• 제목/요약/키워드: foam reaction

검색결과 146건 처리시간 0.026초

우르시올을 첨가한 자동차 시트용 항균 폴리우레탄 발포체 개발 (Development of Antimicrobial Polyurethane Foam for Automotive Seat Modified by Urushiol)

  • 홍채환;김현성;박헌희;김연희;김상범;황태원
    • 폴리머
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    • 제30권5호
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    • pp.402-406
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    • 2006
  • 천연 옻 나무에서 추출되는 항균물질 우르시올을 폴리우레탄 발포체 성형 시스템에 도입하여 항균 폴리우레탄 발포체를 제조하였다. 항균물질 우르시올 첨가량을 증가시키는 경우 발포체 성형 반응성이 약간 저하되는 것이 관찰되었으나 기계적 물성 측면에서는 항균물질 미처리 발포체와 비교하여 큰 물성저하는 관찰되지 않았다. 반면 항균성 측면에서는 항균물질 미처리 발포체에 비하여 초기 균수 대비 균수의 성장성이 감소되는 것을 확인할 수 있었다.

과산화수소의 가압침투에 의한 다공성 발포체에 관한 연구 (A Study on Bloating of Porous Foam by Pressure Infiltration with H2O2)

  • 김귀식;정지현
    • 동력기계공학회지
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    • 제20권5호
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    • pp.86-91
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    • 2016
  • This paper is concerned chiefly with the method of porous foam manufacture using basalt stone powder sludge. The hydrogen peroxide($H_2O_2$) of bloating agent has lots of problems to manufacture porous lightweight aggregate due to fast reaction rate with cement or calcium hydroxide($Ca(OH)_2$). The $H_2O_2$ injecting method using nozzle for manufacturing porous lightweight aggregate is proposed, in this study. This method is to inject $H_2O_2$ at the pressure of 10 MPa on upper side of slurry mixing materials such as stone powder sludge and quick-lime(CaO) by injector. The specimen was dried in furnace at $100^{\circ}C$ for 1 hour and cured at ambient temperature for 30 days. We analyzed the characteristics including specific gravity and water absorption. The experiments were found that the porous foam has low specific gravity, high water absorption and uniform distribution of porous more than manufactured foam by general bloating methods.

FABRICATION OF ZrO2-BASED NANOCOMPOSITES FOR TRANSURANIC ELEMENT-BURNING INERT MATRIX FUEL

  • MISTARIHI, QUSAI;UMER, MALIK A.;KIM, JOON HUI;HONG, SOON HYUNG;RYU, HO JIN
    • Nuclear Engineering and Technology
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    • 제47권5호
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    • pp.617-623
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    • 2015
  • $ZrO_2$-based composites reinforced with 6.5 vol.% of carbon foam, carbon fiber, and graphite were fabricated using spark plasma sintering, and characterized using scanning electron microscopy and X-ray diffractometry. Their thermal properties were also investigated. The microstructures of the reinforced composites showed that carbon fiber fully reacted with $ZrO_2$, whereas carbon foam and graphite did not. The carbothermal reaction of carbon fiber had a negative effect on the thermal properties of the reinforced $ZrO_2$ composites because of the formation of zirconium oxycarbide. Meanwhile, the addition of carbon foam had a positive effect, increasing the thermal conductivity from 2.86 to $3.38Wm^{-1}K^{-1}$ at $1,100^{\circ}C$. These findings suggest that the homogenous distribution and chemical stability of reinforcement material affect the thermal properties of $ZrO_2$-based composites.

접시형 태양열 집광 시스템을 이용한 열화학 사이클의 수소생산 (TWO-STEP THERMOCHEMICAL CYCLES FOR HYDROGEN PRODUCTION WITH DISH TYPE SOLAR THERMAL SYSTEM)

  • 권해성;오상준;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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    • pp.169-176
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    • 2011
  • The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

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니켈 폼(Ni foam)에 수열 합성법으로 제조한 수산화니켈(Ni(OH)2) 전극의 구조적 및 전기적 특성 (Structural and Electrical Properties of Nickel Hydroxide Electrode Prepared by Hydrothermal Synthesis on Nickel Foam)

  • 차현진;이석희;박정환;손영국;황동현
    • 한국표면공학회지
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    • 제56권5호
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    • pp.320-327
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    • 2023
  • In this study, the nickel hydroxide (Ni(OH)2) electrode for supercapacitor was prepared via hydrothermal method. Based on the nickel (Ni) foam, the electrode does not require any additional binder material or post-processing. Nickel nitrate (Ni(NO3)2) and hexamethylenetetramine (C6H12N4) were used for synthesis, and the synthesis condition was 12 hours at 80 ℃. X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM) were used to analyze the structural characteristics of the electrode, and it shown that the nickel hydroxide was successfully prepared after only the one-step hydrothermal synthesis. The electrochemical properties were analyzed through the half-cell test. The prepared electrode shown a pair of oxidation/reduction peaks, indicating that the driving method included the redox reaction on the electrode surface. After the charge/discharge test, the specific capacitance was calculated as the value of 438 F/g at 3 A/g.

더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar CO2-Reforming of Methane Using a Double-Layer Absorber)

  • 김동연;이진규;이주한;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.267-273
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    • 2012
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar CO2-Reforming of Methane Using a Double-Layer Absorber)

  • 김동연;신일융;이주한;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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    • pp.80-86
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    • 2011
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber - the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam - was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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접시형 태양열 시스템을 이용한 2단계 열화학 싸이클의 수소 생산과 PID 온도 제어 기법 연구 (A Study on Pill Temperature Control method and Hydrogen Production with 2-step Thermochemical Cycle Using Dish Type Solar Thermal System)

  • 김철숙;김동연;조지현;서태범
    • 한국태양에너지학회 논문집
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    • 제33권3호
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    • pp.42-50
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    • 2013
  • Solar thermal reactor was studied for hydrogen production with a two step thermochemical cycle including T-R(Thermal Reduction) step and W-D(Water Decomposition) step. NiFe2O4 and Fe3O4 supported by monoclinic ZrO2 were used as a catalyst device and Ni powder was used for decreasing the T-R step reaction temperature. Maintaining a temperature level of about $1100^{\circ}C$ and $1400^{\circ}C$, for 2-step thermochemical reaction, is important for obtaining maximum performance of hydrogen production. The controller was designed for adjusting high temperature solar thermal energy heating the foam-device coated with nickel- ferrite powder. A Pill temperature control system was designed based on 2-step thermochemical reaction experiment data(measured concentrated solar radiation and the temperature of foam device during experiment). The cycle repeated 5 times, ferrite conversion rate are 4.49~29.97% and hydrogen production rate is 0.19~1.54mmol/g-ferrite. A temperature controller was designed for increasing the number of reaction cycles related with the amount of produced hydrogen.

비 살상 무기 개발을 위한 생분해성 발포 폴리우레탄에 대한 연구 (Study on Biodegradable Polyurethane Foam for Non-lethal Weapon)

  • 이향무;김영현;김경원;정인우
    • 접착 및 계면
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    • 제17권1호
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    • pp.21-28
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    • 2016
  • 본 연구에서는 불법 조업 어선 제압 및 장비 불용화를 위한 접착형 퇴치제 개발의 일환으로 발포형 생분해성 폴리우레탄 연구를 수행하였다. 발포형 폴리우레탄 접착제는 폴리에스터계 및 폴리에테르 폴리올을 포함하는 주재와 고분자형의 이소시아네이트로 이루어진 경화제를 혼합하여 반응이 완결되는 2액형으로, 단기간의 생분해성을 위해 주재에 starch와 dextrin 및 amylase 등을 첨가하여 4주간 약 34%의 생분해도를 OECD 301C법에 의해 얻을 수 있었다. 주재와 경화제의 온도에 따른 점도를 $0{\sim}50^{\circ}C$의 온도범위에서 측정하여 혼합 시 참고할 수 있도록 하였으며, 또한 신속한 발포 및 접착성능을 위해서 $0{\sim}50^{\circ}C$의 온도 범위에서 발포형 폴리우레탄 접착제의 반응 완결 속도(rising time)를 조절하여 1 min 내외로 제어하였다. 또한 면 직물에 대한 T-peel 시험을 수행한 결과 최대 20.78 N/cm, 평균 11.95 N/cm의 접착력을 얻을 수 있었다.

Increasing the attractiveness of physical education training with the involvement of nanotechnology

  • Jinyan Ge;Yuxin Hong;Rongtian Zeng;Yunbin Li;Mostafa Habibi
    • Advances in concrete construction
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    • 제16권6호
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    • pp.291-302
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    • 2023
  • As the first part of the body that strikes the ground during running, sports shoes are especially important for improving performance and reducing injuries. The use of new nanotechnology materials in the shoe's sole that can affect the movement angle of the foot and the ground reaction forces during running has not been reported yet. It is important to consider the material of the sole of the shoe since it determines the long-term performance of sports shoes, including their comfort while walking, running, and jumping. Running performance can be improved by polymer foam that provides good support with low energy dissipation (low energy dissipation). Running shoes have a midsole made of ethylene propylene copolymer (EPP) foam. The mechanical properties of EPP foam are, however, low. To improve the mechanical performance of EPP, conventional mineral fillers are commonly used, but these fillers sacrifice energy return. In this study, to improve the magnificence of physical education training with nanotechnology, carbon nanotubes (CNTs) derived from recycled plastics were prepared by catalytic chemical vapor deposition and used as nucleating and reinforcing agents. As a result of the results, the physical, mechanical, and dynamic response properties of EPP foam combined with CNT and zinc oxide nanoparticles were significantly improved. When CNT was added to the nanocomposites with a weight percentage of less than 0.5 wt%, the wear resistance, physical properties, dynamic stiffness, compressive strength, and rebound properties of EPP foams were significantly improved.