• KIEE International Transactions on Electrophysics and Applications
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• v.5C no.1
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• pp.23-27
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• 2005

We observed that optical properties of silicon changed under high dose electron irradiation at 250 keV. Our experimental results revealed that the optical transmission through a silicon wafer is significantly increased by electron irradiation. Transmission increase by the change in the absorption coefficient is explained through an analogy with amorphous silicon. Moreover, solar cell open-circuit voltages indicated that defects were generated by electron irradiation, and that the defects responded to annealing. Our results demonstrated that the optical properties of silicon can be controlled by a combination of electron irradiation and hydrogen annealing.

• Bulletin of the Korean Chemical Society
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• v.9 no.3
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• pp.171-175
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• 1988

The spectral properties of piroxicam in different solvents are similar to those of its skeletal precursor, HMBDC. The maximum absorption and emission wavelengths strongly depend on the hydrogen bonding ability of the solvent, and it is shown that intramolecular hydrogen bonding between the -OH and the ortho carbonyl group of the parent benzothiazine ring plays an important role in the solvent-dependence of their spectroscopic properties. The fluorescence spectra in aprotic nonpolar solvent exhibit abnormally large Stokes-shifted (${\sim}9,000cm^{-1}$) emission bands in contrast to the spectra in water. In ethanol, dual emission bands with two different fractional components of lifetimes have been observed. These results suggest that the abnormally red-shifted emission is attributed to the proton transferred form of an intramolecularly hydrogen-bonded closed conformer.

• Korean Journal of Metals and Materials
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• v.50 no.12
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• pp.955-959
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• 2012

To increase the hydrogen storage capacity of Mg-based materials, a sample with a composition of 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ was prepared by planetary ball milling under hydrogen. The absorption and desorption properties of unmilled $MgH_2$, unmilled $LiBH_4$, and 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ were examined. At 648 K the unmilled $MgH_2$ desorbed 5.70 wt% for 60 min. The unmilled $LiBH_4$ desorbed 6.40 wt% H for 780 min at 673 K. The 69.7 wt% $MgH_2$ + 30.3 wt% $LiBH_4$ sample desorbed 3.10 wt% H for 50 min, and 3.32 wt% H for 300 min at 623 K at the second cycle.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.1
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• pp.58-63
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• 2010

Mg and Ma-based alloys are promising hydrogen storage materials for renewable clean energy applications. It has high hydrogen storage capacity (7.6wt.%), lightweight and low economical materials. However, commercial applications of the Mg hydride are currently hindered by its high operating temperature, and very slow reaction kinetics. In this work, we are aimed at studying the hydrogenation properties of the $MgH_x-V_2O_5$ composite prepared by hydrogen induced mechanical alloying. The absorption capacity of the sample is found to be about 4.7wt.% at 623K under 3 MPa $H_2$ pressure. The absorption characteristics observed have been compared with prepared $MgH_x$.

• Korean Journal of Materials Research
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• v.26 no.6
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• pp.332-336
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• 2016

Three kinds of porous polymer were synthesized using a solvothermal of tri-4,4'-diphenylmethane diisocyanate (MDI-trimer) and different diamino monomers. The effects of the synthesis conditions and the monomer selection on the synthesis of porous polymer properties were studied. The results show that the synthesis of $NH_2$-containing monomer molecules smaller the microporous polymers was easy to implement; the specific surface areas of the polymers are related to the monomer ratio and the reaction time. The results show that the synthesized porous polymer had good hydrogen storage performance; the hydrogen storage ability improved with the addition of heterocyclic nitrogen.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.178-183
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• 2011

Metal hydride alloys are a promising type of material in hydrogen storage applications, allowing for low-pressure, high-density storage. However, while many studies are being performed on enhancing the hydrogen storage properties of such alloys, there has been little research on large-scale storage vessels which make use of the alloys. In particular, large-scale, high-density storage devices must make allowances for the inevitable generation or absorption of heat during use, which may negatively impact functioning properties of the alloys. In this study, we develop a numerical model of the discharge properties of a high-density MH hydrogen storage device. Discharge behavior for a pilot system is observed in terms of temperature and hydrogen flow rates. These results are then used to build a numerical model and verify its calculated predictions. The proposed model may be applied to scaled-up applications of the device, as well as for analyses to enhance future device designs.

• 전기의세계
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• v.22 no.2
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• pp.11-18
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• 1973

This paper reports some results of Si and SiO$_{2}$ films obtained from the expitaxial growth by hydrogen reduction of SiCI$_{4}$ with a hydrogen and carbon dioxide mixture in an epitaxial-deposition chamber. The deposited Si and SiO$_{2}$ are studied by observing the process parameters affecting the rate of deposition, and the quantitative properties at the interface of Si and SiO$_{2}$ are also considered briefly according to the results of the optical absorption and the voltage-current characteristic of MOS etc. using step etching procedure for oxide films.

• Transactions of the Korean hydrogen and new energy society
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• v.35 no.2
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• pp.216-229
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• 2024

Pipeline steels for hydrogen transmission may cause hydrogen embrittlement due to absorption and diffusion of hydrogen through metals. Hydrogen pipes exhibited similar mechanical properties to atmospheric conditions in terms of tensile and yield strength in a hydrogen atmosphere. This paper aims to provide relevant information regarding hydrogen embrittlement in hydrogen transmission pipeline.

• Transactions of the Korean hydrogen and new energy society
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• v.7 no.1
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• pp.63-69
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• 1996

Effect of nickel powder to added to the hydrogen absorbing alloy electrode of $MmNi_{4.5}-xCoxMn_{0.3}Al_{0.2}$ system alloy was investigated. The addition of nickel powder was effective for the improvement of discharging characteristic. It was found that the discharge capacity was 310mAhig when the alloy negative electrode was mixed $MmNi_{3.75}CO_{0.75}Mn_{0.3}Al_{0.2}$ and nickel powder with a mix of one to three. Still another, we have investigated thermodynamic stability of hydrogen in the alloy negative electrode. As a result, enthalpy of hydrogen and hydrogen equilibrium pressure in the alloy negative electrode were a suitable value to easy hydrogen absorption-desorption.

• Journal of Photoscience
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• v.11 no.3
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• pp.95-99
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• 2004

Optical absorption and emission studies have been carried out to understand the effect of deuterium on the solvent dependent photophysical properties of curcumin in deuterated solvents such as $CDCl_3,\;(CD_3)_2SO,\;(CD_3)_2CO,\;CD_3OD\;and\;CD_3CN$. Optical absorption spectral studies showed that there is no significant shift in absorption maxima compared to the non-deuterated solvent. The fluorescence maxima shows significant shift with polarity of solvent but not much affected by the deuteration. The fluorescence quantum yield of curcumin increased marginally in almost all the deuterated solvents, indicating reduction in the non-radiative pathways. The fluorescence decay was biexponential in all the solvents and the average fluorescence lifetime was not much affected with deuteration, but showed decrease with increasing solvent polarity. Based on these studies, it is concluded that intermolecular hydrogen transfer is only partially responsible for the excited state deactivation of curcumin.