• Title/Summary/Keyword: lead aerosol

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High Energy Density Dielectric Ceramics Capacitors by Aerosol Deposition (상온 분사 공정을 이용하여 제조한 고에너지 밀도 세라믹 유전체 커패시터)

  • Hyunseok Song;Geon Lee;Jiwon Ye;Ji Yun Jung;Dae-Yong Jeong;Jungho Ryu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.2
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    • pp.119-132
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    • 2024
  • Dielectric ceramic capacitors present high output power density due to the fast energy charge and discharge nature of dielectric polarization. By forming dense ceramic films with nano-grains through the Aerosol Deposition (AD) process, dielectric ceramic capacitors can have high dielectric breakdown strength, high energy storage density, and leading to high power density. Dielectric capacitors fabricated by AD process are expected to meet the increasing demand in applications that require not only high energy density but also high power output in a short time. This article reviews the recent progress on the dielectric ceramic capacitors with improved energy storage properties through AD process, including energy storage capacitors based on both leadbased and lead-free dielectric ceramics.

Fabrication of Piezoelectric PZT Thick Film by Sol-gel Process (Sol-Gel 법에 의한 압전 PZT 후막의 제조)

  • Park, Jong-whan;Bang, Kook-soo;Park, Chan
    • Journal of Ocean Engineering and Technology
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    • v.29 no.1
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    • pp.94-99
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    • 2015
  • Lead zirconate titanate (PZT) thick films with thicknesses of ㎛ were fabricated on silicon substrates using an aerosol deposition method. A PZT powder solution was prepared using a sol-gel process. The average diameters (d50) obtained were 1.67, 1.98, and 2.40μm when the pyrolysis temperatures were 300℃, 350℃, and 450℃ respectively. The as-deposited film had a uniform microstructure without any cracks or pores. The as-deposited films on silicon were annealed at a temperature of 700℃. The 20-㎛-thick PZT film showed good adherence between the PZT film and substrate, with no tearing observed in the conventional solid phase process. This was probably because the presence of pores produced from organic residue during annealing relieved the residual stresses in the deposited film.

Anti-bacterial properties and safety evaluation of disinfectant using Dendropanax morbifera (Hwangchil) extract for passenger cabin in the subway (지하철 객실 적용을 위한 황칠 추출물 소독제의 항균특성 및 안전성 평가)

  • Bui, Vu Khac Hoang;Park, Jae-Seok;Lee, Young-Chul
    • Particle and aerosol research
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    • v.18 no.2
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    • pp.37-50
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    • 2022
  • Due to the syndrome coronavirus 2 (SARS-CoV-2) pandemic, the subway passenger cabin should be continuously sterilized. However, a disinfectant such as chlorine is toxic and can lead to different issues to human health. In this paper, we introduced a novel disinfectant based on natural product (Dendropanax morbifera extract). Via ultra-high performance liquid chromatography - mass spectrometer (UHPLC-MS), different compounds from Dendropanax morbifera extract showed antivirus potentials. Antimicrobial experiments confirmed that the air-disinfectant containing Dendropanax morbifera can eliminate harmful microorganisms including Gram (-), Gram (+), and yeast within 5 mins. The as-prepared air-disinfectant also showed high antivirus activity against H1N1, HRV, and EV71. Deodorization test also indicates that the as-prepared air-disinfectant can lower the harmful gas such as ammonia and trimethylamine in the atmosphere. To evaluate the potential of air-disinfectant containing Dendropanax morbifera in practical applications, different safety tests including acute oral toxicity, acute skin irritation, and eye irritation were conducted. Results showed that the as-prepared disinfectant did not negatively affect tested animals during these safety investigations.

Gas ebullition associated with biological processes in radioactively contaminated reservoirs could lead to airborne radioactive contamination

  • E.A. Pryakhin;Yu.G. Mokrov;A.V. Trapeznikov;N.I. Atamanyuk;S.S. Andreyev;A.A. Peretykin;K. Yu. Mokrov;M.A. Semenov;A.V. Akleyev
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4204-4212
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    • 2023
  • Background: Storage reservoirs of radioactive waste could be the source of atmospheric pollution due to the efflux of aqueous aerosol from their water areas. The main mechanism of formation of aqueous aerosols is the collapse of gas bubbles at the water surface. In this paper, we discuss the potential influence of biological factors on gas ebullition in the water areas of the radioactively contaminated industrial reservoirs R-9 (Lake Karachay) and R-4 (Metlinsky pond) of the Mayak PA. The emission of the released non-dissolved gases captured with gas traps in reservoir R-9 was (88-290) ml/m2 per day (2015) and in reservoir R-4 (270-460) ml/m2 per day (2016). The analysis of gas composition in reservoir R-4 (60% methane, 35% nitrogen, 2.4% oxygen, 1.5% carbon dioxide) confirms their biological origin. It is associated with the processes of organic matter destruction in bottom sediments. The major source of organic matter in bottom sediments is the dying phytoplankton developing in these reservoirs. Conclusion: The obtained results form the basis to set a task to quantify the relationship between the phytoplankton development, gases ebullition and radioactive atmosphere contamination.

Electrical properties of piezoelectric PZT thick film by aerosol deposition method (에어로졸 증착법에 의한 압전 PZT 후막의 전기적 특성)

  • Kim, Ki-Hoon;Bang, Kook-Soo;Park, Dong-Soo;Park, Chan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.6
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    • pp.239-244
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    • 2015
  • Lead zirconate titanate (PZT) thick films with thickness of $10{\sim}20{\mu}m$ were fabricated on silicon substrate by aerosol deposition method. As-deposited films on silicon were annealed at the temperatures of $700^{\circ}C$. The electrical properties of films deposited by PZT powders were characterized using impedance analyzer and Sawyer-Tower circuit. The PZT powder was prepared by both conventional solid reaction process and sol-gel process. The remanent polarization, coercive field, and dielectric constant of the $10{\mu}m$ thick film with solid reaction process were $20{\mu}C/cm^2$, 30 kV/cm and 1320, respectively. On the other hand, the PZT films by sol-gel process showed a poor dielectric constant of 635. The reason was probably due to the presence of pores produced from organic residue during annealing.

Fabrication of Nano-sized ZnO Colloids from Spray Combustion Synthesis (SCS) (분무연소합성(SCS)법에 의한 나노크기 산화아연(ZnO) 콜로이드의 제조)

  • Lee, Sang-Jin;Lee, Sang-Won;Jun, Byung-Sei
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.76-80
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    • 2004
  • Nano-sized ZnO colloids were prepared by use of spray combustion method. for combustion reaction, $Zn(NO_3)_2{\cdot}6H_2O$ and $CH_6N_4O$ were employed as an oxidizer and a fuel. Exothermic peak was shown at $230^{\circ}C$ by DTA/TGA, and it was considered as a combustion reaction followed by ignition of the precursor mixture. In case of spray combustion method, because insufficient contents of molecules and radicals generated from precursor droplets may lead an incomplete igmition, the ignition temperature of combustion chamber was chosen at $500^{\circ}C$. For diminishing aerosol coagulation, the droplet number concentration was reduced by filter media. The fluid was laminar with 2.5 seconds of aerosol residence time. The synthesized colloids had spherical shape with 180 nanometer size, and the crystalline phase was ZnO with hexagonal structure.

Determination of Pb and Cd in Rain Waters by the Coprecipitation Pre-concentration technique (공침 선농축법에 의한 강수속의 Pb와 Cd의 정량분석)

  • 노세원;송기형;박용남
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.4
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    • pp.265-270
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    • 1993
  • Trace amount of heavy metals in rain waters were determined after preconcentration by coprecipitaion technique. Indium was selected as a coprecipitating reagent and concentrated heavy metals were analyzed by a conventional AA spectrometer. Two areas, Cheng-Won and Tae-Ahn, were selected and comparison. The concentrations of Pb and Cd in Cheong-Won (raural) area were 14.3 .pm. 8.0 ppb and 2.77 .pm. 5.37 ppb, respectively. These values are higher than those of Tae-Ahn, which indicates that even a rural area is polluted by a nearly industrial area (Cheong-Ju). The isotope ratios of lead in rainwaters were very similar to theos of aerosol particles.

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Potential Biases Arising in the Use of Cascade Impactors to Estimate Respiratory Tract Deposition Patterns of Lead-Acid Battery Plant Aerosols

  • Hodgkins Douglas G.;Robins Thomas G.;Hinkamp David L.;Levine Steven P.;Schork M. Anthony;Krebs William H.
    • 대한예방의학회:학술대회논문집
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    • 1994.02a
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    • pp.585-595
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    • 1994
  • The region of the respiratory tract where inhaled particles deposit can have important implications for the causation of local or systemic toxic effects. For most aerosols of occupational importance, respiratory tract deposition can be predicted from the aerodynamic diameter of the particles. With the advent of cascade impactors, particularly those of personal sampler size, the determination of the aerodynamic diameters of aerosols has become more common. Some limitations of cascade impactor use are well recognized (e.g., particle bounce and substrate overloading) and are generally correctable. However, two important limitations of the instruments may not be receiving adequate attention: relative humidity effects on potentially hygroscopic aerosols and the collection characteristics of fibrous aerosols as compared to their actual deposition site potential. The results of this study, when compared to results of previous controlled laboratory trials, suggest that, while potentially hygroscopic lead aerosols from lead acid battery plant operations do not appear to be affected by changes in plant environmental humidity levels, the potential - exists for significant size changes upon inhalation. Secondly, fibers were detected in aerodynamic size ranges that would be associated with deep lung deposition; however, upon microscopic examination, these same fibers would actually be predicted to deposit in the upper airways. This study suggests that the physicalchemical properties and morphological features of an aerosol should be carefully considered by industrial hygienists before cascade impactors are used in attempts to predict the effects of inhaled aerosols.

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Improvement of Energy Storage Characteristics of (Ba0.7Ca0.3)TiO3 Thick Films by the Increase of Electric Breakdown Strength from Nano-Sized Grains (절연파괴특성 향상을 위한 나노미세구조 (Ba0.7Ca0.3)TiO3 후막 제조 및 에너지 저장 특성 평가)

  • Lee, Ju-Seung;Yoon, Songhyeon;Lim, Ji-Ho;Park, Chun-Kil;Ryu, Jungho;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.73-78
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    • 2019
  • Lead free $(Ba_{0.7}Ca_{0.3})TiO_3$ thick films with nano-sized grains are prepared using an aerosol deposition (AD) method at room temperature. The crystallinity of the AD thick films is enhanced by a post annealing process. Contrary to the sharp phase transition of bulk ceramics that has been reported, AD films show broad phase transition behaviors due to the nano-sized grains. The polarization-electric hysteresis loop of annealed AD film shows ferroelectric behaviors. With an increase in annealing temperature, the saturation polarization increases because of an increase in crystallinity. However, the remnant polarization and cohesive field are not affected by the annealing temperature. BCT AD thick films annealed at $700^{\circ}C/2h$ have an energy density of $1.84J/cm^3$ and a charge-discharge efficiency of 69.9 %, which is much higher than those of bulk ceramic with the same composition. The higher energy storage properties are likely due to the increase in the breakdown field from a large number of grain boundaries of nano-sized grains.

Comparison of particle collection characteristics in a wire-cylindrical wet electrostatic precipitator with and without a water film (와이어-실린더형 습식 전기집진기의 수막 유무에 따른 집진 특성 비교)

  • Woo, Chang Gyu;Cho, Won Ki;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.89-95
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    • 2018
  • People's environmental concerns for fine particles in Korea lead to the strong necessity of improving the performance of environmental control systems. Wet electrostatic precipitators (ESPs) are considered as one of the alternatives to overcome the limit of previous dry ESPs, the re-entrainment of collected particles during rapping and back corona problem for high electrical resistivity dusts etc. In this study, a wire-cylindrical ESP with a thin water film has been developed. Particle collection characteristics were compared in the ESP with operations of water film on and off. Particle collection efficiencies at various applied voltages as well as voltage-current curves were almost the same in the ESP with and without a water film. Particle collection performance for PM1.0, PM2.5 and PM10 in the wet ESP with a water film was constantly maintained with operation time even in the high dust loading environment. This results indicate that a uniform water film in our wet ESP was successfully formed with a very thin layer without any dry spot and therefore could continuously clean the collected particles on the inner wall of the ESP without any performance degradation.