• Title/Summary/Keyword: elemental analysis

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Measurement and Analysis of Visibility lmpairment during June, 1994 in Seoul (1994년 6월 서울지역 시정장애의 측정 및 분석)

  • 백남준;이종훈;김용표;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.407-419
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    • 1996
  • Characteristics of visual air quality in Seoul have been investigated between June 13 and 21, 1994. Optical properties (extinction coefficient and particle scattering coefficient), meteorological parameters (relative humidity, temperature, wind speed, wind direction, and cloud cover), particle characteristics (mass size distribution, components) were measured and analyzed. During measurement periods, northwest wind with less than 2m/sec of wind speed deteriorates visibility. Effects of relative humidity are though to be not a direct factor which influence to visibility through the size change due to hygroscopic species in aerosol. During the smoggy period both the aerosol mass concentration and fine particle fraction of the size distribution are increased compared to the clear period. Sulfate, organic carbon, and elemental carbon in aerosol are the major species in determining the occurrence and severity of a smog in Seoul.

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A Study of Debinding Behavior and Microstructural Development of Sintered Al-Cu-Sn Alloy

  • Kim, J.S.;Chang, I.T.;Falticeanu, C.L.;Davies, G.J.;Jiang, K.C.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.722-723
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    • 2006
  • A new method has been developed to fabricate microcomponents by a combination of photolithography and sintering of metallic powder mixtures, without the need for compression and the addition of Mg. This involves (1) the fabrication of a micromould, (2) mould filling of the powder/binder mixture, (3) debinding and (3) sintering. The starting powdered materials consisted of a mixture of aluminium powder(average size of 2.5 um) and alloying elemental powder of Cu and Sn(less than 70nm), at appropriate proportions to achieve nominal compositions of Al-6wt%Cu, Al-6wt%Cu-3wt%Sn. This paper presents detailed investigation of debinding behaviour and microstructural development.

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Synthesis of Hexyltriphenylphosphonium-TCNQ Complex and Stability in Spreading Solvent (Hexyltriphenylphonium-TCNQ 착물(錯物)의 합성(合成)과 분산용매 중에서의 안정성)

  • Han, Jong-Soo;Hwang, Kyo-Hyeon;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.115-118
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    • 1995
  • Hexyltriphenylphosphonium-TCNQ(HTPP-TCNQ) complex for preparing organic thin film by Langmuir-Blodgett technique was synthesized from LiTCNQ and Hexyltriphenylphosphonium bromide. The structure of the new complex was confirmed by $^{1}H$ NMR, $^{31}P$ NMR, IR, UV spectroscopies, TGA and elemental analysis. A stability to spreading solvent, which is acetonitrile, ethylacetate, ethanol and acetonitrile-ethylacetate(1:1 v/v), of HTPP-TCNQ complex was investigated by UV-visible spectrophotometer. The complex was stabilized in acetonitrile, ethylacetate, aceton, acetonitrile-ethylacetate (1:1 v/v) for 6 h.

Synthesis of New Triazolyl-N,N-Dialkyldithiocarbamates as Antifungal Agents

  • Ozkirimli Sumru;Apak T. Idil;Kiraz Muammer;Yegenoglu Yildiz
    • Archives of Pharmacal Research
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    • v.28 no.11
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    • pp.1213-1218
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    • 2005
  • N,N-Dialkylditihiocarbamate derivatives have been well known as broad-range fungicides. In this study, the triazole derivatives of ten new N,N-disubstituted dithiocarbamates (3a-j) were synthesized and their structures were identified by spectral and elemental analysis. Results of the antifungal activity studies showed that some of the compounds tested were active against M. canis, M. gypseum, and T rubrum at the concentration of 12.5 $\mu$g/mL when c1otrimazol was used as a standard.

Studies on the Components of Fruits of Forsythia Koreana NAKAI (III). Occurrence of Ursolic Acid in the Fruits of Forsythia Koreana (Forsythia Koreana NAKAI 씨 (토연교)의 성분에 관한 연구 (III). Ursolic acid의 분리 및 확인)

  • Sae Hee Chang;Jae Soon Kim
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.444-449
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    • 1973
  • From the methanol extract of the fruits of Forsythia Koreana NAKAI a sapogenin and its derivatives were isolated. Through the mass spectra, ultraviolet spectra, nuclear magnetic resonance spectra, elemental analysis and chemical tests it was identified as ursolic acid.

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Synthesis and Characterization of Substituted Pyridine Complexes of Molybdenum (III). Pyridinium and 3,5-Lutidine Complexes of Oxomolybdenum(V) (몰리브덴의 피리딘계 착물합성과 그 성질 (제3보) 몰리브덴(V)의 피리딘 및 3,5-루티딘착물)

  • Sang Oh Oh;Chang Su Kim
    • Journal of the Korean Chemical Society
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    • v.26 no.2
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    • pp.73-80
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    • 1982
  • The pyridine and 3,5-lutidine complexes of quinquevalent molybdenum have been prepared. The infrared, electronic and reflectance spectra and magnetic susceptibility data of the complexes are reported. It is found that the binuclear complexes contain the di-${\mu}$-oxo-dimolybdenum(V) group, $MoO_2Mo$, and the possible structures are proposed on the basis of elemental analysis and physical measurements.

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Thiadiazole Derivatives as Potential Anticonvulsant Agents

  • Mullick, Pooja;Khan, Suroor A.;Verma, Surajpal;Alam, Ozair
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.1011-1016
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    • 2011
  • A series of thiadiazole derivatives were synthesized with differently substituted benzoic acids which were cyclized to give differently substituted thiazolidin-4-one. Elemental analysis, IR, $^1H$ NMR, $^{13}C$ NMR and mass spectral data confirmed the structure of the synthesized compounds. The derivatives of these moieties were evaluated for anticonvulsant activity by MES model and neurotoxicity by rotarod method. The synthesized compounds showed good potential for anticonvulsant activity besides this, the compounds also showed neurotoxic effect. It was observed that compounds with $OCH_3$ at 3, 4 position of phenyl ring [5(a-l)] showed less protection against convulsions as compared to compounds having unsubstituted phenyl ring [4(a-l)].

Synthesis of Some New Biologically Active Benzothiazole Derivatives Containing Benzimidazole and Imidazoline Moieties

  • Chaudhary, Manish;Pareek, Deepak;Pareek, Pawan K.;Kant, Ravi;Ojha, Krishan G.;Pareek, Arun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.131-136
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    • 2011
  • Synthesis of N-(1H-benzimidazol-2-yl)-6-substituted-1,3-benzothiazol-2-amines and 6-substituted-N-(4,5-dihydro-1H-imidazol-2-yl)-1,3-benzothiazol-2-amines by the reaction of substituted 2-aminobenzothiazoles with carbon disulphide and methyl iodide followed by the reaction with o-phenylene diamine/ethylene diamine are reported. All the synthesized compounds were characterized by elemental analysis, IR spectra and $^1H$ NMR spectral studies. The potent antibacterial and entomological (antifeedant, acaricidal, contact toxicity and stomach toxicity) activities of the synthesized compounds were investigated.

Synthesis and Spectroscopic Characterization of the New Sitting-atop Complexes from Reaction of Zirconyl Nitrate and Free Base meso-Tetraarylporphyrins in Mild Conditions

  • Dehghani, Hossein;Mansournia, Mohammad Reza
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1715-1718
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    • 2009
  • A series of sitting-atop (SAT) complexes, [(ZrO)$H_2t(X)pp(NO_3)_2$], have been prepared via the reactions of free base meso-tetraarylporphyrins, $H_2$t(X)pp, with zirconyl nitrate hydrate, ZrO(N$O_3)_2{\cdot}xH_2$O. The products have been characterized by a variety of methods including $^1H\;NMR,\;^{13}C$ NMR, IR and UV-Vis spectroscopies, elemental analysis and conductance measurements. The data indicate that the meso-tetraarylporphyrins coordinate with two pyrrolenine nitrogen atoms to the zirconyl cation located above the distorted porphyrin plane and two protons remain on the pyrrole nitrogens. Such half sandwich-type sitting-atop complexes may be considered as models for the initial steps of the metallation of the macrocycles.

Synthesis and Characterization of Three-dimensional Polymer Produced by Mutual Condensation of Ethylenediamine and $C_{60}$

  • Vovk, O.;Lee, Joong-Kee
    • Carbon letters
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    • v.5 no.2
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    • pp.68-74
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    • 2004
  • The polymer with contents of $C_{60}$ up to 57 wt.% was produced by mutual condensation of fullerene $C_{60}$ and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.

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