• 제목/요약/키워드: oxide reduction

검색결과 1,337건 처리시간 0.026초

선택적 산화 방식을 이용한 핀 채널 MOSFET의 소스/드레인 저항 감소 기법 (Reduction of Source/Drain Series Resistance in Fin Channel MOSFETs Using Selective Oxidation Technique)

  • 조영균
    • 융합정보논문지
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    • 제11권7호
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    • pp.104-110
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    • 2021
  • 본 핀 채널 전계 효과 트랜지스터에서 낮은 소스/드레인 직렬 저항을 위한 새로운 선택적 산화 방식을 제안하였다. 이 방법을 이용하면, gate-all-around 구조와 점진적으로 증가되는 형태의 소스/드레인 확장영역을 갖는 핀 채널 MOSFET를 얻을 수 있다. 제안된 트랜지스터는 비교 소자에 비해 70% 이상의 소스/드레인 직렬 저항의 감소를 얻을 수 있다. 또한, 제안된 소자는 단채널 효과를 억제하면서도 높은 구동 전류와 전달컨덕턴스 특징을 보인다. 제작된 소자의 포화전류, 최대 선형 전달컨덕턴스, 최대 포화 전달컨덕턴스, subthreshold swing, 및 DIBL은 각각 305 ㎂/㎛, 0.33 V, 13.5 𝜇S, 76.4 𝜇S, 78 mV/dec, 62 mV/V의 값을 갖는다.

알레르기성 비염에서 황련-감초 하태독법의 IL-4활성 조절을 통한 항염증효과 (Anti-inflammatory effects of Hataedock with Coptidis Rhizoma and Glycyrrhiza Uralensis on Allergic Rhinitis through Regulating IL-4 Activation)

  • 정아람
    • 동의생리병리학회지
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    • 제33권2호
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    • pp.116-122
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    • 2019
  • The aim of this study is to evaluate the anti-inflammatory effect of Hataedock treatment using Coptidis Rhizome and Glycyrrhiza Uralensis (CG) mixed extract in allergic rhinitis induced NC/Nga mice. We divided NC/Nga mice into 3 groups as follows; allergic rhinitis-induced group after CG Hataedock treatment (CGT, n=10), no treatment group (Ctrl), allergic rhinitis elicited group (ARE). To induce allergic rhinitis, NC/Nga mice of 3 weeks age were sensitized on 7, 8 and 9week by Ovalbumin (OVA) antigen in intranasal space. Hataedock using CG extract was administered on week 3 in allergic rhinitis-induced group (CGT) after Hataedock treatment. To identify distribution of Interlukin (IL)-4, Cluster of differentiation 40 (CD40), high-affinity IgE receptor ($Fc{\varepsilon}RI$), substance P, Matrix metallopeptidase 9 (MMP-9), Nuclear $factor-{\kappa}B$ ($NF-{\kappa}B$) p65, Inducible nitric oxide synthase (iNOS) and Cycloxygenase-2 (COX-2), we used histological examination. CGT significantly inhibited IL-4 and CD40 response compared with ARE. The reduction of Th2 cytokine expression decreased inflammatory mediators such as $Fc{\varepsilon}RI$, substance P, MMP-9, $NF-{\kappa}B$ p65, iNOS and COX-2. Such immunological improvement induced reduction of respiratory epithelial damage and mucin secretion in goblet cell. These results indicate that Hataedock treatment suppresses allergic rhinitis through modulating of Th2 responses and diminishing various inflammatory mediators in nasal mucosal tissue. It might have potential applications for prevention and treatment of allergic rhinitis.

칼슘 증기에 의한 Ti-48Al-2Cr-2Nb 분말의 산소 저감 및 표면 화학적 상태 분석 (Evaluation of Oxygen Reduction and Surface Chemical State of Ti-48Al-2Cr-2Nb Powder by Ca Vapor)

  • 김태헌;권한중;임재원
    • 한국분말재료학회지
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    • 제28권1호
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    • pp.31-37
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    • 2021
  • This study explores reducing the oxygen content of a commercial Ti-48Al-2Cr-2Nb powder to less than 400 ppm by deoxidation in the solid state (DOSS) using Ca vapor, and investigates the effect of Ca vapor on the surface chemical state. As the deoxidation temperature increases, the oxygen concentration of the Ti-48Al-2Cr-2Nb powder decreases, achieving a low value of 745 ppm at 1100℃. When the deoxidation time is increased to 2 h, the oxygen concentration decreases to 320ppm at 1100℃, and the oxygen reduction rate is approximately 78% compared to that of the raw material. The deoxidized Ti-48Al-2Cr-2nb powder maintains a spherical shape, but the surface shape changes slightly owing to the reaction of Ca and Al. The oxidation state of Ti and Al on the surface of the Ti-48Al-2Cr-2Nb powder corresponds to a mixture of TiO2 and Al2O3. As a result, the peaks of metallic Ti and Ti suboxide intensify as TiO2 and Al2O3 in the surface oxide layer are reduced by Ca vapor deposition.

Inclusion and mechanical properties of ODS-RAFM steels with Y, Ti, and Zr fabricated by melting

  • Qiu, Guo-xing;Wei, Xu-li;Bai, Chong;Miao, De-jun;Cao, Lei;Li, Xiao-ming
    • Nuclear Engineering and Technology
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    • 제54권7호
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    • pp.2376-2385
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    • 2022
  • Two groups of oxide dispersion-strengthened reduced-activation ferritic/martensitic steels (A and B) were prepared by adding Y, Ti, and Zr into steels through vacuum induction melting to investigate the inclusions, microstructures, mechanical properties of the alloys. Results showed that particles with Y, Ti, and Zr easily formed. Massive, Zr-rich inclusions were found in B steel. Density of micron inclusions in A steel was 1.42 × 1014 m-3, and density of nanoparticles was 3.61 × 1016 m-3. More and finer MX carbides were found in steel tempered at 650 ℃, and yield strengths (YS) of A and B steel were 714±2 and 664±3.5 MPa. Thermomechanical processing (TMP) retained many dislocations, which improved the mechanical properties. YSs of A and B treated by TMP were 725±3 and 683±4 MPa. The existence of massive Zr-rich inclusions in B steels interrupted the continuity of the matrix and produced microcracks (fracture), which caused a reduction in mechanical properties. The presence of fine prior austenite grain size and inclusions was attributed to the low DBTTs of the A steels; DBTTs of A650 and A700 alloy were -79 and -65 ℃. Tempering temperature reduction and TMP are simple, readily useable methods that can lead to a superior balance of strength and impact toughness in industry applications.

Evaluation of the anti-inflammatory effects of silkworm (Bombyx mori L.) pupal extracts against lipopolysaccharide-induced inflammation in the murine macrophage cell line RAW264.7

  • Kamidi, Rahul;HaeYong, Kweon;Hun-bok, Kim;Ji Hae, Lee
    • International Journal of Industrial Entomology and Biomaterials
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    • 제45권2호
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    • pp.99-107
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    • 2022
  • Silkworm pupal extracts (SPE) were prepared in different solvents (water, 30%, 50%, 70%, and 100% ethanol) and their anti-inflammatory effects were evaluated in the RAW264.7 cell line. The SPE composition was initially evaluated by determining the protein content and performing Fourier transform infrared (FTIR) analysis. The protein content of the different SPE ranged from 6.75-130.93 mg/g of extract. FTIR analysis exhibited distinguishable absorption peaks among the extracts and indicated the presence of lipids, proteins, carbohydrates, and nucleic acid moieties. The levels of released nitric oxide (NO) and interleukin-6 (IL-6) expression in lipopolysaccharide (LPS)-induced RAW264.7 cells were only attenuated by 100% ethanolic SPE to 19.44% and 16.77%, respectively. The other solvent extracts were ineffective. Hence, further studies were conducted with 100% ethanolic SPE from three distinct stages of male and female silkworm pupae belonging to four silkworm varieties (Baegokjam; B, GoldenSilk; G, Juhwangjam; J, and YeonNokjam; Y). The best reduction in NO release and interleukin-1β (IL-1β) expression levels was achieved by the SPE of early female pupae belonging to the Baegokjam variety (32.72%) and those of early female pupae belonging to the Baegokjam and GoldenSilk (59.93%) varieties, respectively. The best reduction in IL-6 expression by 49.70% was achieved by SPE from female pupae of the mid-pupal stage belonging to the Baegokjam variety.

선박 배가스 내 질소산화물 제거를 위한 선택적촉매환원법(SCR) 기술동향 (Selective Catalytic Reduction (SCR) Technology Trend for the Removal of Nitrogen Oxide from Ship Flue Gas)

  • 원종민;홍성창
    • 공업화학전망
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    • 제22권5호
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    • pp.25-40
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    • 2019
  • 전 세계적으로 환경문제를 해결하기 위한 방안으로 환경규제를 강화시키며 특히 다양한 대기오염 물질 중 최근 큰 이슈인 초미세먼지 저감을 위해 전구물질로 알려진 질소산화물을 제어하기 위한 다양한 기술개발이 가속화되고 있다. 특히, 다양한 처리기술 중에 기술적·경제적인 이점을 갖춘 선택적 촉매환원법(selective catalytic reduction, SCR) 기술을 통하여 질소산화물 제거를 위해 암모니아를 환원제로 반응에 참여시켜 인체에 무해한 H2O, N2로 전환하는 기술이 대표적이다. 최근 전 세계적으로 다양한 산업군에서 질소산화물이 배출되고 있으며, 점오염원뿐만이 아니라 비점오염원(mobile sources)에 대한 규제가 강화되고 있다. 디젤엔진이 장착된 선박 배가스 처리장치 내 SCR 기술이 주목을 받고 있으며, NH3-SCR에 사용되는 촉매는 주로 VOx/TiO2, VOx/W/TiO2 촉매가 대표적이다. 한편 선박 디젤엔진에 사용되는 연료에 따라 연소배가스 특성이 다르다. 이러한 연료가 연소됨에 따라 SO2, SO3가 발생되고 환원제인 NH3와 결합하여 황산암모늄염((NH4)2SO4), ABS (ammonium bisulfate, NH4HSO4)과 같은 염을 형성시켜 탈질촉매의 비활성화 문제가 발생된다. 이러한 비활성화 물질이 침적된 탈질촉매를 재활성화 시키기 위하여 열 산화를 통해 재생시키고 있다. 이처럼 선박용 SCR 촉매는 강화되는 배출규제 및 엔진기술의 발달로 저감되는 운전 온도에 대비하여 저온 활성 재생이 가능한 고활성, 고내구성 촉매기술 개발이 필요하다.

첨가제가 유기성 폐기물 퇴비화 과정 중 온실가스 발생에 미치는 영향: 리뷰 및 데이터 분석 (Effects of Additives on Greenhouse Gas Emission during Organic Waste Composting: A Review and Data Analysis)

  • 정석순;박병준;윤정환;이상필;양재의;김혁수
    • 한국환경농학회지
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    • 제42권4호
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    • pp.358-370
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    • 2023
  • Composting has been proposed for the management of organic waste, and the resulting products can be used as soil amendments and fertilizer. However, the emissions of greenhouse gases (GHGs) such as CO2, CH4, and N2O produced in composting are of considerable concern. Hence, various additives have been developed and adopted to control the emissions of GHGs. This review presents the different additives used during composting and summarizes the effects of additives on GHGs during composting. Thirty-four studies were reviewed, and their results showed that the additives can reduce cumulative CO2, CH4, and N2O emission by 10.5%, 39.0%, and 28.6%, respectively, during composting. Especially, physical additives (e.g., biochar and zeolite) have a greater effect on mitigating N2O emissions during composting than do chemical additives (e.g., phosphogypsum and dicyandiamide). In addition, superphosphate had a high CO2 reduction effect, whereas biochar and dicyandiamide had a high N2O reduction effect. This implies that the addition of superphosphate, biochar, and dicyandiamide during composting can contribute to mitigating GHG emissions. Further research is needed to find novel additives that can effectively reduce GHG emissions during composting.

마이크로버블과 환원제를 이용한 습식 NO 및 SO2의 동시제거 (Simultaneous Removal of NO and SO2 using Microbubble and Reducing Agent)

  • 송동훈;강조홍;박현식;송호준;정용철
    • 청정기술
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    • 제27권4호
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    • pp.341-349
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    • 2021
  • 연소시설에서는 화석연료에 포함된 질소와 황이 산소와 반응하여 대기 오염물질인 질소산화물(NOX)과 황산화물(SOX)을 발생시킨다. 인체에 유해하고 환경 오염을 야기하는 NOX, SOX를 저감하기 위해 전세계적으로 환경규제를 시행 중이며, 규제를 충족하기 위해 다양한 기술들을 적용하고 있다. 상용화된 NOX 및 SOX 저감방식들로 SCR (selective catalytic reduction), SNCR (selective non-catalytic reduction), WFGD (wet flue gas desulfurization) 등이 있으나 이 방식들의 단점들 때문에 NOX, SOX를 동시제거하는 연구가 근래 많이 수행되고 있다. 그러나 NOX, SOX 동시 제거 방식에서도 산화제 및 흡수제로 인한 폐수 발생에 대한 문제점, 특정 산화제를 활성화 하기 위한 촉매 및 전기분해 사용에 따른 비용 발생, 마지막으로 기체 산화제들 자체 유해성의 문제점을 가지고 있다. 따라서 본 연구에서는 NOX, SOX 동시처리 방식의 단점들을 보완하고자 고압분산기에서 생성된 마이크로버블과 환원제를 이용하여 비용절감 및 폐수처리 시 환경부하저감 가능성을 확인해 하고자 하였다. 분산기가 마이크로버블을 생성하는 것을 이미지 프로세싱과 ESR (electron spin resonance) 분석을 통해 확인하였으며, 마이크로버블만을 이용하여 온도에 따른 NOX, SOX 제거율 성능 테스트도 진행하였다. 뿐만 아니라 폐수를 저감하기 위해 환원제와 마이크로버블을 이용하여 습식으로 NOX 제거율 약 75%, SOX 제거율 99%를 달성하였다. 본 마이크로버블 시스템에 산화제를 함께 투여할 경우 NOX, SOX제거율 모두 99%이상을 달성 하였다. 이러한 연구 결과를 토대로 습식산화제거방식을 적용하는 시설의 단점이었던 비용 및 환경 문제를 해결함에 기여할 수 있을 것으로 기대 된다.

$RuO_2{\cdot}xH_2O$ 박막의 가스채색 현상을 이용한 수소검지 광센서 (Optical Hydrogen Sensor Based on Gasochromic $RuO_2{\cdot}xH_2O$ Thin Film)

  • 정현식;조현철;김경문
    • 한국수소및신에너지학회논문집
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    • 제16권1호
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    • pp.9-16
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    • 2005
  • We studied the electrochromic properties of hydrated amorphous ruthenium oxide ($RuO_2{\cdot}xH_2O$) thin films using in-situ Raman spectroscopy during electrochemical charging/discharging cycles. We have found that the principal effect of hydrogen insertion into $RuO_2{\cdot}xH_2O$ is reduction of $Ru^{4+}\;to\;Ru^{3+}$, and not formation of new bonds involving hydrogen. We compared the changes in the Raman spectrum of a gasochromic $Pd/RuO_2{\cdot}xH_2O$ film as it is exposed to hydrogen gas with that of electrochemical hydrogen insertion. We tested the changes in the optical transmission of the $Pd/RuO_2{\cdot}xH_2O$ film when exposed to hydrogen gas.

저압식 진공 침탄(LPC) 열처리 공정 기술 개발 (Development of Process Technology for Low Pressure Vaccum Carburizing)

  • 동상근;양제복
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.231-237
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    • 2004
  • Vacuum carburizing continues to gain acceptance as an alternative to atmosphere carburizing particularly in the car industry. The advantages of low-pressure carburization over atmospheric gas carburization is not only the creation of a surface entirely free of oxide and the environmentally friendly nature of these methods but also an improvement in deformation behaviour achieved by combining carburization with gas quenching, a reduction in batch times by increasing the carburization temperature, low gas and energy consumption and the prevention of soot to a large extent. In present study, an improved vacuum carburizing method is provided which is effective to deposit carbon in the surface of materials and to reduce cycle time. Also LPC process simulator was made to optimize to process controls parameters such as pulse/pause cycles of pressure pattern, temperature, carburizing time, diffusion time. The carburizing process was simulated by a diffusion calculation program, where as the model parameters are proposed with help the experimental results and allows the control of the carburizing process with good accordance to the practical results. Thus it can be concluded that LPC process control method based on the theoretical simulation and experimental datas appears to provide a reasonable tool for prototype LPC system.

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