• Title/Summary/Keyword: nParticle

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High Strength $Si_3N_4/SiC$ Structural Ceramics (고강도 $Si_3N_4/SiC$ 구조세라믹스에 관한 연구)

  • 김병수;김인술;장윤식;박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.30 no.12
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    • pp.999-1006
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    • 1993
  • Si3N4(p)-SiC(p) composites were prepared by gas pressure sintering at 190$0^{\circ}C$ for 1 hour. $\alpha$-SiC with average particle size of 0.48${\mu}{\textrm}{m}$ were dispersed from zero to 50vol% in $\alpha$-Si3N4 with average particle size of 0.5${\mu}{\textrm}{m}$. Y2O3-Al2O3 system was used as sintering aids. When 10vol% of SiC was added to Si3N4, optimum mechanical properties were observed; relative density of 98.8%, flextural strength of 930MPa, fracture toughness of 5.9MPa.m1/2 and hardness value of 1429kg/$\textrm{mm}^2$. Grain growth of $\beta$-Si3N4 was inhibited as the amount of added SiC was increased. SiC particles were found inside the $\beta$-Si3N4 intragrains in case of 10, 20 and 30vol%SiC added composites.

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A Study on Mobility Gradients and Phase Transitions in N-propyl-N,N-dimethylethanolamine Reaction (N-propyl-N,N-dimethylethanolamine 반응에서 유동성 변화와 상전이에 관한 연구)

  • Kim, Ki-Jun;Sung, Wan-Mo;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.165-169
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    • 2015
  • N-propyl-N,N-dimethylethanolamine was directly ultrasonicated in acidic water for 6 minute to give clear stock solutions. The catalytic hydrolysis of N-propyl-N,N-dimethylethanolamine was studied at $30{\sim}55^{\circ}C$ in the presence of uni-lamellar vesicle and mixture of uni- and multi-lamellar aggregates. The difference of rate between uni- and mixture was observed, where uni-lamellar reaction was more catalytic effect. The phase transition temperature of vesicle was $37{\sim}44^{\circ}C$. The particle size of multi-lamellar than that of uni-lamellar of biological membrane was measured more largely.

Evaluation on the Photodegradation Rate of NOx Using High Efficiency Visible-Light Responsive Photocatalysts (고효율 가시광 반응형 광촉매를 이용한 NOx의 광저감율 평가)

  • Cha, Ji An;An, Sang Hun;Cho, Eun hee;Kim, Tae Oh
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.165-172
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    • 2010
  • Titania is widely used as an effective photocatalyst for the photodegradation of environmental pollutants in air. In this study, novel N-doped $ZrO_2/TiO_2$ photocatalysts were synthesized via sol-gel method and characterized by UV-Vis spectrophotometer, transmission electron microscope, and X-ray diffractometer. N-doped $ZrO_2/TiO_2$ photocatalysts were nano-sized with an average particle size of about 20 nm. The XRD pattern of N-doped $ZrO_2/TiO_2$ photocatalysts showed both anatase and rutile phases. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was evaluated by degradation of NO under UV and visible light irradiation at various parameters such as amount of photocatalyst, concentration of NO, and intensity of light. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was effective for the enhancement of the degradation of NO and higher than that of $TiO_2$ photocatlysts under UV and visible light irradiation.

Effect of Mixed Gases on Decomposition Characteristic of CF4 by Non-Thermal Plasma (비열플라즈마를 이용한 CF4 분해에 미치는 혼합가스의 영향)

  • 박재윤;정장근;김종석;임근희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.6
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    • pp.543-550
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    • 2002
  • In this paper, the $CF_4$ decomposition rate and by-product were investigated for two simulated plasma reactors which are metal particle reactor and spiral wire reactors as a function of mixed gases. The $CF_4$ decomposition rate by plasma reactor with metal particle electrode had a gain of 20~25% over that by plasma reactor with spiral wire electrode. The $CF_4$ decomposition efficiency increases with increasing applied voltage up to the critical voltage for spark formation. The $CF_4$ decomposition efficiency of metal particle reactor was about 80% at AC 24kV. The $CF_4$ decomposition rate used Ar-$N_2$ as base gas was the highest among three base gases of $N_2$, $Ar-N_2$, air. The by-products of the $N_2$, $N_2Ar$ base as were similar, but in case of air base they were different.

A study of dielectric strength and insulating property for particle contamination Under SF6/N2 Mixture (혼합가스의 이물 존재시 절연 특성 연구)

  • Jeong, Dong-Hoon;Woo, Su-Youl;Seo, Kyoung-Bo;Kim, Jin-Ho
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1262-1263
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    • 2011
  • Sulfur hexafluoride is the most commly used insulation gas in electrical systems. Gas insulated systems are widely used in the electric power industry for transmission and distribution of electrical energy. When $SF_6$ was first discovered, the potential application was only considered for insulation because of good dielectric properties. But the widespread use of $SF_6$ gas by electric power and other industries has led to increase concentrations of $SF_6$ gas in the atmosphere. This concern as to possible effects on global warming because $SF_6$ is a potent greenhouse gas. That's why firstly we studied uniform and nonuniform field property by mixing $SF_6$ and N2 gas. This paper presents the dielectric strength and insulating property for particle contamination under $SF_6/N_2$ mixtures. Two types of mixed gases(50% $SF_6$_50%$N_2$, 20% $SF_6$_80%$N_2$) were applied. We performed tests for the length and shape of particle. Test gas pressure is from 0.3 to 0.7 Mpa. The study was conducted to develop environment-friendly insulating material for GIS that can reduce $SF_6$ gas and make a design criteria for mixtures.

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Effect of Non-thermal plasma Reactor construction by $CF_4$ decomposition ($CF_4$ 분해에 미치는 비열플라즈마 반응기 구조의 영향)

  • Kim, Sun-Ho;Park, Jae-Yun;Ha, Hyun-Jin;Hwang, Bo-Guk;Kim, Kwang-Soo;Rim, Geun-Hie
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.912-916
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    • 2002
  • In this paper, the $CF_4$ decomposition rate and by-product were investigated for a simulated two plasma reactors which are metal particle reactor and spiral wire reactor as function of mixed gases. The $CF_4$ decomposition rate by plasma reactor with metal particle electrode had a gain of 20~25[%] over that by plasma reactor with spiral wire electrode. The $CF_4$ decomposition efficiency increases with increasing applied voltage up to the critical voltage for spark formation. The $CF_4$ decomposition efficiency of metal particle reactor was about 80[%] at AC 24[kV]. The $CF_4$ decomposition rate used $Ar-N_2$ as base gas was the highest among three base gases of $N_2$, $Ar-N_2$, air. The by-products of the $N_2$, $Ar-N_2$ base as were similar, but in case of air base they were different.

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Treatment of ETA wastewater using GAC as particle electrodes in three-dimensional electrode reactor (활성탄 충진 3D 복극전기분해조를 이용한 ETA 처리)

  • Kim, Ran;Kim, Yu-Jin;Shin, Ja-Won;Kim, Jeong-Joo;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.2
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    • pp.241-249
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    • 2013
  • Ethanolamine (ETA) is widely used for alkalinization of water in steam cycles of nuclear power plants with pressurized water reactor. When ETA contained wastewater was released, it could increase COD and T-N. The treatment of the COD and T-N from ETA wastewater was investigated using the GAC as particle electrodes in three-dimensional electrode reactor (TDE). This study evaluated the effectiveness of GAC as particle electrode using different packing ratio at 300 V. The results showed that GAC-TDE could reduce ETA much more efficiently than ZVI-TDE at the mass ratio of GAC to insulator, 1:2. Additionally, The effect of applied electric potential to COD and T-N reduction was investigated. The results showed the high COD, T-N reduction and current efficiency at the low electric potential. Using the GAC-TDE will provide a better ETA reduction with reducing electrical potential dissipation.

A Study on the Influence of Substituting Cu Eine Particle for CuO on NiCuZn Ferrite (CuO 대신 Cu 미분말 치환이 NiCuZn Ferrite에 미치는 영향에 관한 연구)

  • Kim, Jae-Sik;Koh, Jae-Gui
    • Journal of the Korean Magnetics Society
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    • v.13 no.1
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    • pp.15-20
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    • 2003
  • Diffusion speed of Cu metal fine particle is fast better than CuO, so it will promote grain growth in sintering. In this paper, the influence on substituting Cu fine particle for CuO of NiCuZn ferrite with basic composition (N $i_{0.204}$C $u_{0.204}$Z $n_{0.612}$ $O_{1.02}$)F $e_{1.98}$ $O_{2.98}$ has been investigated with varying Cu/CuO ratio. The perfect spinel structure of sintered specimen at 90$0^{\circ}C$ was confirmed by the analysis of XRD patterns. The best condition was obtained when the ratio of Cu/CuO was 60%, and the permeability was 1100 and Ms was 87 emu/g in this condition. Cu has influenced on grain growth in sintering, substituting Cu fine particle for CuO could lower sintering temperature over the 3$0^{\circ}C$. After sintering, substituting Cu performed as good as CuO.s CuO.s CuO.

A Study on the Optimal Make of X-ray Ionizer using the Monte Carlo N-Particle Extended Code(II) (Monte Carlo N-Particle Extended Code를 이용한 연 X선 정전기제거장치의 최적제작에 관한 연구(II))

  • Jeong, Phil Hoon;Lee, Dong Hoon
    • Journal of the Korean Society of Safety
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    • v.32 no.6
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    • pp.29-33
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    • 2017
  • In order to solve this sort of electrostatic failure in Display and Semiconductor process, Soft X-ray ionizer is mainly used. Soft X-ray Ionizer does not only generate electrical noise and minute particle but also is efficient to remove electrostatic as it has a wide range of ionization. There exist variable factors such as type of tungsten thickness deposited on target, Anode voltage etc., and it takes a lot of time and financial resource to find optimal performance by manufacturing with actual X-ray tube source. Here, MCNPX (Monte Carlo N-Particle Extended) is used for simulation to solve this kind of problem, and optimum efficiency of X-ray generation is anticipated. In this study, X-ray generation efficiency was compared according to target material thickness using MCNPX and actual X-ray tube source under the conditions that tube voltage is 5 keV, 10 keV, 15 keV and the target Material is Tungsten(W). At the result, In Tube voltage 5 keV and distance 100 mm, optimal target thickness is $0.05{\mu}m$ and fastest decay time appears + decay time 0.28 sec. - deacy time 0.30 sec. In Tube voltage 10keV and distance 100 mm, optimal target Thickness is $0.16{\mu}m$ and fastest decay time appears + decay time 0.13 sec. - deacy time 0.12 sec. In the tube voltage 15 keV and distance 100 mm, optimal target Thickness is $0.28{\mu}m$ and fastest decay time appears + decay time 0.04 sec. - deacy time 0.05 sec.

The Removal of Si3N4 Particles from the Wafer Surface Using Supercritical Carbon Dioxide Cleaning (웨이퍼 표면의 Si3N4 파티클 제거를 위한 초임계 이산화탄소 세정)

  • Kim, Yong Hun;Choi, Hae Won;Kang, Ki Moon;Karakin, Anton;Lim, Kwon Teak
    • Clean Technology
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    • v.24 no.3
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    • pp.157-165
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    • 2018
  • In this study, the removal of $Si_3N_4$ particles from the surface of a silicon wafer was investigated by using supercritical carbon dioxide, the IPA co-solvent and cleaning additive chemicals. First, the solubility of several surfactants and binders in supercritical carbon dioxide solubility and particle dispersibility in the binders were evaluated in order to confirm their suitability for the supercritical cleaning process. Particle removal experiments were carried out with adjusting various process parameters and reaction conditions. The surfactants used in the experiment showed little particle removal effect, producing secondary contamination on the surface of wafers. On the other hand, 5 wt% (with respect to $scCO_2$) of the cleaning additive mixture of trimethyl phosphate, IPA, and trace HF resulted in 85% of particle removal efficiency after $scCO_2$ flowing for 4 minutes at $50^{\circ}C$, 2000 psi, and the flow rate of $15mL\;min^{-1}$.