• Title/Summary/Keyword: green emission

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Effects of Boron Doping on the Structural and Optical Properties of CdS Thin Films (보론 도핑된 CdS 박막의 구조적 및 광학적 특성)

  • Lee, Jae-Hyeong;Jung, Hak-Kee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.7 no.5
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    • pp.1032-1037
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    • 2003
  • Boron-doped CdS thin films were chemically deposited onto glass substrates. X-ray diffraction (XRD), photoluminescence (PL), and Raman techniques were used to evaluate the quality of B-doped CdS films. XRD results have confirmed that B-doped CdS films has a hexagonal structure with a preferential orientation of the (002) plane. The PL spectra for all samples consists of two prominent broad bands around 2.3 eV (green emission) and 1.6 eV (red emission) and the higher doping concentrations gradually decreased the green emission and red emission. Raman analysis has shown that undoped films have structure superior to those of B-doped CdS films. Boron doping into CdS films improved the optical transmittance and increased the optical band gap.

Microwave Sol-Gel Derived NaGd(MoO4)2:Ho3+/Yb3+ Phosphors and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.6
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    • pp.364-369
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    • 2017
  • Double molybdate $NaGd_{1-x}(MoO_4)_2:Ho^{3+}/Yb^{3+}$ phosphors with proper doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ ($x=Ho^{3+}+Yb^{3+}$, $Ho^{3+}=0$ and 0.05, and $Yb^{3+}=0$, 0.35, 0.40, 0.45, and 0.50) were successfully synthesized using the microwave sol-gel method. Well-crystallized particles formed after heat-treatment at $800^{\circ}C$ for 16 h showed fine and homogeneous morphologies with particle sizes of $1{\sim}3{\mu}m$. The spectroscopic properties were examined using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the upconversion doped samples exhibited strong yellow emissions, from the combination of strong emission bands at 545 nm and 655 nm in the green and red spectral regions, respectively. The strong 545 nm emission band in the green region corresponded to the $^5S_2/^5F_4{\rightarrow}^5I_8$ transition in the $Ho^{3+}$ ions, while the strong 655 nm band in the red region appeared because of the $^5F_5{\rightarrow}^5I_8$ transition in the $Ho^{3+}$ ions. The pump power dependence and the Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail.

Development of LED Alternative to Standard Illuminant A Using Emission Spectrum Control (발광 스펙트럼 제어를 통한 표준광원 A 대체형 LED 개발)

  • Cho, Jae-Hyun;Jang, Min-Suk;Kim, Dong-Won;Kim, Wan-Ho;Kim, Gi-Hoon;Kim, Kang-Woong;Song, Sang-Bin;Kim, Jae-Pil
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.11
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    • pp.26-32
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    • 2011
  • In this study, a standard illuminant A type LED that has similar emission spectrum as the standard illuminant A was developed using LED chip(emission peak: 405[nm]) and four types of phosphors(blue, green orangered and red). Using the design of experiment for spectrum control, the trend of the change of spectrum shape influenced by the change of interaction among phosphors and their density could be examined. Computer simulation through the optimization of the design of experiment revealed that, among four phosphors, the most influential one on the shape of the spectrum was green phosphor. Using the obtained optimal combination ratio of the four phosphors, an alternative LED illuminant to the actual standard illuminant A was developed and the spectrums of these two were confirmed identical. Using this standard illuminant A type LED, a portable transmittance meter with the range of measurement error of ${\pm}1.0$[%] was developed.

A Study on the Fabrication and Characteristic Analysis of Multiheterostructure White Organic Light Emitting Device (다층구조 배색 유기발전소자의 제작 및 특성 분석에 관한 연구)

  • 노병규;강명구;오환술
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.429-434
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    • 2002
  • In this paper, multiheterostructure white organic light-emitting device was fabricated by vacuum evaporation. The structure of white organic light-emitting device is ITO/CuPc/TPD/DPBi:DPA/$Alq_3/Alq_3$:DCJTB/BCT/$Alq_3$/Ca/Al. Three primary colors are implemented with DPVBi, Alq$_3$and DCJTB. The maximum EL wavelength of the fabricated white organic light-emitting device is 647nm. And the CIE coordinate is (0.33, 0.33) at 13 V. In the fabrication of white organic light-emitting devices with DCJTB, $Alq_3$, DPVBi, the EL spectrum has two peaks at 492nm, 647nm. Two peaks appeared because the blue light is combined with green light. The maximum wavelength of red light is not changed with applied voltage. After voltage applied, for the first time, the electrons met the holes in the red emission layer and emitted red light. And then the electrons moved to the green emission layer, and blue emission layer continuously. Finally, when all of the emission layer activated, the white light is emitted.

Luminescence Characteristics of ZnGa2O4:Mn2+,Cr3+ Phosphor and Thick Film

  • Cha, Jae-Hyeok;Choi, Hyung-Wook
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.11-15
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    • 2011
  • In this study, $ZnGa_2O_4$ phosphors in its application to field emission displays and electroluminescence were synthesized through the precipitation method and $Mn^{2+}$ ions. A green luminescence activator, $Cr^{3+}$ ions, and a red luminescence activator were separately doped into $ZnGa_2O_4$, which was then screen printed to an indium tin oxide substrate. The thick films of the $ZnGa_2O_4$ were deposited with the various thicknesses using nano-sized powder. The best luminescence characteristics were shown at a thickness of 60 ${\mu}m$. Additionally, green-emission $ZnGa_2O_4:Mn^{2+}$ and red-emission $ZnGa_2O_4:Cr^{3+}$ phosphor thick films, which have superior characteristics, were manufactured through the screen-printing method. These results indicate that $ZnGa_2O_4$ phosphors prepared through the precipitation method have wide application as phosphor of the full color emission.

Up-conversion Luminescence Characterization of CeO2:Ho3+/Yb3+ Particles Prepared by Spray Pyrolysis

  • Jung, Kyeong Youl;Min, Byeong Ho;Kim, Dae Sung;Choi, Byung-Ki
    • Current Optics and Photonics
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    • v.3 no.3
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    • pp.248-255
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    • 2019
  • Spherical $CeO_2:Ho^{3+}/Yb^{3+}$ particles were synthesized using spray pyrolysis, and the upconversion (UC) properties were investigated with changing the preparation conditions and the infrared pumping power. The resulting particles had a size of about $1{\mu}m$ and hollow structure. The prepared $CeO_2:Ho^{3+}/Yb^{3+}$ particles exhibited intense green emission due to the $^5F_4/^5S_2{\rightarrow}^5I_8$ transition of $Ho^{3+}$ and showed weak red or near-IR peaks. In terms of achieving the highest UC emission, the optimal concentrations of $Ho^{3+}$ and $Yb^{3+}$ were 0.3% and 2.0%, respectively. The UC emission intensity of prepared $CeO_2:Ho^{3+}/Yb^{3+}$ particles had a linear relationship with crystallite size and concentration quenching was caused by dipole-dipole interaction between the same ions. Based on the dependency of UC emission on the pumping power, the observed green upconversion was achieved through a typical two-photon process and concluded that the main energy transfer from $Yb^{3+}$ to $Ho^{3+}$ was involved in the ground-state adsorption (GSA) process.

$LCCO_2$ Comparison of Existing Apartment Housing and Environment-Friendly Apartment Housing (기존 설계기준 아파트와 친환경 저에너지 아파트의 $LCCO_2$ 비교)

  • Kim, Yu-Min;Sohn, Jang-Yeul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.4
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    • pp.234-240
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    • 2010
  • In October 2009, the Ministry of Land Transport and Maritime Affairs noticed 'Environment-friendly housing construction standards and performance' to build energy saving environment-friendly housings (Green Homes) for the reduction of energy consumption and carbon dioxide emission. In this study, the $CO_2$ emissions were evaluated during the life cycle of the existing apartments which were built in 1980's and Green Home apartment. $LCCO_2$ was evaluated by dividing the life cycle into three stages which are construction, maintenance and destruction stage. $CO_2$ emission from the materials for improving insulation performance was estimated by Input-output analysis. As a result, in 40 year-life cycle of $84\;m^2$ apartment, 400.68 T-$CO_2$ was emitted from 1980's apartment, on the other hand 231.02 T-$CO_2$ was emitted from Green Home apartment.

Forecasting Market Shares of Environment-Friendly Vehicles under Different Market Scenarios

  • Bae, Jeong Hwan;Jung, Heayoung
    • Environmental and Resource Economics Review
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    • v.22 no.1
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    • pp.3-29
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    • 2013
  • The purpose of this study is to estimate consumer preferences on hybrid cars and electric cars by employing a choice experiment reflecting the various market conditions, such as different projected market shares of green vehicles and $CO_2$ emission regulations. Depending on different market scenarios, we examine as to which attribute and individual characteristic affect the preferences of potential consumers on green vehicles and further, forecast the potential market shares of green cars. The primary results, estimated by a conditional logit and panel probit models, indicate that sales price, fuel cost, maximum speed, emission of air pollutants, fuel economy, and distance between fuel stations can significantly affect consumer's choice of environment-friendly cars. The second finding is that the unique features of electric cars might better appeal to consumers as the market conditions for electric cars are improved. Third, education, age, and gender can significantly affect individual preferences. Finally, as the market conditions become more favorable toward green cars, the forecasted market shares of hybrid and electric vehicles will increase up to 67% and 14%.

The Study of $Eu^{2+}$-activated Calcium Aluminium Silicate Phosphors for White UV-LED (백색 UV-LED를 위한 $Eu^{2+}$-활성화 칼슘 알루미늄 실리케이트 형광체 연구)

  • Hwang, Jung-Ha;Jang, Bo-Yun;Park, Joo-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.32-35
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    • 2006
  • For the white UV-LED applications, $Eu^{2+}$-activated calcium aluminium silicate phosphors were synthesized for the first time and the structures and luminescence characteristics of these phosphors were investigated. The phosphors in this study emitted blue. green or blue-green light depending on the starting materials for synthesis. In addition, the structure was also changed when the different starting materials were used. When CaO and $CaCO_3$ was used as a starting material. tetragonal $Ca_2Al_2SiO_7$ was formed and blue-green and pure green light was emitted. respectively. However. in the case of $CaSiO_3$, triclinic $CaAl_2Si2O_8$ was formed and only pure blue emission was detected. The maximum emission intensity was obtained from $CaAl_2Si_2O_8:Eu^{2+}$ phosphors, which intensity was about 1.4 times higher than that of YAG:$Ce^{3+}$ phosphor used for blue LED.

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Synthesis of rhombohedral-structured zinc germanate thin films and characteristics of divalent manganese-activated electroluminescence

  • Yoon, Kyung-Ho;Kim, Joo-Han
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.453-453
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    • 2010
  • In this study, zinc germanate ($Zn_2GeO_4$) thin films has been synthesized by using radio frequency magnetron sputtering and the divalent manganese-activated luminescence was characterized. X-ray diffraction patterns of the as-deposited $Zn_2GeO_4$:Mn films showed only a broad feature, indicative of an amorphous structure. Scanning electron microscopy images revealed that the as-deposited $Zn_2GeO_4$:Mn has a smooth surface morphology. The $Zn_2GeO_4$:Mn films were found to be crystallized by annealing in air ambient at temperatures as low as $700^{\circ}C$. The annealed $Zn_2GeO_4$:Mn possessed a rhombohedral polycrystalline structure. The broad-band photoluminescent emission spectrum from 470 to 650nm was obtained at room temperature from the $Zn_2GeO_4$:Mn films. The emission peak was centered at around 535nm in the green range, which originates from the intrashell transition of manganese $3d^5$ electrons from $^4T_1$ excited-state level to the $^6A_1$ ground state. The PL emission spectrum had an asymmetric line shape, which results from the $^3d_5$ electron transitions of divalent manganese ions located at different sites of the zinc germanate host crystal lattice. Electroluminescent devices were fabricated using $Zn_2GeO_4$:Mn as an emission layer. The fabricated devices showed a green EL emission similar to the PL emission. The CIE chromaticity color coordinates of the EL emission were determined to be x=0.308 and y=0.657.

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