• 제목/요약/키워드: electrode activation

검색결과 194건 처리시간 0.025초

Effects of pore structures on electrochemical behaviors of polyacrylonitrile-based activated carbon nanofibers by carbon dioxide activation

  • Lee, Hye-Min;Kim, Hong-Gun;An, Kay-Hyeok;Kim, Byung-Joo
    • Carbon letters
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    • 제15권1호
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    • pp.71-76
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    • 2014
  • Activated carbon nanofibers (ACNF) were prepared from polyacrylonitrile (PAN)-based nanofibers using $CO_2$ activation methods with varying activation process times. The surface and structural characteristics of the ACNF were observed by scanning electron microscopy and X-ray diffraction, respectively. $N_2$ adsorption isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. As experimental results, many holes or cavernous structures were found on the fiber surfaces after the $CO_2$ activation as confirmed by scanning electron microscopy analysis. Specific surface areas and pore volumes of the prepared ACNFs were enhanced within a range of 10 to 30 min of activation times. Performance of the porous PAN-based nanofibers as an electrode for electrical double layer capacitors was evaluated in terms of the activation conditions.

Lithium intercalation into a plasma-enhanced-chemical-vapour-deposited carbon film electrode

  • Pyun Su-II
    • 전기화학회지
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    • 제2권1호
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    • pp.38-45
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    • 1999
  • Electrochemical lithium intercalation into a PECVD (plasma enhanced chemical vapour deposited) carbon film electrode was investigated in 1 M $LiPF_6-EC$ (ethylene carbonate) and DEC (diethyl carbonate) solution during lithium intercalation and deintercalation, by using cyclic voltammetry supplemented with ac-impedance spectroscopy. The size of the graphitic crystallite in the a- and c-axis directions obtained from the carbon film electrode was much smaller than those of the graphite one, indicating less-developed crystalline structure with hydrogen bonded to carbon, from the results of AES (Auger electron spectroscopy), powder XRD (X-ray diffraction) method, and FTIR(Fourier transform infra-red) spectroscopy. It was shown from the cyclic voltammograms and ac-impedance spectra of carbon film electrode that a threshold overpotential was needed to overcome an activation barrier to entrance of lithium into the carbon film electrode, such as the poor crystalline structure of the carbon film electrode showing disordered carbon and the presence of residual hydrogen in its structure. The experimental results were discussed in terms of the effect of host carbon structure on the lithium intercalation capability.

검도 머리치기 동작의 근전도 및 운동학적 분석 (The Analysis of Electromyography and Kinematic of Kumdo Player's Head Hitting)

  • 박종율
    • 한국운동역학회지
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    • 제15권1호
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    • pp.63-74
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    • 2005
  • J. R. PARK. The Analysis of Electrimyography and Kinematic of Kumdo Player's Head Hitting. Korean Journal of Sport Biomechanics, Vol. 15, No. 1, pp. 63-74, 2005. The purpose of this study were to describe and compare the selected electromyographical muscle activities of arm and kinematic data of kumdo player's head hitting. Using surface electrode electromyography, we evaluated muscle activity in 6 male players during head hitting motion. Surface electrodes were used to record the level of muscle activity in the carpi radialis, deltoid, triceps, biceps muscles during the player's head hitting. These signals were compared with %RVC(Reference voluntary contraction) which was normalized by IEMG(Integrated EMG). The kumdo head hitting motion was divided into two phases: back swing, down swing. we observed patterns of arm muscle activity throughout two phases of the kumdo head hiting The results can be summarized as follows: right elbow angle had decreased and left deltoid muscle's activation had higher than right deltoid muscle's activation, right carpi radialis muscle's activation had higher than left carpi radialis muscle's activation in back swing phase, knee angle had decreased and left triceps muscle's activation had higher than right triceps muscle's activation, right deltoid muscle's activation had higher than left deltoid muscle's activation, right carpi radialis muscle's activation had higher than left carpi radialis muscle's activation in down swing phase

Supercapacitor 전극용 최적의 mesoporous carbon 합성을 위한 PVDC-resin 전구체로 부터 CuO를 이용한 화학적 활성화 과정 연구 (Study on the chemical activation process from PVDC-resin with CuO agent to synthesize mesoporous carbon for supercapacitor electrodes)

  • 전상은
    • 한국표면공학회지
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    • 제57권4호
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    • pp.285-295
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    • 2024
  • PVDC-resin transforms into porous carbon through the removal of heteroatoms during heat treatment. When PVDC-resin mixed with chemical agent undergoes heat treatment, it transforms into porous carbon with a significant surface area. In this study, we aim to produce porous carbon using PVDC-resin as a precursor by mixing it with an inexpensive CuO agent in various ratios (1:1, 1:2) and varying the process temperatures (750℃, 950℃). To utilize the developed porous carbon as electrode for supercapacitors, this study explored the formation of micropores and mesopores during the activation process. The porous characteristics and specific surface area of the synthesized porous carbon were estimated using N2 isotherm. The specific capacitance and rate capability required for supercapacitor electrodes were evaluated through cyclic voltammetry. Experimental results demonstrated that when the precursor and agent were mixed in a 1:2 ratio, a high surface areal carbon with numerous micropores and mesopores was obtained. When the activation was performed at 950℃, no impurities remained from the agent, resulting in high rate performance. The porous carbon synthesized using PVDC-resin and CuO demonstrated high specific surface area and excellent rate capability, indicating its potential as an electrode material for supercapacitors.

침 근전도로 측정한 만성 요통 환자의 어깨 굴곡시 나타나는 다열근 활성도 비교 (A Study on multifidus muscle activation by Needle EMG during shoulder flexion in Chronic Low Back Pain Patients)

  • 장원석
    • 대한물리치료과학회지
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    • 제18권3호
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    • pp.63-69
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    • 2011
  • Purpose : The purpose of study is activation of lumbar multifidus muscle by needle EMG during shoulder flexion in chronic low back pain patients. The subject were consisted of 10 women patients with chronic low back pain and healthy asymtomatic subject 10 women. Methods : 10 women patients with chronic low back pain and healthy asymptomatic subject 10 women is voluntary participated for the research. Subjects were positioned in standing. The needle EMG were measured activation of multifidus. Needle electrode was used to 28 gauge. The shoulder flexion movement used to activate the multifidus was then measured. Results : Results of the analysis showed that asymptomatic subjects had significantly larger multifidus muscle activation compared with CLBP subjects during shoulder flexion. Conclusion : This study will be used as multifidus measurement method of patient with chronic LBP. The multifidus muscle in chronic LBP patient clinical significance. Most of chronic LBP patients have multifidus contraction pattern. Therefore chronic LBP patients necessary multifidus activation measurement with needle EMG.

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Si-sealant를 이용하여 제조한 금속수소화물 전극의 특성 (The Properties of the Metal Hydride electrodes prepared by Silicon Sealant)

  • 최전;박충년
    • 한국수소및신에너지학회논문집
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    • 제4권2호
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    • pp.23-28
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    • 1993
  • The $(LM)Ni_{4.5}Co_{0.1}Mn_{0.2}Al_{0.2}$ hydrogen storage alloy powders were conducted 25wt% electroless copper plating in an acidic bath. For the preparation of a hydride electrodes, the copper coated alloy powder was mixed with Si-sealant(organosilicon) and compacted with $6t/cm^2$ at room temperature. The electrode characteristics were examined through electrochemical measurements in a half cell. As a sealant contents increased, the initial discharge capacity of si-sealant bounded electrode was lower and the activation rate in high current density was slower. For extended cycles, however, the electrodes with the Si-sealant were superior in a high rate discharge and useful range of temperature over the sealant-free electrode. In addition, the cycle life increased with increasing the amount of Si-sealant added. It can be suggested from the results that the Si-sealant as a binder could be applied to the preparation of the metal hydride electrode.

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근활성도(EMG) 측정 전극 레이어 설계에 따른 성능 및 안정성 평가 (Performance and Stability Evaluation of Muscle Activation (EMG) Measurement Electrodes According to Layer Design)

  • 구본학;이동희;김주용
    • 감성과학
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    • 제26권4호
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    • pp.41-50
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    • 2023
  • 본 연구는 EMG(electromyography) 텍스타일 전극 개발을 목적으로 레이어 수의 디자인 및 원단을 다르게 하여 성능 및 신호 획득 안정성을 평가한다. 레이징 및 프레스 공정을 통하여 텍스타일 전극을 제조하며 Layer-0, Layer-1, Layer-2로 레이어 유무 및 수에 따른 결과를 분석했다. 이에 레이어 유무에 따라서는 근활성 측정에 영향을, 수가 많을수록 높은 성능이 나타남을 확인할 수 있었다. Layer-2 구조로 통일하여 5가지의 원단(네오프렌, 스판덱스 쿠션, 폴리에스테르 100%, 나일론 스판덱스, 광목 캔버스)으로 전극을 제조해 실험해 보았다. 성능적인 면에서, 원단의 중량이 높은 나일론 스판덱스가 높은 성능을 보였으며, 스판쿠션 텍스타일 전극이 근활성도 수득에 높은 안정성을 보였다. 이에 위 연구는 레이어에 따른 성능 연관성과 전극-피부사이의 닿는 면적 간의 관계 등을 고찰하여 슬리브 전체의 의복압을 늘리는 대신 특정 센서 측정 부위에만 높은 압력을 가함으로 차후 연구에서 레이어의 수 및 물성에 따른 전극의 공학적 설계 가능성을 제시한 의의가 있다.

Synthesis of Activated Carbon from a Bio Waste (Flower of Shorea Robusta) Using Different Activating Agents and Its Application as Supercapacitor Electrode

  • Ghosh, Souvik;Samanta, Prakas;Murmu, Naresh Chandra;Kim, Nam Hoon;Kuila, Tapas
    • Composites Research
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    • 제35권1호
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    • pp.1-7
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    • 2022
  • The activated carbon is a very good choice for using as supercapacitor electrode materials. Herein, the flower of Shorea robusta, a bio-waste material was successfully used to synthesize the activated carbons for application as supercapacitor electrode materials. The activated carbon was synthesized through chemical activation process followed by thermal treatment at 700℃ in presence of N2 atmosphere using KOH, ZnCl2 and H3PO4 as the activating agents. The physicochemical analyses demonstrate that the obtained activated carbons are graphitic in nature and the degree of disorder of the graphitic carbons is changed with the activating agents. The activated carbon obtained from Shorea robusta flower (ACSF-K) electrode shows the specific capacitance of ~610 F g-1 at 2 A g-1 current density, which is higher than ACSF-Z (560 F g-1) and ACSF-H (470 F g-1) electrode material under the identical current density. The synthesized graphitic carbons also demonstrated good rate capability and high electrochemical stability as supercapacitor electrode.

Interconnected meso/microporous carbon derived from pumpkin seeds as an efficient electrode material for supercapacitors

  • Gopiraman, Mayakrishnan;Saravanamoorthy, Somasundaram;Kim, Seung-Hyun;Chung, Ill-Min
    • Carbon letters
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    • 제24권
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    • pp.73-81
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    • 2017
  • Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).