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Fabrication of Transparent Conductive Oxide-less Dye-Sensitized Solar Cells Consisting of Titanium Double Layer Electrodes

이중층 티타늄 전극으로 구성된 TCO-less 염료감응형 태양전지 제작에 관한 연구

  • Received : 2010.11.30
  • Accepted : 2010.12.12
  • Published : 2011.01.01

Abstract

Dye-Sensitized Solar Cells(DSSCs) consist of a titanium dioxide($TiO_2$) nano film of the photo electrode, dye molecules on the surface of the $TiO_2$ film, an electrolyte layer and a counter electrode. But two transparent conductive oxide(TCO) substrates are estimated to be about 60[%] of the total cost of the DSSCs. Currently novel TCO-less structures have been investigated in order to reduce the cost. In this study, we suggested a TCO-less DSSCs which has titanium double layer electrodes. Titanium double layer electrodes are formed by electron-beam evaporation method. Analytical instruments such as electrochemical impedance spectroscopy, scanning electron microscope were used to evaluate the TCO-less DSSCs. As a result, the proposed structure decreases energy conversion efficiency and short-circuit current density compared with the conventional DSSCs structure with FTO glass, while internal series impedance of TCO-less DSSCs using titanium double layer electrodes decreases by 27[%]. Consequently, the fill factor is improved by 28[%] more than that of the conventional structure.

Keywords

References

  1. B. O'Regan and M. Gratzel, "A low-cost, high-efficiency solar cell based on dye-sensitized colloidal $TiO_2$ films", Nature, Vol 353, pp. 737-740, Oct. 1991. https://doi.org/10.1038/353737a0
  2. Y. Chiba, A. Islam, Y. Watanabe, R. Komiya, N. Koide and L. Han, "Dye-Sensitized Solar Cells with Conversion Efficiency of 11.1%", Japanese Journal of Applied Physics, Vol. 45, No. 25, pp. L638-L640, 2006. https://doi.org/10.1143/JJAP.45.L638
  3. H. Greijer, L. Karlson, S.-T. Lindquist, A. Hagfeldt, "Environmental aspects of electricity generation from a nanocrystalline dye sensitized solar cell system", Renewable Energy, Vol. 23, pp. 27-39, 2001. https://doi.org/10.1016/S0960-1481(00)00111-7
  4. J. M. Kroon, N. J. Bakker, H. J. P. Smit, P. Liska, K. R. Thampi, P. Wang, S. M. Zakeeruddin, M. Graetzel, A. Hinsch, S. Hore, U. Wurfel, R. Sastrawan, J. R. Durrant, E. Palomares, H. Pettersson, T. Gruszecki, J. Walter, K. Skupien, and G. E. Tulloch, "Nanocrystalline Dye-sensitized Solar Cells Having Maximum Performance", Progress In Photovoltaics: Research And Applications, Vol 15, pp. 1-18, 2007. https://doi.org/10.1002/pip.707
  5. 팽성환, 김두환, 박민우, 성열문, "티타늄 메쉬 전극구조 를 이용한 염료 태양전지 제작", 대한 전기학회 논문지, 12호, 제 58권, pp. 2436-2440, 2009. 12.
  6. Y. Kashiwa, Y. Yoshida and S. Hayase, "All-metal-electrode-type dye sensitized solar cells (transparent conductive oxide-less dye sensitized solar cell) consisting of thick and porous Ti electrode with straight pores", Applied Physics Letters, Vol, 92, 033308, 2008. https://doi.org/10.1063/1.2837633
  7. K. Onoda, S. Ngamsinlapasathian, T. Fujieda, and S. Yoshikawa, "The superiority of Ti plate as the substrate of dye-sensitized solar cells", Solar Energy Materials & Solar Cells, Vol. 91, pp. 1176-1181, 2007. https://doi.org/10.1016/j.solmat.2006.12.017
  8. N. Fuke, A. Fukui, Y. Chiba, R. Komiya, R.Hamanaka, and L. Han, "Back Contact Dye-Sensitized Solar Cells", Japanese Journal of Applied Physics, Vol. 46, No. 18, pp. L420-L422, 2007. https://doi.org/10.1143/JJAP.46.L420
  9. 김윤기, 심충환, 김현규, 성열문, 김동현, 이해준, 박정후, 이호준, "전자빔 증착법에 의한 티타늄 전극 구조 염료 태양전지 제작에 관한 연구", 대한 전기학회 논문지, 4호, 제 59권, pp. 754-758, 2010.
  10. N. Koide, A. Islam, Y. Chiba, L. Han, "Improvement of efficiency of dye-sensitized solar cells based on analysis of equivalent circuit", J. Photochem. Photobio. A Chem. 182, pp. 296-305, 2006 https://doi.org/10.1016/j.jphotochem.2006.04.030
  11. L. Han, N. Koide, Y. Chiba, and T. Mitate, "Modeling of an equivalent circuit for dye-sensitized solar cells", Appl. Phys. Lett. 84, pp. 2433-2435, 2004 https://doi.org/10.1063/1.1690495
  12. L. Han, N. Koide, Y. Chiba, A. Islam, R. Komiya, N. Fuke, A. Fukui, and R. Yamanaka, "Improvement of efficiency of dye-sensitized solar cells by reduction of internal resistance", Applied Physics Letters 86, pp. 213501, 2005 https://doi.org/10.1063/1.1925773