• Title/Summary/Keyword: lower amine

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Absorption of Methyl Mercaptan into Aqueous Diethanolamine Solutions (Diethanolamine 수용액에서의 Methyl Mercaptan의 흡수)

  • Park Moon-Ki
    • Journal of Environmental Science International
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    • v.14 no.12
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    • pp.1177-1183
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    • 2005
  • The kinetics of the reaction of methyl mercaptan into aqueous diethanolamine were studied over a range in temperature ($20^\~60{\circ}C$) and amine concentrations (0-40 $wt\%$) using a wetted-sphere absorber. The physicochemical properties needed to interpret the data are the solubility and diffusivity of methyl mercaptan in the aqueous diethanolamine solution. The density and the viscosity were obtained and correlated in the experimental range. The Wilke Chang equation was applied to estimate the diffusion coefficient. The enhancement factor was found to be high temperature is below than low temperature. It means the absorption rate with chemical reaction is lower than the physical absorption rate.

Seasonal Analysis of Odorous Compounds Emitted From the Chemical Plant (계절별 악취물질의 배출량 분석 및 평가에 관한 연구)

  • Cho, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.27-32
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    • 2007
  • In this study, the concentrations of offensive odorous compounds seasonally emitted from the chemical plant at Chongju industrial complex in Korea were determined by the analytical methods of gas chromatography, high performance liquid chromatography and uv/vis spectroscopy. The kinds of offensive odorous compounds examined are formaldehyde, acetaldehyde, butyl aldehyde, propion aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide, dimethyl disulfide, trimethyl amine and ammonia. The seasonally emission levels of all odorous compounds except dimethyl sulfide at 13 sampling points of plant were lower than those of the regulation standard levels of the industrial complex in Korea. The levels were the highest in June, and lowest in December. The propion aldehyde and iso-valeric aldehyde in June and December, butyl aldehyde in December, and n-valeric aldehyde were not detected in all the three seasons at any sampling points of the plant examined. But in June, dimethyl sulfide was emitted up to 16 times than that of the regulation level.

Analysis of Offensive Odorous Compounds Emitted From the Chemical Plants (화학공장에서 배출되는 악취규제물질의 분석 및 평가)

  • Choi, Jae-Sung;Kim, Jae-Woo
    • Journal of Environmental Science International
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    • v.16 no.1
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    • pp.33-38
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    • 2007
  • The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous com-pounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.

Comparison of Coverage-Dependent Adsorption Structures of Alanine and Leucine on Ge(100): Bonding Configuration and Adsorption Stability

  • Park, Yeong-Chan;Yang, Se-Na;Kim, Jeong-Won;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.215-215
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    • 2011
  • The bonding configuration and adsorption stability of alanine and leucine adsorbed on Ge(100)-2${\times}$1 surface were investigated and compared using core-level photoemission spectroscopy (CLPES) and density functional theory (DFT) calculations. The bonding configuration, stability, and adsorption energies were evaluated for two different coverage levels. In both cases, the C 1s, N 1s, and O 1s core-level spectra at a low coverage (0.30 ML) indicated that the carboxyl and amine groups participated in bonding with the Ge(100) surface in an "O-H dissociated-N dative bonded structure". At high coverage levels (0.60 ML), both this structure and an "O-H dissociation bonded structure" were present. As a result, we found that alanine adsorbs more easily (lower adsorption energy) than leucine on Ge(100) surfaces due to less steric hindrance of side chain.

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The Effect of Short-Term Administration of Excessive Amount of Garlic on Hematology in HK Phenotype Jindo-Dog (단기간 과량의 마늘투여가 HK phenotype 진도견의 혈액상에 미치는 영향)

  • 진태원;김홍태;장우석;오태호;송재찬;정규식;박승춘;이근우
    • Journal of Veterinary Clinics
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    • v.18 no.3
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    • pp.232-236
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    • 2001
  • It has been known that garlic, one of the essential ingredient in korean food, has a hypotensive effect. and it is reported that they lower the level of triglycerides, cholesterol and glucose in blood. Especially, the sulfur containing amine acid and the derivatives of the garlic has the counteracting effect to heavy metals. Nowadays, the garlic is known for its efficiency for the various kinds of cancer, neoplasms, hypertension, arteriosclerosis and apoplexy. But, it is reported that the intake of the excessive amount of garlic causes hemolytic anemia recently. The hemolytic anemia is more severe especially in HK phenotype dogs which has a Na-K-ATPase activity. Therefore, this study was performed to examine the effect on the blood of the HK phenotype Jindo dogs when administered the excessive amount of garlic. HK phenotype group showed the significant decrease on RBC, WBC, PCV, Hb, MCV, MCHC, GSH, Met-Hb but LK phenotype group didn't show the significant decrease.

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ON NONLINEAR ELLIPTIC EQUATIONS WITH SINGULAR LOWER ORDER TERM

  • Marah, Amine;Redwane, Hicham
    • Bulletin of the Korean Mathematical Society
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    • v.58 no.2
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    • pp.385-401
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    • 2021
  • We prove existence and regularity results of solutions for a class of nonlinear singular elliptic problems like $$\{-div\((a(x)+{\mid}u{\mid}^q){\nabla}u\)=\frac{f}{{\mid}u{\mid}^{\gamma}}{\text{ in }}{\Omega},\\{u=0\;on\;{\partial}{\Omega},$$ where Ω is a bounded open subset of ℝℕ(N ≥ 2), a(x) is a measurable nonnegative function, q, �� > 0 and the source f is a nonnegative (not identicaly zero) function belonging to Lm(Ω) for some m ≥ 1. Our results will depend on the summability of f and on the values of q, �� > 0.

Seismic response of pipes under the effect of fluid based on exact solution

  • Liu, Yanbing;Khadimallah, Mohamed Amine;Behshad, Amir
    • Earthquakes and Structures
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    • v.22 no.4
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    • pp.431-437
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    • 2022
  • One of the best choice for transportation of oil and gas at the end of rivers or seas is concrete pipelines. In this article, a concrete pipe at the end of river is assumed under the earthquake load. The Classic shell theory is applied for the modelling and the corresponding motion equations are derived by energy method. An external force induced by fluid around the pipe is asssumed in the final motion equations. For the solution of motion equations, the differential quadrature method (DQM) and Newmark method are applied for deriving the dynamic deflection of the pipe. The effects of various parameters including boundary conditions, fluid and length to thickness ratio are presented on the seismic response of the concrete pipe. The outcomes show that the clamped pipe has lower dynamic deflection with respect to simply pipe. In addition, with the effect of fluid, the dynamic defelction is increased significantly.

Seismic response of pipes under the effect of fluid based on exact solution

  • Liu, Yanbing;Khadimallah, Mohamed Amine;Behshad, Amir
    • Earthquakes and Structures
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    • v.22 no.5
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    • pp.439-445
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    • 2022
  • One of the best choice for transportation of oil and gas at the end of rivers or seas is concrete pipelines. In this article, a concrete pipe at the end of river is assumed under the earthquake load. The Classic shell theory is applied for the modelling and the corresponding motion equations are derived by energy method. An external force induced by fluid around the pipe is asssumed in the final motion equations. For the solution of motion equations, the differential quadrature method (DQM) and Newmark method are applied for deriving the dynamic deflection of the pipe. The effects of various parameters including boundary conditions, fluid and length to thickness ratio are presented on the seismic response of the concrete pipe. The outcomes show that the clamped pipe has lower dynamic deflection with respect to simply pipe. In addition, with the effect of fluid, the dynamic defelction is increased significantly.

Potential probiotics activity of Bacillus spp. from traditional soybean pastes and fermentation characteristics of Cheonggukjang (전통장류유래 Bacillus spp.의 프로바이오틱스 활성과 청국장 발효 특성)

  • Ryu, Myeong Seon;Yang, Hee-Jong;Kim, Jin Won;Jeong, Su-Ji;Jeong, Seong-Yeop;Eom, Jeong-Seon;Jeong, Do-Youn
    • Food Science and Preservation
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    • v.24 no.8
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    • pp.1168-1179
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    • 2017
  • In this study, we tried to screen the Bacillus strain having safety probability by isolation of strains from traditional fermented food, measurement of probiotic properties, and the fermentative characteristics of Cheonggukjang. We isolated 400 Bacillus-like isolates from traditional fermented foods. Selected strains examined on the prevalent characteristic such as extracellular enzyme and antibacterial activities, and their safety probability was confirmed by biogenic amine productivity, hemolytic, and harmful substances and enzyme productivity. We selected the 5 strains by analysis of biogenic amine, antibacterial and B. cereus toxic associated gene. Five selected strains were examined on cell surface hydrophobicity, and bile and acid tolerance, and we selected the SRCM100730 as the final strain. SRCM100730 was confirmed B. amyloliquefaciens by 16S rRNA sequencing, and named the B. amyloloquefaciens SRCM100730 (KCCM11966P). Finally, we manufactured Cheonggukjang using SRCM100730 for confirmation of fermentation properties. Manufactured Cheonggukjang did not contain B. cereus, and showed that ${\gamma}$-PGA and extracellular enzyme activities were superior to commercial Chunggukjang. Amino nitrogen content was 544.02 mg% and 26 free amino acid were detected, and the bitterness-related amino acid content was lower than commercial Cheonggukjang. Especially, the amount of GABA was 3 fold higher than commercial Cheonggukjang. These results suggest that SRCM100730 have high availability in commercial probiotics market and fermented food industry.

Efficiency of Hurdle Technology Applied to Raw Cured Meat (Si-Raw)Processing

  • Chen, Ming-Tsao;Lin, Young-Sun;Tsai, Hung-Tsung;Kuo, Hsiu-Lan
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.11
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    • pp.1646-1652
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    • 2002
  • Si-Raw is a raw cured meat (raw, cured meat fermented with steamed rice) produced by the aboriginal people of Taiwan. In order to prevent food poisoning or intoxication from botulism, new methods of monitoring the production base on hurdle technology were investigated. New methods investigated incorporated citric acid, sodium hypophosphite, Monascus anka mash, plum paste or lactic acid bacteria inoculum added separately to meat with steamed rice and salt to lower the Aw (water activity) and pH values of the products to control the microbial growth. Results showed that anaerobic bacterial counts, lactic acid bacterial counts and aerobic bacterial counts for the products of all treatments were less than $10^6$, $10^5$ and $10^2cfu/g$, respectively. Sodium chloride content of all products was above 5.46%, water activity was below 0.939 and pH value was below 4.27. IMP was lower and ATP and hypoxanthine were higher. ATP concentrations were higher in the samples which contained the anka mash. Result of sensory panel test indicated that most people preferred the products with added sodium hypophosphite. Except for the fact that the content of tryptamine in the sample with Monascus anka mash was higher, the amine concentrations for all treatments were lower than those of other fermented meat products. The amino acid nitrogen content was higher in the product made from raw meat treated with citric acid, but lower in the other products. Neither Clostridium botulinum nor Trichinella spiralis were detected in any of the treatments. The result may indicate that hurdle technology is effective for hygiene and safe producing Si-Raw.