• Title/Summary/Keyword: long term stability

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A Review on Zeolite-based Ceramic Membrane for Oil/Water Separation (기름/물 분리를 위한 제올라이트 기반의 세라믹 분리막에 대한 총설)

  • Lee, Joo Yeop;Rajkumar, Patel;Kim, Jong Hak
    • Membrane Journal
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    • v.32 no.2
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    • pp.83-90
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    • 2022
  • Wastewater from refineries and petroleum plant lead to severe environmental pollution. There are various existing processes applied for oily water treatment, but membrane-based technology is one of the most efficient methods. Polymeric membranes prepared from organic materials for the separation of oil in water often face chronic problem of membrane fouling. Inorganic membranes are considered to be more efficient due to longer lifetime than organic membranes. Zeolite membranes have better chemical stability and long-term recyclability. The presence of hydrophilicity enhances the water flux of membrane. Ceramic membranes prepared from zeolites are another efficient class of inorganic membranes applied for oil water separation. This review is focused on oily wastewater separation based on zeolite membrane which classified into two categories, i) neat zeolite and ii) zeolite composites with other materials.

Ag2Se Modified TiO2 Heterojunction with Enhanced Visible-Light Photocatalytic Performance

  • Zhu, Lei;Tang, Jia-Yao;Fan, Jia-Yi;Sun, Chen;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.31 no.12
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    • pp.657-664
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    • 2021
  • To build a highly active photocatalytic system with high efficiency and low cast of TiO2, we report a facile hydrothermal technique to synthesize Ag2Se-nanoparticle-modified TiO2 composites. The physical characteristics of these samples are analyzed by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray analysis, transmission electron microscopy and BET analysis. The XRD and TEM results show us that TiO2 is coupled with small sized Ag2Se nanoplate, which has an average grain size of about 30 nm in diameter. The agglomeration of Ag2Se nanoparticles is improved by the hydrothermal process, with dispersion improvement of the Ag2Se@TiO2 nanocomposite. Texbrite BA-L is selected as a simulated dye to study the photodegradation behavior of as-prepared samples under visible light radiation. A significant enhancement of about two times the photodegradation rate is observed for the Ag2Se@TiO2 nanocomposite compared with the control sample P25 and as-prepared TiO2. Long-term stability of Ag2Se@TiO2 is observed via ten iterations of recycling experiments under visible light irradiation.

Investigating the Trends of Research for the Small Business Owners (소상공인 연구 동향 분석)

  • Bang, Mi-Hyun;Lee, Young-Min
    • The Journal of the Korea Contents Association
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    • v.22 no.7
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    • pp.73-80
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    • 2022
  • In this study, prior studies of 280 small business owners in Korea over the past two decades were comprehensively analyzed through keyword network and LDA topic modeling analysis, and overall views and trends in academia were examined. As core keywords, "sales" and "protection," which conflict with each other but are essential for stable and sustainable growth were selected, and 7 topics (Topic 1: start-up, topic 2: digital, topic 3: tax system, topic 4: capability, topic 5: coexistence, topic 6: regulation, and topic 7: funding) were drawn up. Based on the results of the analysis, the need to improve digital maturity for the continued growth and development of small business owners was raised, and the response at the pan-ministerial level and the stability of the performance of functions that can survive even after the new administration to solve the economic damage problems facing small business owners were suggested. In addition, attention to the long-term, speed, detail, and direction of government support in a new way, and a flexible approach to the negative way in which pre-allowance and post-regulation is given were suggested.

The effectiveness of an early intervention program based on electronic games in developing the visual perception of children with intellectual disabilities within the age group 2-5 years

  • Felemban, Bashayer Muhammed;Alqudah, Derar Mohammed
    • International Journal of Computer Science & Network Security
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    • v.22 no.10
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    • pp.322-332
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    • 2022
  • The current research aimed to ascertain the effectiveness of the early intervention program based on electronic games in developing the visual perception of children with intellectual disabilities within the age group of (2-5) years, using the quasi-experimental approach with one group, and the study sample consisted of (11) children with disabilities. Simple and medium intellectuals enrolled in the early intervention program at the Successful Communication Center for Day Care in Makkah Al-Mukarramah and were deliberately selected. To achieve the research objectives, the researchers prepared and applied the visual perception scale after ensuring its validity and stability. Three electronic games were also designed and applied to the sample for (17) sessions. The results showed the effectiveness of the electronic games program in developing the visual perception of children with intellectual disabilities within the age group (2-5) years and maintaining this improvement over time. Where the results showed that there were statistically significant differences at the level (α = 0.05) between the grades of the group children in the pre and post-measurements on the visual perception skills scale for children with intellectual disabilities in the post-measurement after applying the program, in favor of the post measurement. The results also showed that there were no statistically significant differences at the level (α = 0.05) between the grades of the group children in the two post and follow-up measurements on the visual perception skills scale for children with intellectual disabilities in the follow-up measurement which indicates the long-term impact of the program. The researchers recommend the necessity of activating educational programs based on various electronic games to develop the visual perception of children with intellectual disabilities and employ them effectively in the educational process for children with intellectual disabilities.

Mo,Cu-doped CeO2 as Anode Material of Solid Oxide Fuel Cells (SOFCs) using Syngas as Fuel

  • Diaz-Aburto, Isaac;Hidalgo, Jacqueline;Fuentes-Mendoza, Eliana;Gonzalez-Poggini, Sergio;Estay, Humberto;Colet-Lagrille, Melanie
    • Journal of Electrochemical Science and Technology
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    • v.12 no.2
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    • pp.246-256
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    • 2021
  • Mo,Cu-doped CeO2 (CMCuO) nanopowders were synthesized by the nitrate-fuel combustion method aiming to improve the electrical and electrochemical properties of its Mo-doped CeO2 (CMO) parent by the addition of copper. An electrical conductivity of ca. 1.22·10-2 S cm-1 was measured in air at 800℃ for CMCuO, which is nearly 10 times higher than that reported for CMO. This increase was associated with the inclusion of copper into the crystal lattice of ceria and the presence of Cu and Cu2O as secondary phases in the CMCuO structure, which also could explain the increase in the charge transfer activities of the CMCuO based anode for the hydrogen and carbon monoxide electro-oxidation processes compared to the CMO based anode. A maximum power density of ca. 120 mW cm-2 was measured using a CMCuO based anode in a solid oxide fuel cell (SOFC) with YSZ electrolyte and LSM-YSZ cathode operating at 800℃ with humidified syngas as fuel, which is comparable to the power output reported for other SOFCs with anodes containing copper. An increase in the area specific resistance of the SOFC was observed after ca. 10 hours of operation under cycling open circuit voltage and polarization conditions, which was attributed to the anode delamination caused by the reduction of the Cu2O secondary phase contained in its microstructure. Therefore, the addition of a more electroactive phase for hydrogen oxidation is suggested to confer long-term stability to the CMCuO based anode.

Case Studies of Indirect Coupled Behavior of Rock for Deep Geological Disposal of Spent Nuclear Fuel (사용후핵연료 심층처분을 위한 암석의 간접복합거동 연구사례)

  • Hoyoung, Jeong;Juhyi, Yim;Ki-Bok, Min;Sangki, Kwon;Seungbeom, Choi;Young Jin, Shin
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.411-434
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    • 2022
  • In deep geological disposal concept for spent nuclear fuel, it is well-known that rock mass at near-field experiences the thermal-hydraulic-mechanical (THM) coupled behavior. The mechanical properties of rock changes during the coupled process, and it is important to consider the changes into the analysis of numerical simulation and in-situ tests for long-term stability evaluation of nuclear waste disposal repository. This report collected the previous studies on indirect coupled behaviors of rock. The effects of water saturation and temperature on some mechanical properties of rock was considered, while the change in hydraulic conductivity of rock due to stress was included in the indirect coupled behavior.

Effect of LiCoO2-Coated Cathode on Performance of Molten Carbonate Fuel Cell

  • Kim, Dohyeong;Kim, Hyung Tae;Song, Shin Ae;Kim, Kiyoung;Lim, Sung Nam;Woo, Ju Young;Han, Haksoo
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.112-119
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    • 2022
  • Molten carbonate fuel cells (MCFCs) are environmentally friendly, large-capacity power generation devices operated at approximately 650℃. If MCFCs are to be commercialized by improving their competitiveness, their cell life should be increased by operating them at lower temperatures. However, a decrease in the operating temperature causes a reduction in the cell performance because of the reduction in the electrochemical reaction rate. The cell performance can be improved by introducing a coating on the cathode of the cell. A coating with a high surface area expands the triple phase boundaries (TPBs) where the gas and electrolyte meet on the electrode surface. And the expansion of TPBs enhances the oxygen reduction reaction of the cathode. Therefore, the cell performance can be improved by increasing the reaction area, which can be achieved by coating nanosized LiCoO2 particles on the cathode. However, although a coating improves the cell performance, a thick coating makes gas difficult to diffuse into the pore of the coating and thus reduces the cell performance. In addition, LiCoO2-coated cathode cell exhibits stable cell performance because the coating layer maintains a uniform thickness under MCFC operating conditions. Therefore, the performance and stability of MCFCs can be improved by applying a LiCoO2 coating with an appropriate thickness on the cathode.

Analysis of Rock Surface Roughness and Chemical Species Generation by Freeze-Thaw Experiments (동결융해 실험을 통한 암석 표면 거칠기 및 화학종 생성에 관한 분석)

  • Choi, Junghae
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.299-311
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    • 2022
  • Rocks exposed to the surface are subject to long-term weathering, and such effects weaken their engineering stability. Especially as weathering progresses, the surface of rocks will be changed by weathering, and such surface changes will affect the engineering safety of the rock mass. In addition, the chemical species produced in the weathered rock have a direct effect on the surrounding environment or on the structure. In areas where rocks are exposed, such as mining areas, chemical species produced by weathering can have a serious impact on the surrounding natural environment. In this study, accelerated weathering experiments using freeze/thaw system were conducted on rocks that had already been weathered and fresh rocks, and surface changes of each rock were observed with confocal laser scanning microscope (CLSM), and chemical species were analyzed using IC/ICP-MS. As the weathering progressed, the surface roughness decreased, and the amount of chemical species produced increased. The results of this study can be used as basic data for evaluating engineering/environmental safety in areas where rocks are exposed.

Comparative Analysis of Final Consolidation Settlement by Degree of Consolidation in Soft Soils of Yeongam-Haenam Areas (영암-해남 연약지반의 압밀도 변화에 따른 최종침하량 비교분석)

  • Kim, Tae-Wan;Nam, Geon;Kim, Jae-Hong
    • Journal of the Korean Geotechnical Society
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    • v.39 no.9
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    • pp.25-33
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    • 2023
  • To effectively improve soft soils, it is necessary to perform ground behavior characteristics and stability management through measurement activities when embankment of structures on soft soils is conducted. However, there are many differences between the actual ground behavior and the initial design plan. To address this issue, this study analyzed the measured settlement in the Yeongam-Haenam areas using the Hyperbolic method to predict the settlement based on the measurement data. From the completion time of the embankment in the target area, the final settlement was predicted through the change in the degree of consolidation by the measurement period. Furthermore, the final settlement according to the change in degree of consolidation was compared and analyzed through finite element analysis and field measurement.

Expression and Characterization of the Human Lactoferrin in the Milk of Transgenic Mice

  • Z. Y. Zheng;Y. M. Han;Lee, K. K.
    • Proceedings of the Korean Society of Developmental Biology Conference
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    • 2003.10a
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    • pp.85-85
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    • 2003
  • Human lactoferrin (hLF) is an 80 kDa iron-binding glycoprotein that is expressed in high concentration in milk and in lesser amount in the secondary or specific granules of neutrophils and in plasma, LF is classically considered to be related to the binding, transport, and storage of iron. The transgenic mice carrying the human hLF gene in conjunction with the bovine $\beta$-casein promoter produced the human hLF in their milk during lactation. To screen transgenic mice, PCR was carried out using chromosomal DNA extracted from tail or toe tissues. In this study, stability of germ line transmission and expression of hLF were monitored up to generation Fl7 of a transgenic line. When female mouse of generation F9 was crossbred with normal male, generation F9 to Fl7 mice showed similar transmission rates ($66.0 \pm 12.57%, 42.0 \pm 14.98%, 72.2 \pm 25.45%, 50.0 \pm 16.70%, 65.7 \pm 6.45%, 48.6 \pm 14.65%, 54 1 \pm 18 11%, 57.8 \pm 16.16% and 48.6 \pm 20.66$, respectively), implying that the hLF gene can be transmitted stably up to long term generation in the transgenic mice For ELISA analysis, hLF expression levels were determined with an hLF ELISA kit in accordance with the supplier's protocol. Expression levels of human hLF from milk of generation F9 to Fl3 mice were $ 3.2 \pm 0.69 mg/ml, 3.1 \pm 0.81 mg/ml, 4.6 \pm 1.38 mg/ml, 3.1 \pm 0.42 mg/ml, and 4.5 \pm 1,48 mg/ml$, respectively. These expression levels were lower than that of founder (6.6 mg/$m\ell$) mouse. We concluded that transgenic mice faithfully passed the transgene on their progeny and successively secreted target proteins into their milk through several generations.

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