction condition. Adsorbent performance for removing carbon monoxide was investigated. The adsorbent with 54.8 wt% Ni prepared using urea precipitant under reduction condition at $500^{\circ}C$ for 3 h exhibited the best CO removal performance.

Design of gas suspension absorber to improve desulfurization efficiency

  • Hwang, Woohyeon;Lee, Kyung-Ok
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.2
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    • pp.189-195
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    • 2020
  • In this study, the inlet duct and guide vane of the gas floating absorption tower were redesigned to improve the desulfurization efficiency so that the exhaust gas can be uniformly introduced into the absorption tower. In order to reduce the sulfur oxide pollutants among the main sources of air pollutants in industrial boilers, the existing equipment is redesigned and solved. For this purpose, change the exhaust gas, the slurry and recycling the adsorbent to improve the removal efficiency of SOx component in the exhaust gas inside the gas floating absorption tower so as to uniformly contact. And the initial design value and CFD value for the pressure loss from the boiler outlet to the gas floating absorption tower outlet are verified. Also, the velocity distribution of the exhaust gas, the concentration distribution of the recycled adsorbent, the liquid slurry behavior, and the pressure loss were compared. The results confirmed that the desulfurization efficiency was improved because the pressure loss from the boiler outlet to the absorption tower outlet was reduced and the deflection of the exhaust gas was minimized.

The Action of Ginkgo Bibloba Extract in the Isolated Rabbit Corpus Cavernosum

  • Chung, Woo-Sik;Choi, Young-Deuk;Park, Young-Yo;Hah, Jong-Sik
    • The Korean Journal of Physiology
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    • v.29 no.1
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    • pp.61-67
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    • 1995
  • The extract of Ginkgo bibloba (EGb) is a complex mixture of natural products from the Ginkgo leaves and clinically used for the treatment of cerebral and peripheral circulatory disturbances due to its combined activity of several vasoactive principles. In this study we investigated the action of EGb and its mechanism in isolated rabbit corporal smooth muscle to evaluate the possibility of using this material as a pharmacoerecting agent. Strips of rabbit corpus cavernosum were mounted in organ chambers to measure isometric tension. EGb began to exert an relaxing effect at 1 mg/ml in the submaximally precontracted muscle strips with phenylephrine $(PHE,\;5{\times}10^{-6}\;M)$; causing concentration-dependent relaxation with maximal effect at $3{\sim}5\;mg/ml$. That relaxation was partially inhibited by removal of the smooth muscle endothelium or by pretreatment with a NO scavenger, pyrogallol $(10^{-4}\;M)$ or the guanylate cyclase inhibitor, methylene blue $(10^{-4}\;M)$. Pretreatment with EGb (3 mg/ml) inhibited PHE- $(5{\times}10^{-6}\;M)$ or KCI- (20 and 40 mM) induced contraction of muscle strip. In calcium-free high potassium solution EGb depressed the basal tone of the depolarized muscle strip and inhibited calcium-induced contraction when $CaCl_2$ $(10^{-4}\;M)$ was added. These results suggest that EGb relaxes rabbit corpus cavernosal smooth muscle through multiple action mechanisms that include increasing the release of nitric oxide from the corporal sinusoidal endothelium, sequestration of intracytosolic calcium, and maybe a hyperpolarizing action.

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Characteristics of Damage on Photosensor Irradiated by Intense Illumination : Thermal Diffusion Model (고섬광에 노출된 광센서의 손상 특성 : 열확산 모델)

  • Kwon, Chan-Ho;Shin, Myeong-Suk;Hwang, Hyon-Seok;Kim, Hong-Lae;Kim, Seong-Shik;Park, Min-Kyu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.2
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    • pp.201-207
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    • 2012
  • Pulsed lasers at the 613 nm and 1064 nm wavelengths on nanoseconds have been utilized to characterize the damage on Si photodiode exposed to intense illumination. Morphological damages and structural changes at sites on the photodiode irradiated during microseconds of laser pulses were analyzed by FE-SEM images and XRD patterns, respectively. The removal of oxide coating, ripple, melting marks, ridges, and crater on photodiodes were definitely observed in order of increasing the pulse intensities generated above the damage threshold. Then, the degradation in photosensitivity of the Si photodiode irradiated by high power density pulses was measured as a function of laser irradiation time at the various wavelengths. The free charge carrier and thermal diffusion mechanisms could have been invoked to characterize the damage. The relative photosensitivity data calculated using the thermal diffusion model proposed in this paper have been compared with the experimental data irradiated above the damage threshold.

A Study on the Two-Step CMP for Prevention of Over-polishing (과다연마 방지를 위한 두 단계 CMP에 관한 연구)

  • Shin, Woon-Ki;Kim, Hyoung-Jae;Park, Boum-Young;Park, Ki-Hyun;Joo, Suk-Bae;Kim, Young-Jin;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.525-526
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    • 2007
  • Over-polishing is required to completely remove the material of top surface across whole wafer, in spite of a local dishing problem. This paper introduces the two-step CMP process using protective layer and high selectivity slurry, to reduce dishing amount and variation. The 30nm thick protective oxide layer was deposited on the pattern, and then polished with low selectivity slurry to partially remove the projected area while suppressing the removal rate of the recessed area. After the first step CMP process, high selectivity slurry was used to minimize the dishing amount and variation in pattern structure. Experimental result shows that two-step CMP process can be successfully applicable to reduce the dishing defect generated in over-polishing.

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Study on the Mechanism of Vascular Relaxation Induced by Cortex Caryphylli (정향피 추출물의 혈관 이완효과 및 작용기전에 대한 연구)

  • Song, Chul-Min;Shin, Sun-Ho;Jung, Hyun-Ae;Lee, Jun-Kyoung;Cao, Li-Hua;Kang, Dae-Gil;Lee, Ho-Sup
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.5
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    • pp.1166-1173
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    • 2006
  • The aqueous extracts of Cortex Caryophylli (AEC) induced dose-dependent relaxation of phenylephrine-precontracted aorta, which was abolished by removal of functional endothelium. Pretreatment of the endothelium-intact aortic tissues with N$^G$_nitro-L-arginine methyl ester (L-NAME) or 1 H-[1,2,4]-oxadiazole-[4,3-${\alpha}$l-quinoxalin-1-one (ODQ) inhibited the relaxation induced by AEC. AEC-induced vascular relaxations were also markedly attenuated by addition of verapamil, diltiazem and glibenclamide, tetraethylammonium (TEA), respectively, while the relaxation effect of AEC was not blocked by indomethacin, atropine, or propranolol. Moreover, incubation of endothelium-intact aortic rings with AEC increased the production of cGMP. These results suggest that AEC dilates vascular smooth muscle via endothelium-dependent nitric oxide/cGMP signaling, which seems to be causally related with L-type Ca$^{2+}$ and K$^+$ channels.

A Study on Characterization for Low Temperature SCR Reaction by $Mn/TiO_2$ Catalysts with Using a Various Commercial $TiO_2$ Support (다양한 상용 $TiO_2$ 담체를 이용한 $Mn/TiO_2$ 촉매의 저온 SCR 반응 특성 연구)

  • Kwon, Dong Wook;Choi, Hyun Jin;Park, Kwang Hee;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.190-194
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    • 2012
  • 10 wt% Mn supported on various commercial $TiO_2$ catalysts were prepared by wet-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with $NH_3$. A combination of various physico-chemical techniques such as BET, XRD, XPS and TPR were used to characterize these catalysts. MnOx surface densities on MnOx/$TiO_2$ catalyst were related to surface area. As MnOx surface density lowered with high dispersion, the SCR activity for low temperature was increased and the reduction temperature ($MnO_2$ ${\rightarrow}$ $Mn_2O_3$) of surface MnOx was lower. For a high SCR, MnOx could be supported on a high surface area of $TiO_2$ and should be existed a high dispersion of non-crystalline species.

Synthesis and Morphology Control of Rod Shaped Potassium Hexatitanate (봉상형 육티탄산칼륨(K2Ti6O13) 제조 및 형상제어)

  • Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.145-151
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    • 2018
  • Rod shaped Potassium hexatitanate ($K_2Ti_6O_{13}$) was synthesized from colloidal mixture of $TiO_2$, KOH and graphene oxide (GO) by aerosol spray drying and post heat treatment. Firstly, $TiO_2-KOH-GO$ composites were fabricated by aerosol spray drying in argon atmosphere. The composites were then calcined to form a rod shaped morphology of potassium titanate (KTO) in the presence of graphene at $900^{\circ}C$ for 3 h in argon atmosphere. Finally, the rod shaped KTO was obtained after removal of graphene (GR) at $800^{\circ}C$ and 3 h in air atmosphere. Characterization of the synthesized $K_2Ti_6O_{13}$ was carried out using the XRD, BET and FE-SEM. The length and diameter of the synthesized $K_2Ti_6O_{13}$ could be controlled by weight fraction of GO in the aerosol precursor. The length of $K_2Ti_6O_{13}$ rod increased with decreasing its diameter as GO concentration increased. The aspect ratio of the synthesized $K_2Ti_6O_{13}$ rod was controlled from 5 to 13.

Low-Temperature Sintering Behavior of Aluminum Nitride Ceramics with Added Copper Oxide or Copper

  • Hwang, Jin-Geun;Oh, Kyung-Sik;Chung, Tai-Joo;Kim, Tae-Heui;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.104-110
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    • 2019
  • The low-temperature sintering behavior of AlN was investigated through a conventional method. $CaF_2$, CuO and Cu were selected as additives based on their low melting points. When sintered at $1600^{\circ}C$ for 8 h in $N_2$ atmosphere, a sample density > 98% was obtained. The X-ray data indicated that eutectic reactions below $1200^{\circ}C$ were found. Therefore, the current systems have lower liquid formation temperatures than other systems. The liquid phase showed high dihedral angles at triple grain junctions, indicating that the liquid had poor wettability on the grain surfaces. Eventually, the liquid was likely to vaporize due to the unfavorable wetting condition. As a result, a microstructure with clean grain boundaries was obtained, resulting in higher contiguity between grains. From EDS analysis, oxygen impurity seems to be well removed in AlN lattice. Therefore, it is believed that the current systems are beneficial for reducing sintering temperature and improving oxygen removal.

Trend of Nitrogen Oxide Reduction Technologies in Cement Industry (시멘트 산업에서의 질소산화물 저감 기술 동향)

  • Seo, JunHyung;Kim, YoungJin;Cho, KyeHong;Cho, JinSang;Han, KyungHo;Yoon, DoYoung
    • Resources Recycling
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    • v.29 no.6
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    • pp.114-124
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    • 2020
  • In the cement industry, NOx emission is recognized as an important problem, and NOx reduction technologies can be divided into process change, staged combustion, low NOx burner, selective non-catalytic reduction and selective catalytic reduction method. The operation of the selective non-catalytic reduction method, which is the most used in the cement industry, is expected to make it difficult to meet the emission standards to be strengthened in the future, and it is necessary to improve equipment such as SCR and secure technologies. Recently, we are developing technologies for simultaneous application of SNCR and SCR, dust and denitrification filter technology, and removal technology using NO oxidation.