Journal of environmental and Sanitary engineering (환경위생공학)

Korean Society for Environmental Sanitary Engineers (대한환경위생공학회)
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Adsorption of Metal Ions on OenNdien Resin

OenNdien수지에 의한 금속 이온의 흡착

  • Kang Young-Shik (Dept. of Environmental Administration, Kwangju Health College) ;
  • Rho Gi-Hwan (Dept. of Environmental Administration, Kwangju Health College) ;
  • Kim Joon-Tae (Dept. of Environmental Administration, Kwangju Health College)
  • 강영식 (광주보건대학 환경행정과) ;
  • 노기환 (광주보건대학 환경행정과) ;
  • 김준태 (광주보건대학 환경행정과)
  • Published : 2005.09.01
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Abstract

The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Keywords

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