• Title/Summary/Keyword: energy change

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Improved Cycle Performance of High-Capacity SiOx Negative Electrodes with Carbon Nanotube Conducting Agents for Lithium-Ion Batteries (탄소나노튜브 도전재 적용을 통한 리튬이온 이차전지용 고용량 SiOx 음극의 사이클 성능개선)

  • Hyang Sun Jeon;Ji Heon Ryu
    • Journal of the Korean Electrochemical Society
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    • v.26 no.3
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    • pp.35-41
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    • 2023
  • The carbon-coated silicon monoxide (c-SiOx), which is a negative electrode active material for lithium-ion batteries (LIBs), has a limited cycle performance due to severe volume changes during cycles, despite its high specific capacity. In particular, the significant volume change of the active material can deform the electrode structure and easily damage the electron transfer pathway. To improve performance and mitigate electrode damage caused by volume changes, we replaced parts of the carbon black conducting agent with carbon nanotubes (CNTs) having a linear shape. The content of the entire conductive material in the electrode was fixed at 10% by mass, and the relative content of CNTs ranged from 0% to 25% by mass to prepare electrodes and evaluate electrochemical performance. As the CNT content in the electrode increased, both cycle life and rate capability improved. Even a small amount of CNT can significantly improve the electrochemical performance of a c-SiOx negative electrode with large volume changes. Furthermore, dispersing CNTs effectively can lead to achieving the equivalent performance with a reduced quantity of CNTs.

EU Enlargement and economic environmental change of Russia and Eastern Europe - From asymmetry and subsidiarity paradigm in industrial cooperative paradigm (EU의 동방확대에 따른 동유럽·러시아간의 경제 환경 변화 - 비대칭성 및 보완성 패러다임에서 산업협력 패러다임으로)

  • Kim, Sang Won
    • Journal of International Area Studies (JIAS)
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    • v.13 no.1
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    • pp.135-156
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    • 2009
  • The two waves of EU enlargement in 2004 and 2007, have been milestones of European integration. While research has been conducted into the impact of these events on both the European and the global economies,1 there have been few attempts to assess the effects of EU enlargement and the introduction of the euro on countries such as Russia, which neighbour the EU but currently have no perspective of accession. This paper aims to provide an assessment of the effects that EU enlargement and the introduction of the euro have had on Russia, the largest country neighbouring the EU. In particular, it focuses on trade and investment links between the EU and Russia, as well as the use of the energy by Russian residents and authorities. Economic links between Russia and the EU are found to have strengthened considerably in the areas of trade, investment and other financial flows in recent years. Strong growth, particularly in Russia, as well as the high price of oil and gas, Russia's major export items, has facilitated this expansion of trade and finance. Moreover, available data do not suggest that EU enlargement has had a negative impact on Russia in terms of trade or investment diversion. Thus, the strategic partnership between Russia and the EU has been increasingly underpinned by an expansion of cross-border economic activities. Thus, the paper contributes to two broad strands of literature on this subject, namely the impact of regional trade and economic arrangements on non-member countries and the international role of currencies.

Durability Evaluation of Cement Concrete Using Ferrosilicon Industrial Byproduct (페로실리콘 산업부산물 활용 시멘트 콘크리트의 내구성능 평가)

  • Chang-Young Kim;Ki Yong Ann
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.89-96
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    • 2023
  • In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO2 content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

Evaluation of Cavity Characterization Using Infrared Thermal Images (적외선 이미지를 이용한 지하공동 평가)

  • Jang, Byeong-Su;Kim, Young-Seok;Kim, Se-Won ;Choi, Hyun-Jun;Yoon, Hyung-Koo
    • Journal of the Korean Geotechnical Society
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    • v.39 no.7
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    • pp.69-76
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    • 2023
  • Cavity causes settlement and its remediation after an accident results in significant time and economic losses. This study aims to experimentally evaluate the prospect of using infrared camera to detect and measure underground subsidence. Emissivity is necessary to detect the energy emitted from an object and accurately assess temperature using an infrared camera. The emissivity in laboratory tests is fixed to evaluate a reasonable distance between the infrared camera and the object, and temperature values are assessed at various distances. In field experiments, the cavity of the field experiment is simulated using a PVC pipe with a diameter of 5 cm, artificially buried at depths of 5 and 25 cm from the surface. The infrared camera measurements are taken from 4 PM to 3 PM of the next day (a total of 23 h). The analysis included the time-series temperature distribution and the cooling rate index assessment, which represents the temperature change rate per unit of time. The results showed that various temperature trends are observed depending on the location of the subsidence. This study demonstrates that the infrared camera can be used to assess the condition of the subsurface.

Biodegradation of VOC Mixtures using a Bioactive Foam Reactor II: Analysis of Microbial Community (계면활성제 미생물반응기의(혼합 VOCs) 생분해 II: 미생물의 군집해석)

  • Jang, Hyun Sup;Shin, Shoung Kyu;Song, Ji Hyeon;Hwang, Sun Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6B
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    • pp.695-701
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    • 2006
  • A toluene-degrading bacterial strain was isolated from a mixed culture that was maintained using toluene as a sole carbon and energy source. The isolated bacterium was classified as Pseudomonas sp. TBD4 based on the close relationship to bacteria belonging to this genus. A bottle study to determine biodegradation rates of individual aromatic compounds showed that the biodegradation was faster in the order of toluene, benzene, styrene, and p-xylene. However, when various mixtures were subjected to TDB4, styrene was degraded at the highest rate, indicating that both toluene and p-xylene could stimulate the degradation of other substrates whereas styrene played as an inhibitor. In addition, the mixed culture and TDB4 were inoculated to the bioactive foam reactor (BFR), and the reactor performance and the corresponding change of microbial community were monitored using the fluorescent in situ hybridization (FISH) method. When an inlet concentration of the VOC mixture increased to greater than 250 ppm, the overall removal efficiency dropped significantly. The FISH measurement demonstrated that the ratio of TDB4 to the total bacteria also decreased to less than 20% along with the decline in removal efficiency in the BFR. As a result, the periodic addition of the pre-grown TDB4 might have been beneficial to achieve a stable performance in the BFR operated over an extended period.

A Real Situation Experimental Study on The Thermal Protection Performance of Firefighter Clothes and Gloves (소방방화복 및 소방장갑의 열 보호 성능에 대한 실제 화재 실험 연구)

  • Lee, Won Jae;Kang, Gu Hyun;Jang, Yong Soo;Kim, Wonhee;Choi, Hyun Young;Kim, Jae Guk;Kim, MinJi;Seo, Kyo;kim, Do hee;Lee, Joo-young;Choi, Jung Yoon
    • Journal of the Korean Burn Society
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    • v.21 no.1
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    • pp.17-21
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    • 2018
  • Purpose: This study aimed to evaluate the thermal protective function of firefighter clothes and gloves through real scale fire simulations. Methods: Firstly, the fire simulation by real scale flame was performed for firefighter clothes. A manikin equipped with firefighter clothes was directly exposed to flames which energy average is 84 Kw/m2. for 22 seconds. Heat flux gauges attached on the body measured surface temperature elevation. Secondly, we also performed the other fire simulation by hot plate exposure to firefighter gloves. Firefighter gloves with heat flux gauges exposed hot plate which temperature is 300℃ in both dry and moist conditions. Primary outcome was surface temperature change of manikin body (first simulation) and hand (second simulation) over times. Results: In the first flame simulation, the surface temperature of face and shoulders elevated more rapidly comparing with the other body surface area when initial period of flame shutter open. After 18sec of shutter open, the surface temperature of upper trunk elevated rapildy. After shutter closure, high surface temperature kept continuously on right side of face and left shoulder. In the second hot plate simulation, fingers and palms showed higher surface temperature than the other areas of hands in the both dry and wet conditions. Conclusion: This study suggests that the real scale flame enables firefighter clothes to lose their heat protective function suddenly after 18 seconds. Additionally, the protective function of firefighter gloves were relatively weaker in the palmar side of fingers than the other parts of hand. There should be additional study for evaluate thermal protection performance of firefighter clothes. And, further effort for reinforce palmar side of fingers of firefighter gloves should be done.

An Experimental Study on the Quality of Mortar Mixed with Tapioca Starch (타피오카 전분을 혼합한 모르타르의 품질에 관한 실험적 연구)

  • Yong Jic Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.3
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    • pp.244-250
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    • 2023
  • In this paper, mortar mixed with tapioca starch was manufactured to evaluate the effect of tapioca starch on mortar, through evaluating the quality characteristics of mortar, the impact of tapioca starch on improving the performance and basic quality of mortar was examined. Tapioca starch tended to decrease flow by increasing the viscosity of the dough consistency of fresh mortar, which tended to reduce flow, and decreased by about 10 % as the tapioca starch mixing ratio increased by 0.025 %. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mix ing tapioca starch. In addition, the effect of tapioca starch on the compressive strength of mortar was at the same level regardless of the tapioca starch mixture at 28 days of age. However, at an early age of 3 days, the speed of compressive strength development was accelerated by mixing tapioca starch. The speed of strength development improved by about 20 % when mixing 0.050 % tapioca starch. The adhesion strength improved by about 60 % when mixing 0.050 % tapioca starch, and the final shrinkage in length change decreased by 5 %.

Why is ecological restoration practiced differently from the international community in Korea? (우리나라에서는 왜 생태복원이 국제사회와 다르게 진행될까?)

  • Chang Seok Lee
    • Journal of Wetlands Research
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    • v.25 no.4
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    • pp.394-407
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    • 2023
  • Ecological restoration is an ecological technology that diagnoses problematic ecological spaces and restores the damaged ecosystem to a healthy appearance similar to its original appearance based on reference information obtained by analyzing intact nature. To achieve successful restoration, the project must be carried out in respect of a series of procedures. However, in Korea, restoration projects are usually actively promoted regardless of diagnostic evaluation, which wastes cost and energy, and the effect is not significant. As the reference information is not utilized, ecological restoration to return the damaged nature makes features different greatly from the appearance of nature, causing another damage. As the restoration effect is not evaluated, it is impossible to determine whether it is successful or not, and as a result, even if the project continues, there is no development and no effect. However, advanced societies have not only made academic progress by respecting these procedures but also have great economic effects along with the improvement of environmental conditions as ecological restoration has become an industry. Therefore, the international society recognizes ecological restoration as an important means of solving environmental problems at the global level, including climate change, and international organizations are actively promoting projects to treat the injured planet. However, most of the restoration projects promoted in Korea were evaluated below the level as a result of the evaluation of the effect. Nevertheless, those who have led low-quality projects are blocking plans to establish ecological restoration as a new industry that can contribute significantly to improving these levels, and thus the problem is expected to worsen. To solve this problem, it is necessary to filter out defective businesses by introducing a strict and correct project evaluation system by dividing it into before and after. Furthermore, it is necessary to establish ecological restoration as an industry and leave the process in the principles of the market.

A Study on the Performance Analysis of AIoT High-Efficiency Streetlamp for Carbon Emissions (탄소배출권용 AIoT 고효율 가로등 성능분석 연구)

  • Seung-Ho Park;Seong-Uk Shin;Kyung-Sunl Yoo
    • Journal of Advanced Technology Convergence
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    • v.2 no.4
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    • pp.13-19
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    • 2023
  • Following the signing of the Paris Agreement on Climate Change (UNFCCC, 2015), the world is expanding greenhouse gas reduction activities through comprehensive participation that includes not only developed countries but also developing countries. Major countries around the world are placing high expectations on the effectiveness of total carbon emissions regulation through the carbon emissions market. However, in order to obtain carbon credits, third-party verification is required based on quantitative carbon reduction data. Accordingly, in this paper, we developed an AIoT high-efficiency street light for carbon emissions and conducted a performance analysis study to measure the luminous efficiency of the lighting fixture. To obtain carbon emissions rights, we used high-efficiency LED PKG, developed our own high-voltage PFC, and developed high-efficiency lighting fixtures capable of communication. For communication, the 2.4GHz LoRa method was adopted between the lighting fixture and the gateway. Lens design was conducted through simulation of Korea Expressway Corporation's standard streetlight types A, B, and C. The performance of the streetlight was verified as being more efficient than other existing products through the measurement of luminous efficiency by an accredited rating agency, and it is expected that carbon emissions rights will be obtained by reducing electrical energy through this.

Evaluation of Bonding Performance of Hybrid Materials According to Laser and Plasma Surface Treatment (레이저 및 플라즈마 표면처리에 따른 이종소재 접합특성평가)

  • Minha Shin;Eun Sung Kim;Seong-Jong Kim
    • Composites Research
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    • v.36 no.6
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    • pp.441-447
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    • 2023
  • Recently, as demand for high-strength, lightweight materials has increased, there has been great interest in joining with metals. In the case of mechanical bonding, such as bolting and riveting, chemical bonding using adhesives is attracting attention as stress concentration, cracks, and peeling occur. In this paper, surface treatment was performed to improve the adhesive strength, and the change in adhesive strength was analyzed. For the adhesive strength test were conducted with Carbon Fiber Reinforced Plastic(CFRP), CR340(Steel), and Al6061(Aluminum), and laser and plasma surface treatment were used. After plasma surface treatment, the adhesive strength improved by 7.3% and 39.2% in CFRP-CR340 and CFRP-Al6061, respectively. CR340-Al6061 was improved by 56.2% in laser surface treatment. Surface free energy(SFE) was measured by contact angle after plasma treatment, and it is thought that the adhesion strength was improved by minimizing damage through a chemical reaction mechanism. For laser surface treatment, it is thought that creates a rough bonding surface and improves adhesive strength due to the mechanical interlocking effect. Therefore, surface treatment is effect to improve adhesive strength, and based on this paper, the long-term fatigue test will be conducted to prevent fatigue failure, which is a representative cause of actual structural damage.