• Title/Summary/Keyword: metallic ion

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A Study on the Characteristics of DC Flashover with Floating Metallic Objects in Unipolar Ion Field (불평등 전계중에 금속구 및 금속침의 부유 물체가 존재하는 경우의 Flashover특성)

  • Seok, B.Y.;Huh, G.D.;Kim, K.S.;Cho, J.S.;Park, C.H.
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.469-471
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    • 1995
  • This paper describes the effect of floating metallic object on do flashover characteristics in all gap producing unipolar ion flow field. Needle-to-plane electrodes of 120mm in gap length were used as the main gap electrode and the tested metallic objects were spheres with the radius of 2,10 and 15mm or needles from 5 to 40mm long. The characteristics of flashover voltage vs. location of the floating object are different completely with the shape of the floating metal and polarity of the applied voltage.

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Ionic-to-Metallic Layer Transition in Cs Adsorption on Si(111)-(7$\times$7). Charge-State Selective Detection of Adsorbate by Cs+ Reactive Ion Scattering.

  • Han, Seung-Jin;Park, Sung-Chan;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.155-155
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    • 2000
  • Adsorption of alkali metals on a silicon surface has attracted much attention due to its importance in metal-semiconductor interface technology, In particular, the bonding nature of alkali metal to silicon substrate has been a focus of fundamental research efforts. We examined the adsorbed layer of Cs on a Si(111)-(7$\times$) surface by reactive ion scattering (RIS) of hyperthermal Cs+ beams. RIS from a Cs-adsorbed surface gives rise to Cs, representing pickup of surface Cs by Cs projectile. The Cs intensity is proportional to surface coverage of Cs at a high substrate temperature (473 K), while it varies anomalously with Cs coverage at low temperatures (130-170 K). This observation indicates that RIS selectively detects metallic Cs on surface, but discriminates ionic Cs. Transition from ionic to metallic Cs adlayer is driven by thermal diffusion of Cs and their clustering process.

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Adsorption of U(VI), Fe(II), Sm(III) Ions on OenNen-Styrene DVB Synthetic Resin (OenNen-Styrene DVB 합성수지에 의한 U(VI), Fe(II), Sm(III) 이온들의 흡착)

  • Lee, Chi-Young;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.3
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    • pp.77-87
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    • 2007
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 3%, and 5%-crosslinking and macro cyclic ligand of OenNen-$H_4$ by copolymerization method and the adsorption characteristics of uranium(VI), iron(II) and samarium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium ${UO_2}^{2+}>Fe^{2+}>Sm^{3+}$ ion. The adsorption was in order of 1%, 3%, and 5% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvent.

Adsorption of Metal Ions on OenNdien Resin (OenNdien수지에 의한 금속 이온의 흡착)

  • Kang Young-Shik;Rho Gi-Hwan;Kim Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.27-35
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    • 2005
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Adsorption Characteristic of U(VI), Cu(II), Dy(III) Ions Utilizing Nitrogen-Donator Synthetic Resin (질소-주게 합성수지를 이용한 U(VI), Cu(II), Dy(III) 이온들의 흡착특성)

  • Rho, Gi-Hwan;Kim, Joon-Tae;Kim, Hee-Joung
    • Journal of environmental and Sanitary engineering
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    • v.21 no.3 s.61
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    • pp.52-60
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    • 2006
  • The ion exchange resins have been synthesized from chlormethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, and 20%-crosslinking and macrocyclic ligand of cryptand 21 by copolymerization method and the adsorption characteristics of uranium(VI), copper(II) and dysprosium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, equilibrium time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium$(UO^{2+}_2)\;>\;copper(Cu^{2+})\;>\;dysprosium(Dy^{3+})$ ion. The adsorption was in order of 1%, 2%, and 20% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Study on Chemical Characterization of $PM^{10}$ Observed in Korean Peninsula, 1998 ~ 2001

  • Bang, So-Young;Oh, S.N.;Choi, J.C.;Choi, B.C
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.61-64
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    • 2003
  • This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

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Behavior of Some Metallic Ions in the Process of Ginseng Extracts Preparation (인삼(人蔘) Extract 제조과정(製造過程)중 무기금속(無機金屬)이온의 동태(動態))

  • Cho, Yung-Hyun;Lee, Joung-Sook
    • Korean Journal of Food Science and Technology
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    • v.15 no.2
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    • pp.133-134
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    • 1983
  • Some metallic ions such as copper, manganese, iron, zinc and cadmium in ginseng extract, originated from white ginseng, were determined by atomic absorption spectrophotometry. The extracts were prepared with water, 35% ethanol, 50% ethanol or 75% ethanol solution followed by filtration or centrifugation. Greater amounts of metallic ions were found in the solution filtrated by filter paper (Toyo No. 5A) or by filter cloth than in that of centrifugation. The residual amount of metallic ions in the extract decreased with increasing concentration of ethanol. The percentages of each metallic ion in ginseng extracts on the basis of original amount of metallic ions were as follows: Cu, 10.4-31.9%, Fe,5.1-19.0%, Mn,3.0-12.2% Zn,7.4-12.0%, Cd,5.9-11.8%.

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Characteristics of Metallic and Ionic Concentration in Fine Particle during Haze Days in Busan (부산 지역 연무 발생일의 미세먼지 중 금속과 이온 성분 농도 특성)

  • Jeon, Byung-Il
    • Journal of Environmental Science International
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    • v.26 no.6
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    • pp.767-778
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    • 2017
  • This research investigates the characteristics of metallic and ionic elements in $PM_{10}$ and $PM_{2.5}$ on haze day and non-haze day in Busan. $PM_{10}$ concentration on haze day and non-haze day were 85.75 and $33.52{\mu}g/m^3$, respectively, and $PM_{2.5}$ on haze day and non-haze day were 68.24 and $23.86{\mu}g/m^3$, respectively. Contribution rate of total inorganic water-soluble ion to $PM_{10}$ mass on haze day and non haze day were 58.2% and 61.5%, respectively, and contribution rate of total water-soluble ion to $PM_{2.5}$ mass on haze day and non haze day were 58.7% and 64.7%, respectively. Also, contribution rate of secondary ion to $PM_{10}$ mass on haze day and non haze day were 52.1% and 47.5%, respectively, and contribution rate of secondary ion to $PM_{2.5}$ mass on haze day and non haze day were 54.4% and 53.6%, respectively. AC (anion equivalents)/CE (cation equivalents) ratio of $PM_{10}$ mass on haze day and non haze day were 1.09 and 1.0, respectively, and AC/CE ratios of $PM_{2.5}$ mass on haze day and non haze day were 1.12 and 1.04, respectively. Also, SOR (Sulfur Oxidation Ratio) of $PM_{10}$ mass on haze day and non haze day were 0.32 and 0.17, respectively, and SOR of $PM_{2.5}$ on haze day and non haze day were 0.30 and 0.15, respectively. Lastly, NOR (Nitrogen Oxidation Ratio) of $PM_{10}$ on haze day and non haze day were 0.17 and 0.08, respectively, and NOR of $PM_{2.5}$ on haze day and non haze day were 0.13 and 0.06, respectively.

A Study on the Characteristics of High Energy Nitrogen ion Implanted CdS Thin Films (고에너지 질소 이온 주입된 CdS 박막 특성에 관한 연구)

  • 이재형;홍석주;양계준
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.4
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    • pp.712-718
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    • 2003
  • The effects of nitrogen ion implantation on vacuum evaporated cadmium sulphide (CdS) thin films were investigated by X-ray diffraction, optical transmittance spectra, and Raman scattering studies. The as-deposited CdS films have a hexagonal structure with preferential (0 0 2) orientation. Formation of Cd metallic clusters was observed in ion implanted films from the XRD patterns. The band gap of N+ implanted films decreased, whereas the optical absorption coefficient values increased with the increase of implantation dose. The Raman peak position appeared at 299 cm-1 and the FWHM increased with the ion dose. A decrease in the area of Raman peak of CdS Al(LO) mode is seen on implantation.

Preparation of Ampholyte Grafted Hollow-fiber Membrane and Its Adsorption Characteristic on Metallic Ions (양성전해질 고정막의 제조 및 그것의 금속이온 흡착 특성)

  • Choi, Hyuk-Jun;Park, Sang-Jin;Kim, Min
    • Membrane Journal
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    • v.20 no.2
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    • pp.151-158
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    • 2010
  • This paper presents the synthesis of ampholyte immobilized hollow-fiber membranes and adsorption characteristic of metallic ions. This is prepared by radiation induced grafting polymerization of an epoxy group containing Glycidyl methacrylate (GMA) onto an existing polyethylene porous hollow-fiber membrane. Ampholyte ion-exchanged alkalic group, $-NH_2$ (amine function) of Taurine (TAU) is reacted with glycidyl of GMA for the synthesis of stable membrane. However, Sodium sulfite (SS) membrane is also prepared by making chemical bonds with GMA of porous hollow-fiber membrane for the comparison of adsorption characteristic of metallic ions. These are called as TAU and SS membranes, respectively. It is shown that TAU membrane shows a steady flux, 0.9 m/h regardless of the density of TAU, while the flux of SS membrane decreases rapidly as the density of $SO_3H$ group increases. SS membrane showed a negligible flux. TAU membrane with the density 0.8 mmol/g shows the amount of metallic ions adsorbed in the following order, Cu > Cd > Mg > Sb > Pb. In general, TAU membrane with high density and reaction time showed the high amount of metallic ions adsorbed and flux.