• 제목/요약/키워드: nParticle

검색결과 1,373건 처리시간 0.032초

고강도 $Si_3N_4/SiC$ 구조세라믹스에 관한 연구 (High Strength $Si_3N_4/SiC$ Structural Ceramics)

  • 김병수;김인술;장윤식;박홍채;오기동
    • 한국세라믹학회지
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    • 제30권12호
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    • pp.999-1006
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    • 1993
  • Si3N4(p)-SiC(p) composites were prepared by gas pressure sintering at 190$0^{\circ}C$ for 1 hour. $\alpha$-SiC with average particle size of 0.48${\mu}{\textrm}{m}$ were dispersed from zero to 50vol% in $\alpha$-Si3N4 with average particle size of 0.5${\mu}{\textrm}{m}$. Y2O3-Al2O3 system was used as sintering aids. When 10vol% of SiC was added to Si3N4, optimum mechanical properties were observed; relative density of 98.8%, flextural strength of 930MPa, fracture toughness of 5.9MPa.m1/2 and hardness value of 1429kg/$\textrm{mm}^2$. Grain growth of $\beta$-Si3N4 was inhibited as the amount of added SiC was increased. SiC particles were found inside the $\beta$-Si3N4 intragrains in case of 10, 20 and 30vol%SiC added composites.

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N-propyl-N,N-dimethylethanolamine 반응에서 유동성 변화와 상전이에 관한 연구 (A Study on Mobility Gradients and Phase Transitions in N-propyl-N,N-dimethylethanolamine Reaction)

  • 김기준;성완모;이주엽
    • 한국응용과학기술학회지
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    • 제32권1호
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    • pp.165-169
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    • 2015
  • N-propyl-N,N-dimethylethanolamine의 용액을 만들기 위해 산성 조건 하에서 6분간 초음파처리하여 제조하였다. N-propyl-N,N-dimethylethanolamine 의 촉매 가수분해는 온도 $30{\sim}55^{\circ}C$에서 uni-lamellar vesicle과 uni-lamellar와 multi-lamellar가 뭉쳐진 혼합물에서 연구되었다. 이들의 차이는 촉매효과에 대해 multi-lamellar보다 uni-lamellar에서 영향이 크게 나타났다. Vesicle의 상전이 온도는 $37{\sim}44^{\circ}C$이며, multi-lamellar의 분자 입자의 크기는 uni-lamellar의 입자의 크기보다 크게 나타 났다.

고효율 가시광 반응형 광촉매를 이용한 NOx의 광저감율 평가 (Evaluation on the Photodegradation Rate of NOx Using High Efficiency Visible-Light Responsive Photocatalysts)

  • 차지안;안상훈;조은희;김태오
    • 한국입자에어로졸학회지
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    • 제6권4호
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    • pp.165-172
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    • 2010
  • Titania is widely used as an effective photocatalyst for the photodegradation of environmental pollutants in air. In this study, novel N-doped $ZrO_2/TiO_2$ photocatalysts were synthesized via sol-gel method and characterized by UV-Vis spectrophotometer, transmission electron microscope, and X-ray diffractometer. N-doped $ZrO_2/TiO_2$ photocatalysts were nano-sized with an average particle size of about 20 nm. The XRD pattern of N-doped $ZrO_2/TiO_2$ photocatalysts showed both anatase and rutile phases. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was evaluated by degradation of NO under UV and visible light irradiation at various parameters such as amount of photocatalyst, concentration of NO, and intensity of light. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was effective for the enhancement of the degradation of NO and higher than that of $TiO_2$ photocatlysts under UV and visible light irradiation.

비열플라즈마를 이용한 CF4 분해에 미치는 혼합가스의 영향 (Effect of Mixed Gases on Decomposition Characteristic of CF4 by Non-Thermal Plasma)

  • 박재윤;정장근;김종석;임근희
    • 한국전기전자재료학회논문지
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    • 제15권6호
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    • pp.543-550
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    • 2002
  • In this paper, the $CF_4$ decomposition rate and by-product were investigated for two simulated plasma reactors which are metal particle reactor and spiral wire reactors as a function of mixed gases. The $CF_4$ decomposition rate by plasma reactor with metal particle electrode had a gain of 20~25% over that by plasma reactor with spiral wire electrode. The $CF_4$ decomposition efficiency increases with increasing applied voltage up to the critical voltage for spark formation. The $CF_4$ decomposition efficiency of metal particle reactor was about 80% at AC 24kV. The $CF_4$ decomposition rate used Ar-$N_2$ as base gas was the highest among three base gases of $N_2$, $Ar-N_2$, air. The by-products of the $N_2$, $N_2Ar$ base as were similar, but in case of air base they were different.

혼합가스의 이물 존재시 절연 특성 연구 (A study of dielectric strength and insulating property for particle contamination Under SF6/N2 Mixture)

  • 정동훈;우수열;서경보;김진호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1262-1263
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    • 2011
  • Sulfur hexafluoride is the most commly used insulation gas in electrical systems. Gas insulated systems are widely used in the electric power industry for transmission and distribution of electrical energy. When $SF_6$ was first discovered, the potential application was only considered for insulation because of good dielectric properties. But the widespread use of $SF_6$ gas by electric power and other industries has led to increase concentrations of $SF_6$ gas in the atmosphere. This concern as to possible effects on global warming because $SF_6$ is a potent greenhouse gas. That's why firstly we studied uniform and nonuniform field property by mixing $SF_6$ and N2 gas. This paper presents the dielectric strength and insulating property for particle contamination under $SF_6/N_2$ mixtures. Two types of mixed gases(50% $SF_6$_50%$N_2$, 20% $SF_6$_80%$N_2$) were applied. We performed tests for the length and shape of particle. Test gas pressure is from 0.3 to 0.7 Mpa. The study was conducted to develop environment-friendly insulating material for GIS that can reduce $SF_6$ gas and make a design criteria for mixtures.

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$CF_4$ 분해에 미치는 비열플라즈마 반응기 구조의 영향 (Effect of Non-thermal plasma Reactor construction by $CF_4$ decomposition)

  • 김선호;박재윤;하현진;황보국;김광수;임근회
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.912-916
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    • 2002
  • In this paper, the $CF_4$ decomposition rate and by-product were investigated for a simulated two plasma reactors which are metal particle reactor and spiral wire reactor as function of mixed gases. The $CF_4$ decomposition rate by plasma reactor with metal particle electrode had a gain of 20~25[%] over that by plasma reactor with spiral wire electrode. The $CF_4$ decomposition efficiency increases with increasing applied voltage up to the critical voltage for spark formation. The $CF_4$ decomposition efficiency of metal particle reactor was about 80[%] at AC 24[kV]. The $CF_4$ decomposition rate used $Ar-N_2$ as base gas was the highest among three base gases of $N_2$, $Ar-N_2$, air. The by-products of the $N_2$, $Ar-N_2$ base as were similar, but in case of air base they were different.

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활성탄 충진 3D 복극전기분해조를 이용한 ETA 처리 (Treatment of ETA wastewater using GAC as particle electrodes in three-dimensional electrode reactor)

  • 김란;김유진;신자원;김정주;박주양
    • 상하수도학회지
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    • 제27권2호
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    • pp.241-249
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    • 2013
  • Ethanolamine (ETA) is widely used for alkalinization of water in steam cycles of nuclear power plants with pressurized water reactor. When ETA contained wastewater was released, it could increase COD and T-N. The treatment of the COD and T-N from ETA wastewater was investigated using the GAC as particle electrodes in three-dimensional electrode reactor (TDE). This study evaluated the effectiveness of GAC as particle electrode using different packing ratio at 300 V. The results showed that GAC-TDE could reduce ETA much more efficiently than ZVI-TDE at the mass ratio of GAC to insulator, 1:2. Additionally, The effect of applied electric potential to COD and T-N reduction was investigated. The results showed the high COD, T-N reduction and current efficiency at the low electric potential. Using the GAC-TDE will provide a better ETA reduction with reducing electrical potential dissipation.

CuO 대신 Cu 미분말 치환이 NiCuZn Ferrite에 미치는 영향에 관한 연구 (A Study on the Influence of Substituting Cu Eine Particle for CuO on NiCuZn Ferrite)

  • 김재식;고재귀
    • 한국자기학회지
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    • 제13권1호
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    • pp.15-20
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    • 2003
  • Cu 금속 미분말은 확산속도가 CuO 보다 CuO 보다 빠르고 소결시 입자성장을 촉진시키기 때문에 기본조성 (N $i_{0.204}$C $u_{0.204}$Z $n_{0.612}$ $O_{1.02}$)F $e_{1.98}$ $O_{2.98}$에 들어가는 CuO대신 Cu/CuO의 비를 변화시켜 가면서 Cu가 ferrite에 미치는 영향을 조사하였다. Cu를 CuO 대신 치환함으로써 90$0^{\circ}C$에서 완전한 Spinel구조를 가짐을 XRD pattern을 통하여 확인하였고, Cu/CuO 비가 60%일 때가 투자율 1100, Ms 87 emu/g의 최적조건을 얻었다. Cu는 소결시 확산속도를 증가시켜 입자성장에 영향을 주었으며, CuO대신 Cu의 치환은 저온에서 투자율이 개선됨을 확인하고 소결온도를 3$0^{\circ}C$이상 낮출 수 있었다. 소결이 끝난 후에는 CuO와 같은 거동을 하는 것으로 확인되었다.

Monte Carlo N-Particle Extended Code를 이용한 연 X선 정전기제거장치의 최적제작에 관한 연구(II) (A Study on the Optimal Make of X-ray Ionizer using the Monte Carlo N-Particle Extended Code(II))

  • 정필훈;이동훈
    • 한국안전학회지
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    • 제32권6호
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    • pp.29-33
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    • 2017
  • In order to solve this sort of electrostatic failure in Display and Semiconductor process, Soft X-ray ionizer is mainly used. Soft X-ray Ionizer does not only generate electrical noise and minute particle but also is efficient to remove electrostatic as it has a wide range of ionization. There exist variable factors such as type of tungsten thickness deposited on target, Anode voltage etc., and it takes a lot of time and financial resource to find optimal performance by manufacturing with actual X-ray tube source. Here, MCNPX (Monte Carlo N-Particle Extended) is used for simulation to solve this kind of problem, and optimum efficiency of X-ray generation is anticipated. In this study, X-ray generation efficiency was compared according to target material thickness using MCNPX and actual X-ray tube source under the conditions that tube voltage is 5 keV, 10 keV, 15 keV and the target Material is Tungsten(W). At the result, In Tube voltage 5 keV and distance 100 mm, optimal target thickness is $0.05{\mu}m$ and fastest decay time appears + decay time 0.28 sec. - deacy time 0.30 sec. In Tube voltage 10keV and distance 100 mm, optimal target Thickness is $0.16{\mu}m$ and fastest decay time appears + decay time 0.13 sec. - deacy time 0.12 sec. In the tube voltage 15 keV and distance 100 mm, optimal target Thickness is $0.28{\mu}m$ and fastest decay time appears + decay time 0.04 sec. - deacy time 0.05 sec.

웨이퍼 표면의 Si3N4 파티클 제거를 위한 초임계 이산화탄소 세정 (The Removal of Si3N4 Particles from the Wafer Surface Using Supercritical Carbon Dioxide Cleaning)

  • 김용훈;최해원;강기문;안톤커랴킨;임권택
    • 청정기술
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    • 제24권3호
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    • pp.157-165
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    • 2018
  • 본 연구에서는 초임계 이산화탄소와 공용매 첨가물을 이용하여 실리콘 웨이퍼 표면의 $Si_3N_4$ 파티클을 제거하는 기술을 조사하였다. 우선, 몇 가지 계면활성제와 첨가제에 관한 초임계 이산화탄소 용해도 및 파티클 분산성 평가를 통하여 초임계 공정에 대한 적합성을 확인하였다. 다양한 변수를 조정하여 파티클 세정 실험을 진행하여 최적의 제거 조건을 확립하였다. 실험에 사용된 계면활성제는 파티클 제거 효과가 떨어졌으며, 실험 후 이차 오염물이 형성됨을 확인하였다. 반면 trimethyl phosphate는 IPA공용매와 미량의 HF와 혼합된 세정 첨가제로서 초임계 이산화탄소에 5 wt%로 포함한 유체로 온도 $50^{\circ}C$, 압력 2000 psi에서 $15mL\;min^{-1}$의 유속으로 4분 간 세정한 결과, 85%의 파티클 제거 효율을 나타내었다.