• Title/Summary/Keyword: entropy change

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A Study of Pre-service Chemistry Teacher's Understanding on Entropy

  • Seo, Young-Jin;Hong, Hun-Gi
    • Journal of The Korean Association For Science Education
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    • v.32 no.3
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    • pp.415-427
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    • 2012
  • In this study, we conducted preliminary survey, diagnostic test and in-depth interview in order to study Korean pre-service chemistry teachers' understanding on entropy and investigate how Korean pre-service chemistry teachers deal with the natural phenomenon which is related to entropy conceptions. Firstly, as a result of the preliminary survey, it was found that pre-service chemistry teachers strongly recognized entropy as the degree of disorder. Secondly, the diagnostic test showed pre-service chemistry teachers were mostly confused about whether the entropy of the universe increases during a spontaneous change, and they had a tendency to interpret the natural phenomenon related to entropy change as the change of disorder. Finally, during in-depth interview, after we explained entropy change in all diagnostic test questions with the concept of microstate, pre-service chemistry teachers revealed a better understanding about entropy. Through this research, pre-service chemistry teachers had an opportunity to reflect on their deficiencies of entropy conceptions, which will ultimately help students to approach the concept of entropy more correctly.

The Magnetic Entropy Change on La0.7Ba0.3Mn1-xFexO3 Compound

  • Hwang, J.S.;Jang, D.M.;Kim, K.S.;Lee, J.S.;Yu, S.C.
    • Journal of Magnetics
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    • v.18 no.1
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    • pp.30-33
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    • 2013
  • The magnetocaloric effect and magnetization behavior have been analyzed in the double-perovskite $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound with the sintering temperature at 1273 K. Samples were fabricated by the conventional solid-state reaction method. X-ray diffraction measurement revealed that all the samples had a single phase in orthorhombic. Detailed investigations of the magnetic entropy behavior of the samples were discussed with the variation of $T_C$. The magnetic entropy changes, ${\Delta}S_M$ of approximately 0.36-1.14 J/kg K were obtained in the temperature range of 145-350 K for the $La_{0.7}Ba_{0.3}Mn_{1-X}Fe_XO_3$ compound. The enhancement of the magnetic entropy change is believed to be due to changes in the microstructure, which changes the magnetic part of the entropy of a solid around the magnetic ordering temperature.

A Study on the Entropy of Binary First Order Markov Information Source (이진 일차 Markov 정보원의 엔트로피에 관한 연구)

  • 송익호;안수길
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.20 no.2
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    • pp.16-22
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    • 1983
  • In this paper, we obtained PFME(probability for maximum entropy) and entropy when a conditional probability was given in a binary list order Markov Information Source. And, when steady state probability was constant, the influence of change of a conditional probability on entropy was examined, too.

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Magnetization and Magnetic Entropy Change in Superparamagnetic Co-Ferrite Nanoparticle (초상자성 코발트 페라이트 나노입자에 대한 자화 및 자기엔트로피 변화)

  • Ahn, Yang-Kyu;Choi, Eun-Jung
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.63-66
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    • 2008
  • In order to the magnetization and magnetic entropy change for superparamagnetic ferrite nanoparticles, ultrafine cobalt ferrite particles were synthesized using a mircoemulsion method. The peak of X-ray diffraction pattern corresponds to a cubic spinel structure with the lattice constant 8.40 $\AA$. The average particle size, determined from X-ray diffraction line-broadening using Scherrer's, is 7.9 nm. The maximal magnetizations measured at 5 and 300 K are 24.3 emu/g and 17.2 emu/g, respectively. Superparamagnetic behavior of the sample is confirmed by the coincidence of the M vs. H/T plots at various temperatures. According to the thermodynamic theory, magnetic entropy change decreases with increasing temperature.

Impact of Ba Substitution on the Magnetocaloric Effect in La1-xBaxMnO3 Manganites

  • Hussain, Imad;Anwar, M.S.;Kim, Eunji;Koo, Bon Heun;Lee, Chan Gyu
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.623-627
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    • 2016
  • $La_{1-x}Ba_xMnO_3$ (x = 0.30, 0.35 and 0.40) samples have been prepared by solid-state reaction method. The X-ray diffraction (XRD) study showed that all the samples crystallized in a rhombohedral structure with an R-3c space group. Variation of the magnetization as a function of the temperature and applied magnetic field was carried out. All the samples revealed ferromagnetic to paramagnetic (FM-PM) phase transition at the Curie temperature $T_C{\sim}342K$. The magnetic entropy change was also studied through examination of the measured magnetic isotherms M(H, T) near $T_C$. The magnetocaloric effect was calculated in terms of the isothermal magnetic entropy change. The maximum entropy change reaches a value of 1.192 J/kgK under a magnetic field change of 2.5T for the $La_{0.6}Ba_{0.4}MnO_3$ composition. The relative cooling power (RCP) is 79.31 J/kg for the same applied magnetic field.

Large Magnetic Entropy Change in Single Crystalline and Ploystalline $La_{0.7}Ca_{0.3}MnO_3$ (망간산화물 $La_{0.7}Ca_{0.3}MnO_3$의 거대 자기 엔트로피 효과)

  • 신현수;주홍렬
    • Journal of the Korean Magnetics Society
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    • v.10 no.4
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    • pp.149-153
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    • 2000
  • Large magnetic entropy change in single crystalline and polycrystalline perovskite manganites La$_{0.7}$Ca$_{0.3}$MnO$_3$ has been observed as magnetic field is changed. The large magnetic entropy change is believed to be caused by the abrupt reduction in magnetization as a result of 1st order-like magnetic transition. The large magnetic entropy change and easiness of the Curie temperature manipulation in the temperature range 100 K

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Studies of the Definition and Explanation of Entropy in the GeneralChemistry Textbook (일반화학 교재에 나타난 엔트로피 정의와 설명의 고찰)

  • Seo, Young-Jin;Chae, Hee K.
    • Journal of the Korean Chemical Society
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    • v.53 no.1
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    • pp.62-72
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    • 2009
  • In this study, entropy definition and explanation in twelve general chemistry textbooks published in USA including what Korean universities select are analyzed. Analysis consists of two parts. One is diachronic analysis which focuses on the change between editions of same authors and the other is contents analysis composed of three sections‐ disorder in entropy definition and explanation, microstates number in entropy definition and explanation, possibility of alternative conception in learning statistical entropy and thermal entropy. As a result, the definition that entropy is the measure of disorder is denied and explanation using microstates number is introduced. Also, caution for the possibility of alternative conception that there are two different entropies is found. Reflecting the change in entropy explanation on new chemistry curriculum and reeducating teachers are meaningful on improvement of Korean chemistry education.

Cut Detection of Video Data Using Color Histogram and Entropy (컬러 히스토그램과 엔트로피를 이용한 동영상 컷 검출)

  • 송현석;안강식;안명석;조석제
    • Proceedings of the Korea Institute of Convergence Signal Processing
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    • 2001.06a
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    • pp.265-268
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    • 2001
  • In content-based video data retrieval, the representative-frame is usually used. To do that, the skill of detection for scene change is needed. Generally the color histogram comparison is used, but sensitive to light variation and tends to miss the scene change of similar color histogram. This paper shows how to use both color histogram comparison and entropy to prevent the false-positive of scene change occurred by light variation. At the experiments, il is more powerful to light variation to use both color histogram comparison entropy than to use only color histogram comparison.

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Simulation of Entropy Decrease in Puzzle Game Play (퍼즐 게임 플레이에 나타난 엔트로피 감소의 시뮬레이션)

  • Yun, Hye-Young
    • Journal of Korea Game Society
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    • v.13 no.5
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    • pp.19-30
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    • 2013
  • This Study analyzes dynamic of a puzzle game play by applying entropy law. Entropy is a concept that a quantitative measure of the amount of thermal energy not available to do work in a closed system. And amount of entropy can be measured only if we see the closed system as whole, the field. Puzzle game is also closed system. When player moves an object in game, it change a relationship among objects in play field. In , through an act of position change, player sustains a play field active. In respect of an entropy, this kind of play is considered as pursue of usability of the energy. In , player piles up objects without empty space. In respect of an entropy, this kind of play is considered as pursue of the order. Likewise, puzzle game play can be considered as simulation of a human's pursue of the order in an entropy increasing physical world. And this pursue is a driving force of puzzle game play.

System Thinking Analysis on The Organizational Entropic Measures: Focusing on Workers' Speedy Compensation (조직의 엔트로피식 처방에 대한 시스템 사고 분석: 산업재해 신속보상을 중심으로)

  • Yang, Jeong-Ho
    • Korean System Dynamics Review
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    • v.14 no.4
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    • pp.63-89
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    • 2013
  • The purpose of this paper is to explain the entropic measures could cause the organization to increase the entropy. The organization as an open system has a tendency to input new energy to adapt itself to the change in its surroundings. This intention of inputting energy into organization is based on the second law of thermodynamics, the laws of entropy.Entropy is a measure of disorder, or a measure of progressing towards thermodynamic equilibrium. The entropy of an isolated system increases. Organizations have to open to their environment, have to do something to reduce their entropy. But, this attempt to reduce entropy entails another entropy. This study shows the side effects by giving examples of illegal receipt of worker's compensation insurance. The implications through the cases of illegal receipt of workers' compensation are as follows. Firstly, organizational policy is that inaction in itself may be the best policy, unless we always think the action best. Secondly, public organization should be careful in substituting business management in the private sector such as customer satisfaction(CS) for the value in public sector. Thirdly, the setting the expiration date of organizational policy could be the way to slow down the degree of entropy.

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