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변성 전분-폴리락트산 블렌드의 상용성 및 물성 (Compatibilization and Properties of Modified Starch-Poly(lactic acid) Blend)

  • 이상환;김덕준;김지흥;이동현;심상준;남재도;계형산;이영관
    • 폴리머
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    • 제28권6호
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    • pp.519-523
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    • 2004
  • 폴리락트산과 상용성을 높이기 위해 전분에 무수 말레산을 그래프팅한 변성 전분을 제조하여 폴리락트산과 혼합하였다. DSC와 TGA 열적거동에서 폴리락트산/변성 전분 혼합체는 폴리락트산에서 관찰되는 172$^{\circ}C$에서의 용융 피크 외에 1$65^{\circ}C$에서 새로운 용융 피크가 관찰되었으며, 열분해 곡선에서는 폴리락트산/변성 전분 혼합체의 분해 온도가 보다 완만하게 감소되는 것으로 나타났다. 또한 기계적 강도의 측정에서는 폴리락트산/변성 전분이 폴리락트산/전분 혼합체와 비교하여 탄성률이 약 12% 증가하였으며, 이는 SEM 이미지에서 나타난 바와 같이 폴리락트산과 변성 전분의 계면 접착력이 향상되었기 때문으로 사료된다.

Electrochemistry and Determination of 1-Naphthylacetic Acid Using an Acetylene Black Film Modified Electrode

  • Huang, Wensheng;Qu, Wanyun;Zhu, Dazhai
    • Bulletin of the Korean Chemical Society
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    • 제29권7호
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    • pp.1323-1325
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    • 2008
  • The acetylene black (AB) was dispersed into water in the presence of dihexadecyl hydrogen phosphate (DHP) via ultrasonication, resulting in a stable and well-distributed AB/DHP suspension. After evaporation of water, an AB/DHP composite film-modified electrode was prepared. The electrochemical responses of $K_3$[Fe$(CN)_6$] at the unmodified electrode, DHP film-modified electrode and AB/DHP film-modified electrode were investigated. It is found that the AB/DHP film-modified electrode possesses larger surface area and electron transfer rate constant. Furthermore, the electrochemical behaviors of 1-naphthylacetic acid (NAA) were examined. At the AB/DHP film-modified electrode, the oxidation peak current of NAA remarkably increases. Based on this, a sensitive and convenient electrochemical method was proposed for the determination of NAA. The linear range is in the range from $4.0 {\times} 10^{-8}\;to\;5.0 {\times} 10^{-6}$ mol $L^{-1}$, and the detection limit is $1.0 {\times} 10^{-8}$ mol $L^{-1}$. Finally, this new sensing method was employed to determine NAA in several soil samples.

Phagocytic Uptake of Surface modified PLGA Microspheres Using Dendritic Cell

  • Kim, Ji-Seon;Lee, Young-Sung;Lee, Jung-Gil;Park, Jeong-Sook;Lee, Jong-Kil;Chung, Youn-Bok;Han, Kun
    • Journal of Pharmaceutical Investigation
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    • 제41권3호
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    • pp.185-190
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    • 2011
  • The purpose of this study was to evaluate the phagocytic uptake of surface modified PLGA microspheres containing ovalbumin (OVA) into dendritic cell. In order to find the most suitable formulation for targeted delivery to antigen presenting cells (APC), OVA was encapsulated by a double emulsion solvent evaporation method with three PLGA microspheres (PLGA 50:50, PLGA 75:25 and PLGA 85:15) and two surface modified microspheres by chitosan and sodium dodecyl sulfate (SDS). Physicochemical properties were evaluated in terms of size, zeta potential, encapsulation efficiency, different scanning calorimeter (DSC), x-ray diffraction, morphology, and OVA release test from microspheres. Phagocytic activity was estimated using dendritic cells and analyzed by fluorescence activated cell sorter (FACS). The result showed that zeta potential of PLGA particles was changed to positive by the chitosan modification. The release profile of chitosan modified PLGA microspheres exhibited sustained release after initial burst. The chitosan modified microspheres had higher phagocytic uptake than the other microspheres. Such physicochemical properties and phagocytic uptake studies lead us to conclude that chitosan modified microspheres is more suitable formulation for the targeted delivery of antigens to APC compared with the other microspheres.

A PMSM Driven Electric Scooter System with a V-Belt Continuously Variable Transmission Using a Novel Hybrid Modified Recurrent Legendre Neural Network Control

  • Lin, Chih-Hong
    • Journal of Power Electronics
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    • 제14권5호
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    • pp.1008-1027
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    • 2014
  • An electric scooter with a V-belt continuously variable transmission (CVT) driven by a permanent magnet synchronous motor (PMSM) has a lot of nonlinear and time-varying characteristics, and accurate dynamic models are difficult to establish for linear controller designs. A PMSM servo-drive electric scooter controlled by a novel hybrid modified recurrent Legendre neural network (NN) control system is proposed to solve difficulties of linear controllers under the occurrence of nonlinear load disturbances and parameters variations. Firstly, the system structure of a V-belt CVT driven electric scooter using a PMSM servo drive is established. Secondly, the novel hybrid modified recurrent Legendre NN control system, which consists of an inspector control, a modified recurrent Legendre NN control with an adaptation law, and a recouped control with an estimation law, is proposed to improve its performance. Moreover, the on-line parameter tuning method of the modified recurrent Legendre NN is derived according to the Lyapunov stability theorem and the gradient descent method. Furthermore, two optimal learning rates for the modified recurrent Legendre NN are derived to speed up the parameter convergence. Finally, comparative studies are carried out to show the effectiveness of the proposed control scheme through experimental results.

오차범위 분석을 통한 고정길이 modified Booth 곱셈기의 최대오차 감소 (Maximum Error Reduction for Fixed-width Modified Booth Multipliers Based on Error Bound Analysis)

  • 조경주;정진균
    • 대한전자공학회논문지SD
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    • 제42권10호
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    • pp.29-34
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    • 2005
  • 최대 양자화 오차는 W 비트 입력으로부터 W 비트의 곱을 출력하는 고정길이 곱셈기의 성능에 많은 영향을 준다. 본 논문에서는 고정길이 modified Booth 곱셈기의 오차범위를 분석한 후 최대오차를 줄이기 위해 추가해야 하는 칼럼 수를 결정하는 방법을 제안한다. 또한, 오차범위 분석방법이 reduced-width 곱셈기 디자인 시에도 적용할 수 있음을 보인다. 시뮬레이션을 통해 제안한 오차분석 방법이 고정길이 modified Booth 곱셈기의 실제 디자인에 유용하게 사용될 수 있음을 보인다.

건조과정에 있어서 폴리머 시멘트 모르터의 수분확산에 관한 연구 (A Study on te Water Diffusion of Polymer-Modified Mortars in Drying Process)

  • 조영국;소양섭
    • 콘크리트학회지
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    • 제8권5호
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    • pp.135-143
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    • 1996
  • 콘크리트 및 모르터중의 수분의 확산 거동은 탄성계수, 크리프, 건축수축 등의 역학적 성질에 큰 영향을 미친다. 일반적으로 건조과정에서 폴리머 시멘트 콘크리트와 모르터의 수분의 증발에 의한 중량감소는 내부의 폴리머 필름형성에 의한 보수효과로 보통 시멘트 콘크리트 및 모르터에 비해 월등히 적다. 본 연구는 폴리머 시멘트 모르터 내부의 수분의 확산 과정을 확인하기 위하여 3종류의 폴리머디스퍼션과 에폭시 수지를 사용한 폴리머 시멘트 모르터를 제조하여 건조조건에 따른 수분의 확산 정도를 확산계수로 평가하였다. 실험결과, 폴리머 시멘트 모르터의 수분확산은 보통 시멘트 모르터에 비하여 아주 적었으며 폴리머 시멘트비에 따라 감소하였다.

수분확산에 의한 폴리머 시멘트 모르터의 건조수축과 확산계수에 관한 연구 (A Study on the Dry Shrinkage and Moisture Diffusion Coefficient of Polymer-Modified Mortars by the Moisture Diffusion)

  • 조영국;소양섭
    • 콘크리트학회지
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    • 제8권5호
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    • pp.145-154
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    • 1996
  • 폴리머 시멘트 모르터는 보수성 및 방수성이 우수한 재료로서 모르터 내부의 수분의 확산거동 대한 연구는 중요하다. 본 연구에서는건조조건을 달리한 폴리머 시멘트 모르터의 수분확산에 영향을 미치는 상대습도와 내부함수율의 변화에 따른 수분의 확산계수와 건조수축과의 관계에 대해 고찰하였으며, 수분확산에 영향을 미치는 내부의 세공조직의 분포를 측정하였다. 본 실험결과, 폴리머 시멘트 모르터의 수분확산에 영향을 미치는 요인과 결과는 상호 상관관계를 나타내며, 건조수축과 수분확산계수는 보통 시멘트 모르터에 비해 아주 적었으며 상대습도, 폴리머 시멘트비 및 세공의 분포에 영향을 받는다.

$Y-{\Delta}$ 변압기 보호용 수정 전류차동 계전기 (Modified Current Differential Relay for $Y-{\Delta}$ Transformer Protection)

  • 김은숙;강용철
    • 대한전기학회논문지:전력기술부문A
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    • 제55권3호
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    • pp.95-101
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    • 2006
  • This paper proposes a modified current differential relay for $Y-{\Delta}$ transformer protection. The relay uses the same restraining current as a conventional relay, but the differential current is modified to compensate for the effects of the exciting current. A method to estimate the circulating component of the delta winding current is proposed. To cope with the remanent flux, before saturation, the core-loss current is calculated and used to modify the measured differential current. When the core then enters saturation, the initial value of the flux is obtained by inserting the modified differential current at the start of saturation into the magnetization cure. Thereafter, the core flux is then derived and used in conjunction with the magnetization curve to calculate the magnetizing current. A modified differential current is then derived that compensates for the core-loss and magnetizing currents. The performance of the proposed differential relay was compared against a conventional differential relay. Test results indicate that the modified relay remained stable during severe magnetic inrush and over-excitation, because the exciting current was successfully compensated. This paper concludes by implementing the relay on a hardware platform based on a digital signal processor. The relay does not require additional restraining signal and thus cause time delay of the relay.

Modified z-변환의 성질상의 해석적 문제점 (Analytic Problems of the Properties of the Modified z-Transform)

  • 정태상;장태규;이영운;김형준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
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    • pp.39-41
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    • 1996
  • While the z-transform method is a basic mathematical tool to relate the signals only at the sampling instants in analyzing and designing sampled-data control systems, the modified z-transform which is a variation of the z-transform is widely used to represent the details of continuous signals between the sampling instants. Regarding the modified z-transform method, some properties were established to relate the modified z-transform to the regular z-transform. This paper will show that these properties, in their current forms, cause some analytic problems, when they are applied to the signals with discontinuities at the sampling instants, which accordingly limit their applications significantly. In this paper, those analytic problems will be investigated, and the theorems of the modified z-transform will be revised by adopting a new notation so that those can be correctly interpreted and used without any analytic problems in the analysis of sampled data systems. Also some useful schemes of applying the modified z-transform will be developed.

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미생물 성장 공정에서의 기질 저해에 관한 modified Haldane 모델의 이론적 고찰 (Theoretical Consideration of the Modified Haldane Model of the Substrate Inhibition in the Microbial Growth Processes)

  • 황영보
    • 공업화학
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    • 제19권3호
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    • pp.277-286
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    • 2008
  • 본 논문은 미생물 성장 공정에서의 기질 저해에 관한 modified Haldane 모델의 이론적 유도를 다룬다. 생물학적 개념인 기질-수용체 복합체의 작동 메커니즘을 바탕으로 새로운 미생물학적 동특성인 N-중첩된 다중 기질 저해 모델의 유도와 더불어 일반화가 이론적으로 고찰되었는데, 이것은 효소 반응에서의 단순 기질 저해 메커니즘이 자연스럽게 확장된 것이다. 결과적으로, 본 기질 저해에 관한 modified Haldane 모델은 완전저해 기질농도라는 생물학적 상수를 포함하고 있는, 잘 설계된 4-파라메터 동특성 모델임이 밝혀졌다.