• Title/Summary/Keyword: liquid mixture

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INFLUENCE OF THE EVAPORATOIN OF LIQUIDS OF DENTAL CEMENTS ON THE PROPERTIES OF HARDENED CEMENTS (치과용 시멘트 용액의 증발이 경화된 시멘트의 성질에 미치는 영향)

  • Kim, Hyang-Kyung;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.22 no.1
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    • pp.156-169
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    • 1997
  • This study was designed to evaluate the influences of evaporation of liquid of dental cements by drying during long term using. Zinc phosphate cement, polycarboxylate cement, and glass ionomer cement were used, and evaluated the properties as follows; consistency, setting time, film thickness, solubility, and compressive strength according to the ADA specification. The specimens of control group were made by mixing the newly opened liquid using the powder-liquid ratio recommended by the manufacturer, and the specimens of ES groups were made by mixing the 10% evaporated liquid by drying with the powder-liquid ratio recommeded by the manufacturer, and the specimens of EM group were made by mixing the 10% evaporated liquid with the powder-liquid ratio modified for standard consistency. The following conclusions were drawn ; 1. The viscosity of mixture of all kinds of cements were increased by the evaporation of liquid, especially the viscosity of glass ionomer cement were influenced significantly. 2. The amount of liquid should be increased to get a standard consistency at the using of evaporated liquid of cement, the most significant increase of liquid amount was required on Ketac-Cem. 3. The setting times were increased at both cases of mixing of evaporated liquid with powder - liquid ratio recommended by manufacturer or modifided through consistency test. 4. At an experimental group of mixing of the evaporated liquid with powder-liquid ratio recommended by manufacturer, solubility was decreased and film thickness was increased. 5. By the result of evaporation of cement liquid, the compressive strength of polycarboxylate cement was increased slightly and it of glass ionomer cement was increased, however, by the increase of amount of liquid to be possible to manipulate the compressive strength were decreased.

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Process Analysis for Rheology Forming Considering Flow and Solidification Phenomena in Lower Solid Fraction (저고상율 소재의 유동 및 응고현상을 고려한 레올로지 성형공정해석)

  • Jung, Young-Jin;Cho, Ho-Sang;Kang, Chung-Gil
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.9
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    • pp.156-164
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    • 2001
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocity and temperature fields during rheology forming process, the earth governing equation correspondent to the liquid and solid region are adapted. Therefore, each numerical models considering the solid and liquid region existing within the semi-solid material have been developed to predict the deflect of rheology forming gnarls. The Arbitrary Boundary Maker And Cell (ABMAC) method is employed to solve the two-phase flow model of the Navier-Stokes equation. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity. The liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

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Separation of Two Amino Acids by Microemulsion Bulk Liquid Membrane

  • Salabat, Alireza;Sanij, Fereshteh Dehghani
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3387-3390
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    • 2012
  • In this research work the potentialities of microemulsion bulk liquid membrane for the selective transport of L-tryptophan (L-Trp) and L-tyrosine (L-Tyr) are investigated at 298.15 K. Reversed micelle formed by sodium bis(2-ethylhexyl)sulfosuccinate (AOT) in dichloroethane, was used as mobile carrier to transport amino acids between a source and a receiving aqueous phase. The effects of pH, surfactant concentration and initial amino acid concentration on the extraction efficiency and transfer rate of the amino acids were studied. It is verified that for a mixture of two amino acids, L-Trp can be extracted selectively by using this type of the bulk liquid membrane with optimized condition.

Liquid Crystal Droplet Patterns to Monitor Catalase Activity at Femtomolar Levels

  • Yoon, Stephanie;Jang, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2704-2710
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    • 2014
  • Catalase (CAT) decomposes hydrogen peroxide that is toxic to the body. In this study, simple and sensitive detector has been developed for observing catalase activity using liquid crystal droplet system. Microscale LC droplet patterns are formed by spreading aldehyde-doped nematic liquid crystal on pre-treated glass slides. When hydrogen peroxide is added, aldehyde is oxidized and amphiphiles are formed. Dodecanoates cause the pattern to transit from bright to dark as they self-assemble to form a carboxyalte monolayer at the interface. When a drop of pre-incubated CAT and hydrogen peroxide mixture is placed onto the pattern, bright fan-shape is observed. This planar optical appearance indicates that catalase has decomposed hydrogen peroxide. Compared to the detectors that have been previously developed, this system is more sensitive with detection limit of 1fM. This research suggests further studies to be on LC droplet patterning to develop highly sensitive and methodologically simple sensors for various chemicals.

Process Analysis for Rheo-Forming of Aluminum Materials (알루미늄재료의 Rheo-forming을 위한 성형공정해석)

  • Seo P. K.;Jung K. Y.;Jung Y. S.;Kang C. G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.124-128
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    • 2001
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum ahoy has been studied Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The unposed mathematical model is applied to the die shape of the two type. To calculate the velocities and temperature fields during rheology forming process, the each governing equation correspondent to the liquid and solid region are adapted. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity.

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Pretilt Angle Properties of Mixture Nematic Liquid crystal for Mobile Information Device (휴대용 통신단말에 사용되는 혼합액정계에서의 프리틸트각 특성에 관한 연구)

  • Han, Jeongmin;Seo, Daeshik
    • Journal of Satellite, Information and Communications
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    • v.10 no.1
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    • pp.67-70
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    • 2015
  • We studied the state of the dual liquid crystal (LC) alignment which displays both homeotropic and homogeneous alignment on blended polyimide (PI) layer. The research was conducted using rubbing method at different imidizing temperatures and the blended PI was made using homeotropic PI having an alkyl side chain and homogeneous PI without the side chain. The uniform LC alignments were achieved, and have thermal stability. The results of contact angles were similar to that of pretilt angles.

Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode

  • Kim, Kyungmin;Jung, Yongju;Kim, Seok
    • Carbon letters
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    • v.15 no.3
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    • pp.187-191
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    • 2014
  • This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate ($PYR_{14}BF_4$) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate ($TEABF_4$) as a common salt. Using the $PYR_{14}BF$ ionic liquid as additive produced higher ionic conductivity in the electrolyte and lower interface resistance between carbon and electrolyte, resulting in improved capacitance. The chemical and electrochemical stability of the electrolyte was measured by ionic conductivity meter and linear sweep voltammetry. The electrochemical analysis between electrolyte and carbon electrode was examined by cyclic voltammetry and electrochemical impedance spectroscopy.

Electrically controllable polymer-dispersed liquid crystal (전기적 스위칭이 가능한 고분자 분산형 액정 제작 및 동적 홀로그램 기록 특성)

  • 성기영;경천수;이영락;최병철;곽종훈;최옥식;이윤우
    • Korean Journal of Optics and Photonics
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    • v.10 no.6
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    • pp.494-499
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    • 1999
  • We report on the results of holographic transmission grating that can be controlled by the applied AC electric field. We have fabricated a polymer-dispersed liquid crystal material that composed of multifunctional acrylate monomer blended with the liquid crystal mixture E7. To investigate an electro-optic properties of fabricated HPDLC, diffraction efficienties (DE) are measured as a fuction of applied electric field and density of liquid crystal. Maximum DE of about 70% is obtained about 30 wt% of LC concentration at a zero field. We have also shown that optical image was recorded in the tllm, and then the reconstructive image was switchable with the applied electric fields. ields.

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Study of Retention in Micellar Liquid Chromatography on a C18 Column on the Basis of Linear Solvation Energy Relationships

  • Tian, Minglei;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.29 no.5
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    • pp.979-984
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    • 2008
  • In this study, 8 solutes (aniline, caffeine, p-cresol, ethyl benzene, methylparaben, phenol, pyridine, and toluene) have been tested in terms of linear solvation energy relationships (LSER). Several micellar liquid chromatography (MLC) systems using cationic surfactant cetyltrimethylammonium bromide (CTAB) and a mixture of water with (methanol, n-propanol, and n-butanol) modifiers were characterized using the LSER solvation parameter model. The effects of the surfactant and modifier concentration on the retention in MLC were discussed. LSER model had demonstrated high potential to predict retention factors with high squared correlation coefficients ($r^2$ > 0.99). A comparison of predicted and experimental retention factors suggests that LSER formalism is able to reproduce adequately the experimental retention factors of the solutes studied in the different experimental conditions investigated. This model is a helpful tool to understand the solute-surfactant interactions and evaluate the retention characteristic of micellar liquid chromatography.

An Experimental Study of Vapor-Liquid Equilibrium for HFC12S+Propane Refrigerant Mixtures (HFC125+Propane 혼합냉매의 기-액 평형에 관한 실험적 연구)

  • 강준원;박영무;유재석;이종화
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.7
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    • pp.563-571
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    • 2003
  • The forty vapor-liquid equilibrium data of the binary system, HFC125+Propane, were measured between 273.15 and 313.15 K at 10 K interval and the composition range 0.2∼0.75, respectively. Experiments were performed in a circulation type apparatus in which the vapor phase was forced through the liquid phase. The composition at equilibrium were mea-sured by gas chromatography, and its response was calibrated using gravimetrically prepared mixtures. Vapor-liquid equilibrium data were calculated by using CSD equation of state and compared with the experimental data.