• 제목/요약/키워드: magnetic absorption

검색결과 341건 처리시간 0.021초

Effects of strain on the optical and magnetic properties of Ce-doped ZnO

  • Xu, Zhenchao;Hou, Qingyu;Guo, Feng;Jia, Xiaofang;Li, Cong;Li, Wenling
    • Current Applied Physics
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    • 제18권12호
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    • pp.1465-1472
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    • 2018
  • The magnetic and optical properties of Ce-doped ZnO systems have been widely demonstrated, but the effects of different strains of Ce-doped ZnO systems remain unclear. To solve these problems, this study identified the effects of biaxial strain on the electronic structure, absorption spectrum, and magnetic properties of Ce-doped ZnO systems by using a generalized gradient approximation + U (GGA + U) method with plane wave pseudopotential. Under unstrained conditions, the formation energy decreased, the system became stable, and the doping process became easy with the increase in the distances between two Ce atoms. The band gap of the systems with different strains became narrower than that of undoped ZnO without strain, and the absorption spectra showed a red shift. The band gap narrowed, and the red shift became weak with the increase of compressive strain. By contrast, the band gap widened, and the red shift became significant with the increase of tensile strain. The red shift was significant when the tensile strain was 3%. The systems with -1%, 0%, and 1% strains were ferromagnetic. For the first time, the magnetic moment of the system with -1% strain was found to be the largest, and the system showed the greatest beneficial value for diluted magnetic semiconductors. The systems with -3%, -2%, 2%, and 3% strains were non-magnetic, and they had no value for diluted magnetic semiconductors. The ferromagnetism of the system with -1% strain was mainly caused by the hybrid coupling of Ce-4f, Ce-5d, and O-2p orbits. This finding was consistent with Zener's Ruderman-Kittel-Kasuya-Yosida theory. The results can serve as a reference for the design and preparation of new diluted magnetic semiconductors and optical functional materials.

Electron Spin Resonance (ESR) and Microwave Absorption Studies of Superparamagnetic Iron Oxide Nanoparticles (SPIONs) for Hyperthermia Applications

  • Choi, Yong-Ho;Yi, Terry;Kim, Do-Kyung
    • 한국세라믹학회지
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    • 제48권6호
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    • pp.577-583
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    • 2011
  • Stabilized biocompatible superparamagnetic iron oxide nanoparticles (SPIONs) were prepared by controlled coprecipitation method for hyperthermia application. ESR measurements determined that all of the interactions in the individual SPIONs (1 nm and 11 nm) were antiferromagnetic in nature because the ions contributed to the magnetization with a range of magnetic moments. In-situ monitoring of the temperature increment was performed, showing that the microwave absorption rate of the SPIONs was dispersed in an appropriate host media (polar or non-polar solvents) during microwave irradiation. Microwave absorption energy rates and heat loss of SPIONs in solvent were calculated by non-linear data fitting with an energy balance equation. The microwave absorption rates of SPIONs dispersed in solvent linearly increases when the concentration of SPIONs increases, implying that the microwave absorption rate can be tunable by changing the concentration of SPIONs.

ME 소자의 저주파 등가회로 모델링 (Electric Circuits Modeling of Magnetoelectric Bulk Composites in Low Frequency)

  • 정수태;류지구
    • 한국전기전자재료학회논문지
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    • 제26권7호
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    • pp.515-521
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    • 2013
  • Magnetoelectric(ME) bulk composites with PZT-PNN-PZN/$Fe_2O_4$ were prepared by using a conventional ceramic methods and investigated on the ME voltage vs frequency of ac magnetic fields. We made the electric equivalent circuits by using the Maxwell-Wagner model and simulated the frequency dependence of ME voltage in low frequency region. ME devices were described by a series of two equivalent circuits of piezoelectric and magnetic, which have the relaxation time ${\tau}$ due to the interaction between ME device and load resistor. Equivalent circuit of piezoelectric material is independent of frequency. However ferrite magnetic materials have Debye absorption and dipolar dispersion, whose equivalent circuit is a function of frequency. Therefore we suggest the resistance in the equivalent circuit is proportion to $1+{\omega}^2{\tau}^2$ and the capacitance is in inverse proportion to $1+{\omega}^2{\tau}^2$ in the magnetic materials.

Electronic structure studies of Co-substituted FINEMET alloys by x-ray absorption spectroscopy

  • Chae, K.H.;Gautam, S.;Song, J.H.;Kane, S.N.;Varga, L.K.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.377-377
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    • 2010
  • FINEMET type nanocrystalline materials synthesized by controlled crystallization of amorphous ribbons[1] exhibit excellent soft magnetic properties making them attractive for technological applications. Present work reports the electronic structure studies of Co-substituted FINEMET to get information on the effect of successive Co substitution on local environment around Fe and Co atom by using near edge x-ray absorption fine structure (NEXAFS) and x-ray magnetic circular dichroism (XMCD) measurements. NEXAFS spectroscopy and XMCD measurements have been carried out at Fe $L_{3,2}$ and Co $L_{3,2}$-edges to investigate the chemical states and electronic structure of FINEMET [$(Fe_{100-x}Co_x)_{78}Si_9Nb_3Cu_1Ba$](0$L_{3,2}$-edge reveal that Fe is in 2+ state and in tetrahedral symmetry with other elements. The magnetic properties exhibiting soft magnetic behavior[2] are discussed on the basis of the electronic structure studied through XMCD.

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자기공명영상장치에서 전자파흡수율 분석 (Analysis of Specific Absorption Rate in Magnetic Resonance Imaging)

  • 한재복;홍성훈;최남길;성호진
    • 한국콘텐츠학회논문지
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    • 제13권2호
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    • pp.308-313
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    • 2013
  • 본 연구는 자기공명영상장치의 특성변수인 숙임각(flip angle), 반복시간(repetition time, TR), 에코시간(echo time, TE)을 사용하여 전자파흡수율(specific absorption rate, SAR)을 알아보고자 하였다. 연구대상은 체중 10 kg부터 90 kg까지를 대상으로 하여 동일한 검사기법을 적용하였고, 매개변수의 변화에 따른 평균 SAR 및 peak SAR 값을 측정하였다. 체중에 따른 SAR는 TE에서 변화는 없지만 숙임각이 커지고 TR이 짧을수록 증가하였다. SAR 값은 두부 허용 기준치 범위에 포함이 되었고 분절별 체중에 따른 영상의 신호 대 잡음비(signal to noise ratio, SNR)는 체중이 증가함에 따라 SNR은 증가하지는 않았다. 본 결과를 바탕으로 적절한 특성변수를 사용하여 다양한 대조도와 SNR을 얻어 진단의 가치를 높일 수 있을 것이다.

X-선 자기 원형 이색성 (X-Ray Magnetic Circular Dichroism)

  • 김재영
    • 한국자기학회지
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    • 제20권5호
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    • pp.201-205
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    • 2010
  • X-선 자기 원형 이색성 측정은 자성물질을 구성하는 원소별 자기적 성질의 측정 및 궤도 자기 모멘트와 스핀 자기 모멘트를 구별하여 측정할 수 있다는 장점으로 인해 여러 가지 자성 신물질 및 다양한 기능성 자성 다층 박막의 연구에 많이 이용되어 왔다. 이 글에서는 이러한 X-선 자기 원형 이색성 현상의 원리 및 실험 방법 등을 설명하겠다. 또한 몇 가지 X-선 자기 원형 이색성을 이용한 최근 몇 가지 연구도 소개하려 한다.

기능성기를 지닌 고분자 자성체를 이용한 수용액 중 납이온 추출

  • 서형석;최규찬;나인욱;황경엽
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.175-176
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    • 2004
  • To develope of efficient method for decontaminating of lead ions from industrial wastewater, treatment of aqueous lead solution with magnetic beads was investigated. Immobilization of carboxyl groups on tile surface of magnetic beads was carried out to introduce chelate effect between lead ions and beads. Experiments were performed with lead solutions and magnetic beads at pH 6. Lead ions were extracted during 1 hour, After extraction, magnetic beads were separated from water by outer magnetic force and the solution was analysed by atomic absorption spectroscopy (AAS). Over 90 % of lead ions could be removed from aqueous solution after beads application. This result indicate that magnetic beads can be used as a efficient method for removing lead ions from industrial wastewater.

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Fabrication of Double-Doped Magnetic Silica Nanospheres and Deposition of Thin Gold Layer

  • Park, Sang-Eun;Lee, Jea-Won;Haam, Seung-Joo;Lee, Sang-Wha
    • Bulletin of the Korean Chemical Society
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    • 제30권4호
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    • pp.869-872
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    • 2009
  • Double-doped magnetic particles that incorporated magnetites into both the surface and inside the silica cores were fabricated via the sol-gel reaction of citrate-stabilized magnetites with silicon alkoxide. Double-doped magnetic particles were easily fabricated and exhibited an higher magnetism in comparison to the singledoped magnetic particles that were prepared by the erosion of surface-deposited magneties from double-doped magentic particles. Thin gold layer was formed over magnetic silica nanospheres via nanoseed-mediated growth of gold clusters. The plasmon-derived absorption bands of double-doped magnetic silica-gold nanoshells were more broadened and shifted down by ca. 20 nm as compared to those of single-doped magnetic silicagold nanoshells, which were attributed to not only the surface scattering of incident light due to relatively rough surafce morphology, but also heterogeneous permittivity of dielectric cores due to surface-deposited magnetites.

Ultrathin Metamaterial for Polarization Independent Perfect Absorption and Band-pass Filter

  • Zhang, Xu;Gong, Zhijie
    • Journal of the Optical Society of Korea
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    • 제19권6호
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    • pp.665-672
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    • 2015
  • We demonstrate an ultrathin metamaterial for polarization independent perfect absorption as well as a band-pass filter (BPF) which works at a higher frequency band compared to the perfect absorption band. The planar metamaterial is comprised of three layers, symmetric split ring resonators (SSRRs) at the front and structured ground plane (SGP) at the back separated by a dielectric layer. The perfect metamaterial absorber (MA) can realize near 100% absorption due to high electromagnetic losses from the electric and/or magnetic resonances within a certain frequency band. The thickness of the structure is only 1/28 of the maximum absorption wavelength.

A New All-optical Flip-flop Based on Absorption Nulls of an Injection-locked FP-LD

  • Lee, Hyuek Jae
    • Current Optics and Photonics
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    • 제4권5호
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    • pp.405-410
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    • 2020
  • A new all-optical flip-flop (AOFF) method based on the absorption nulls of an injection-locked Fabry-Perot laser diode (FP-LD) in transverse magnetic (TM) mode is proposed and experimentally demonstrated. For the set and reset operations of the AOFF, injection locking and the destructive minus of beating in transverse electric (TE) mode are used. The absorption nulls on the TM mode are modulated according to the operations, and then non-inverted (Q) and inverted (${\bar{Q}}$) outputs can be obtained simultaneously. Thanks to the use of several absorption nulls, the proposed AOFF can achieve multiple outputs with extinction ratios of more than 15 dB. Even though the experiment is demonstrated at 100 Mbit/s, the results of previous experiments using the injection of a CW holding beam imply that the operation speed can increase to 10 Gbit/s.