• 제목/요약/키워드: electrode impedance

검색결과 688건 처리시간 0.027초

Bi계 ZnO 칩 바리스터의 저온소결과 전기적 특성 (Low Temperature Sintering and Electrical Properties of Bi-based ZnO Chip Varistor)

  • 홍연우;신효순;여동훈;김진호
    • 한국전기전자재료학회논문지
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    • 제24권11호
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    • pp.876-881
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    • 2011
  • The sintering, defect and grain boundary characteristics of Bi-based ZnO chip varistor (1,608 mm size) have been investigated to know the possibility of lowering a manufacturing price by using 100 % Ag inner-electrode. The samples were prepared by general multilayer chip varistor process and characterized by shrinkage, SEM, current-voltage (I-V), admittance spectroscopy (AS), impedance and modulus spectroscopy (IS & MS) measurement. There are no problems to make a chip varistor with 100% Ag inner-electrode in the sintering temperature range of 850~900$^{\circ}C$ for 1 h in air. A good varistor characteristics ($V_n$= 9.3~15.4 V, a= 23~24, $I_L$= 1.0~1.6 ${\mu}A$) were revealed but formed $Zn_i^{{\cdot}{\cdot}}$(0.209 eV) as dominant defect, and increased the distributional inhomogeneity and the temperature instability in grain boundary barriers.

반구형 전극계에서 뇌임펄스전압에 의한 토양의 종류별 이온화 특성 (Ionization Behaviors by Types of Soil due to Lightning Impulse Voltages in a Hemishperical Electrode System)

  • 이규선;박건훈;김회구;이복희
    • 전기학회논문지
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    • 제58권1호
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    • pp.119-125
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    • 2009
  • This paper deals with the characteristics of soil ionization affecting the dynamic performance of grounding systems under lightning impulse voltage. A concentric hemispherical electrode system was employed in order to facilitate the field calculation and analysis of the experimental results. The parameters such as the ionization threshold and breakdown field intensity, the pre-ionization and the post ionization resistances, the time-lag to ionization, the transient impedance, the equivalent ionized radius for various soil media were measured and analyzed. The dynamic characteristics of ionization processes under lightning impulse voltage are strongly dependent on the types of soil and water content. As a result, a soil ionization reduces the ground resistance and there is a little effect of applied impulse polarity on the soil ionization threshold field intensity. Although the ionization threshold field intensity of wet clay with 30% water content is the highest, its ionized zone was found to be the smallest amongst the test samples.

피부 활성점 측정을 위한 회로설계 및 측정방법연구 (A Study on the circuit design and measurement method for the measurement of active points on skin)

  • 김민수;조영창
    • 전기전자학회논문지
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    • 제24권3호
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    • pp.713-718
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    • 2020
  • 피부 활성점(경혈) 측정 방법은 편리성, 저비용 및 비 침습으로 측정하기 때문에 많은 생체정보를 얻기 위한 기술이다. 본 연구에서는 피부 아래에 활성점을 측정할 수 있는 장점이 있는 3전극 측정방법을 사용되었다. 임피던스측정방법은 측정실험 결과와 관련성이 있는 등가전기회로를 통해서 증명되었다. 활성점의 특성주파수는 주변 피부보다 15-30Hz 높고, 리액턴스는 35-77kΩ 더 작게 측정되었다. 이 기술은 비침습 측정 시스템을 이용해서 활성점과 주변피부의 리액턴스와 특성주파수를 정확하고 객관적으로 분석되었다.

The Thioacetate-Functionalized Self-Assembled Monolayers on Au: Toward High-Performance Ion-Selective Electrode for Ag+

  • Jin, Jian;Zhou, Wei-Jie;Chen, Ying;Liu, Yi-Long;Sun, Xiao-Qiang;Xi, Hai-Tao
    • Bulletin of the Korean Chemical Society
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    • 제35권2호
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    • pp.601-604
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    • 2014
  • Two classes of morpholino-substitued thioacetate have been successfully synthesized and their electrochemical properties of self-assembled monolayers (SAMs) on Au electrode are measured by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The barrier property of the SAMs-modified surfaces is evaluated by using potassium ferro/ferri cyanide. The results suggest that the arenethioacetate forms higher-quality close-packed blocking monolayers in comparison with alkanethioacetate. Furthermore, it has shown that the barrier properties of these monolayers can be significantly improved by mixed SAMs formation with decanethiol. From our experimental results we find that the electron transfer reaction of $[Fe(CN)_6]^{3/4-}$ redox couple occurs predominantly through the pinholes and defects present in the SAM and both SAMs show a good and fast capacity in recognition for $Ag^+$. The morphological and elementary composition have also been examined by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS).

Use of Inner Ionomer Solution in Preparing Membrane-Electrode Assembly (MEA) for Fuel Cells and Its Characterization

  • Seo, Seok-Jun;Woo, Jung-Je;Yun, Sung-Hyun;Park, Jin-Soo;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • 제10권1호
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    • pp.46-52
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    • 2008
  • Optimization of ionomer solution was conducted in order to improve the performance of MEAs in PEMPC. The interface between membrane and electrodes in MEAs is crucial region determining fuel cell performance as well as ORR reaction at cathode. Through the modification of Nafion ionomer content at the interface between membrane and electrodes, an optimal content was obtained with Nafion 115 membranes. Two times higher current density was obtained with the outer Nafion sprayed MEA compared with the non-sprayed one. In addition, the symmetrical impedance spectroscopy mode (SM) exhibited that the resistances of membrane area, proton hydration, and charge transfer decreased as the outer Nafion is sprayed. From the polarization curves and SM, the highest current density and the lowest resistance was obtained at the outer ionomer content of $0.15\;mg\;cm^{-2}$.

Fetal Bovine Serum을 포함한 세포 배양액에 담근 Indium Tin Oxide 전극 계면의 전기화학적 특성 (Electrochemical Properties of Indium Tin Oxide Electrodes Immersed in a Cell Culture Medium with Fetal Bovine Serum)

  • 최원석;조성보
    • 대한의용생체공학회:의공학회지
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    • 제34권1호
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    • pp.34-39
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    • 2013
  • For the biocompatibility test of implantable devices or for the sensitivity evaluation of biomedical sensors, it is required to understand the mechanism of the protein adsorption and the interaction between the adsorbed proteins and cells. In this study, the adsorption of proteins in a cell culture medium with fetal bovine serum onto an indium tin-oxide electrode was characterized by using linear sweep voltammetry and impedance spectroscopy. We immersed the fabricated ITO electrodes in the culture medium for 30, 60, or 90 min, and then measured the electrochemical properties of electrodes with 10 mM $Fe(CN){_6}^{3-/4-}$ and 0.1 M KCl electrolyte. With an increase of contacting time, the anodic peak current was decreased and the charge transfer resistance was increased. However, both parameters were recovered to the values before contact with the medium after the treatment of Trypsin/Ethylenediaminetetraacetic acid hydrolyzing proteins.

이중층 티타늄 전극으로 구성된 TCO-less 염료감응형 태양전지 제작에 관한 연구 (Fabrication of Transparent Conductive Oxide-less Dye-Sensitized Solar Cells Consisting of Titanium Double Layer Electrodes)

  • 심충환;김윤기;김동현;이해준;이호준
    • 전기학회논문지
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    • 제60권1호
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    • pp.114-118
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    • 2011
  • Dye-Sensitized Solar Cells(DSSCs) consist of a titanium dioxide($TiO_2$) nano film of the photo electrode, dye molecules on the surface of the $TiO_2$ film, an electrolyte layer and a counter electrode. But two transparent conductive oxide(TCO) substrates are estimated to be about 60[%] of the total cost of the DSSCs. Currently novel TCO-less structures have been investigated in order to reduce the cost. In this study, we suggested a TCO-less DSSCs which has titanium double layer electrodes. Titanium double layer electrodes are formed by electron-beam evaporation method. Analytical instruments such as electrochemical impedance spectroscopy, scanning electron microscope were used to evaluate the TCO-less DSSCs. As a result, the proposed structure decreases energy conversion efficiency and short-circuit current density compared with the conventional DSSCs structure with FTO glass, while internal series impedance of TCO-less DSSCs using titanium double layer electrodes decreases by 27[%]. Consequently, the fill factor is improved by 28[%] more than that of the conventional structure.

AN IMPROVED ELECTRICAL-CONDUCTANCE SENSOR FOR VOID-FRACTION MEASUREMENT IN A HORIZONTAL PIPE

  • KO, MIN SEOK;LEE, BO AN;WON, WOO YOUN;LEE, YEON GUN;JERNG, DONG WOOK;KIM, SIN
    • Nuclear Engineering and Technology
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    • 제47권7호
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    • pp.804-813
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    • 2015
  • The electrical-impedance method has been widely used for void-fraction measurement in two-phase flow due to its many favorable features. In the impedance method, the response characteristics of the electrical signal heavily depend upon flow pattern, as well as phasic volume. Thus, information on the flow pattern should be given for reliable void-fraction measurement. This study proposes an improved electrical-conductance sensor composed of a three-electrode set of adjacent and opposite electrodes. In the proposed sensor, conductance readings are directly converted into the flow pattern through a specified criterion and are consecutively used to estimate the corresponding void fraction. Since the flow pattern and the void fraction are evaluated by reading conductance measurements, complexity of data processing can be significantly reduced and real-time information provided. Before actual applications, several numerical calculations are performed to optimize electrode and insulator sizes, and optimal design is verified by static experiments. Finally, the proposed sensor is applied for air-water two-phase flow in a horizontal loop with a 40-mm inner diameter and a 5-m length, and its measurement results are compared with those of a wire-mesh sensor.

콘크리트 구조의 재료 물성 재구성을 위한 전기 임피던스 단층촬영 기법 (Electrical Impedance Tomography for Material Profile Reconstruction of Concrete Structures)

  • 정봉구;김보영;강준원;황진하
    • 한국전산구조공학회논문집
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    • 제32권4호
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    • pp.249-256
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    • 2019
  • 이 논문은 재료의 전기 전도도 분포를 재구성하는 전기임피던스 단층이미지 기법(electrical impedance tomography; EIT)을 제시한다. 이 문제는 구조물 표면의 전극에서 측정된 전위와 계산된 전위의 차를 최소화하여 전기 전도도의 공간적 분포를 재구성하는 최적화 문제로 정의된다. 전류 입력 시 전위를 구하는 정해석 문제의 수학적 모델로서 완전전극모델(complete electrode model; CEM)을 사용하였다. 완전전극모델은 전기 포텐셜에 대한 라플라스 방정식과 전류 입력에 따른 경계조건들로 구성되는 경계값 문제이다. 완전전극모델 해의 정확성을 검증하기 위하여 유한요소법을 이용해 구한 원형 구조물의 전위해와 Technology Computer Aided Design(TCAD) 소프트웨어를 사용해 얻은 결과를 비교하였다. 완전전극모델의 지배방정식과 경계조건을 구속조건으로 하는 최적화 문제를 라그랑주 승수법(lagrange multiplier method)을 이용해 비구속 최적화 문제로 전환하고 라그랑지안의 1차 최적화 조건으로부터 전극에서의 전위 차를 최소화하는 최적의 전기전도도 분포를 도출하였다. 원형 균일영역의 전기 전도도 분포를 재구성하는 역해석 예제를 통해 완전전극모델 기반 EIT 프레임워크의 적용성을 검토하였다.

External cross-validation of bioelectrical impedance analysis for the assessment of body composition in Korean adults

  • Kim, Hyeoi-Jin;Kim, Chul-Hyun;Kim, Dong-Won;Park, Mi-Ra;Park, Hye-Soon;Min, Sun-Seek;Han, Seung-Ho;Yee, Jae-Yong;Chung, So-Chung;Kim, Chan
    • Nutrition Research and Practice
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    • 제5권3호
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    • pp.246-252
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    • 2011
  • Bioelectrical impedance analysis (BIA) models must be validated against a reference method in a representative population sample before they can be accepted as accurate and applicable. The purpose of this study was to compare the eight-electrode BIA method with DEXA as a reference method in the assessment of body composition in Korean adults and to investigate the predictive accuracy and applicability of the eight-electrode BIA model. A total of 174 apparently healthy adults participated. The study was designed as a cross-sectional study. FM, %fat, and FFM were estimated by an eight-electrode BIA model and were measured by DEXA. Correlations between BIA_%fat and DEXA_%fat were 0.956 for men and 0.960 for women with a total error of 2.1%fat in men and 2.3%fat in women. The mean difference between BIA_%fat and DEXA_%fat was small but significant (P < 0.05), which resulted in an overestimation of $1.2{\pm}2.2$%fat (95% CI: -3.2-6.2%fat) in men and an underestimation of $-2.0{\pm}2.4$%fat (95% CI: -2.3-7.1%fat) in women. In the Bland-Altman analysis, the %fat of 86.3% of men was accurately estimated and the %fat of 66.0% of women was accurately estimated to within 3.5%fat. The BIA had good agreement for prediction of %fat in Korean adults. However, the eight-electrode BIA had small, but systemic, errors of %fat in the predictive accuracy for individual estimation. The total errors led to an overestimation of %fat in lean men and an underestimation of %fat in obese women.