• Title/Summary/Keyword: dyad

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Fluorescence Behavior Associated with a Possible Intercolumnar Charge-transfer Interaction in the Crystalline State of a Dyad Consisting of Mesitylene and 1,4-Dicyano-2-methylnaphthalene Subunits

  • Ohta, Eisuke;Kobayashi, Hitoshi;Sakai, Atsushi;Matsui, Yasunori;Sato, Hiroyasu;Ikeda, Hiroshi
    • Rapid Communication in Photoscience
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    • v.4 no.2
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    • pp.31-33
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    • 2015
  • Fluorescence (FL) properties of a novel donor-acceptor dyad, comprised of mesitylene and 1,4-dicyano-2-methylnaphthalene (DCMN) subunits connected by an ether linkage, were elucidated. The dyad in cyclohexane exhibits FL arising from an intramolecular exciplex. In the crystalline state, the dyad does not emit light from intra- and inter-molecular exciplexes but rather displays FL that is nearly equivalent to that of 2-methoxymethyl-substituted DCMN. However, the emission spectrum of the crystalline dyad contains a shoulder in the long wavelength region, suggesting that weak intercolumnar charge-transfer interactions take place between columns consisting of the mesitylene and DCMN subunits.

The Effect of Young Children's Dyad Collaboration Based on Their Cognitive and Social Ability on Task Performance (인지적.사회적 변인을 함께 고려한 또래 쌍 협력활동이 유아의 과제 수행력에 미치는 효과)

  • Lee, Jeong-Hwa;Park, Jeong-Eon
    • Korean Journal of Child Studies
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    • v.30 no.1
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    • pp.127-148
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    • 2009
  • This study investigated the effects on task performance of dyad collaboration based on young children's cognitive and social ability. The 108 5-year-old subjects were assigned to a collaborative experimental group, a comparison group working individually in sorting, writing, and making a puzzle, or a control group. Data from before and after measurements on sorting and perspective taking tasks were analyzed by t-test and ANOVA. Results showed that (1) Children working in dyad collaboration obtained significantly more improvement in their performance on both tasks than those working individually. (2) Dyads composed of a child with high level social skill but low level intelligence and a child with low levels of both showed most improvement in performance on the perspective taking task.

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Synthesis of a Porphyrin Derivative Covalently linked to Nickel Aza-macrocycle Cemplex

  • Shin, Eun-Ju;Kwak, Chee-Hun
    • Journal of Photoscience
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    • v.9 no.1
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    • pp.9-12
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    • 2002
  • A porphyrin derivative covalently tinted to Ni aria-macrocycle complex has been prepared. Absorption spectrum of porphyrin-Ni aria-macrocycle dyad (λ$\^$max/$\sub$a/=227 nm) was observed to similar to a sum of those of tetratolylporphyrin (λ$\^$max/$\sub$a/=419 nm) and Ni aza-macrocycle (λ$\^$max/$\sub$a/=227 nm), indicating no electronic interaction between porphyrin and Ni aza-macrocycle moieties. Fluorescence quantum yield of dyad (${\Phi}$$\sub$f/= 0.10) was same to that of tetratolylporphyrin (${\Phi}$$\sub$f/= 0.10). Photoinduced intramolecular electron transfer or energy transfer from excited porphyrin moiety to Ni(II) aza-macrocycle moiety should be very inefficient in dyad.

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Comparative evaluation of the bond strength of self-adhering and bulk-fill flowable composites to MTA Plus, Dycal, Biodentine, and TheraCal: an in vitro study

  • Raina, Aakrati;Sawhny, Asheesh;Paul, Saurav;Nandamuri, Sridevi
    • Restorative Dentistry and Endodontics
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    • v.45 no.1
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    • pp.10.1-10.8
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    • 2020
  • Objectives: This study aimed to compare the shear bond strength (SBS) of a self-adhering flowable composite (Dyad Flow) and a bulk-fill flowable composite (Smart Dentin Replacement [SDR]) to several pulp-capping materials, including MTA Plus, Dycal, Biodentine, and TheraCal. Materials and Methods: Eighty acrylic blocks with 2-mm-deep central holes that were 4 mm in diameter were prepared and divided into 2 groups (n = 40 each) according to the composite used (Dyad Flow or SDR). They were further divided into 4 sub-groups (n = 10 each) according to the pulp-capping agent used. SBS was tested using a universal testing machine at a crosshead speed of 1 mm/min. Data were analyzed using 2-way analysis of variance. A p value of < 0.05 was considered to indicate statistical significance. Results: A statistically significant difference (p = 0.040) was found between Dyad Flow and SDR in terms of bond strength to MTA Plus, Dycal, Biodentine, and TheraCal. Conclusions: Among the 8 sub-groups, the combination of TheraCal and SDR exhibited the highest SBS.

Noncovalently Linked Zinc Porphyrin-Ru(bpy)3 Dyad Assembled via Axial Coordination

  • Kim, Dol;Shin, Eun-Ju
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1490-1494
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    • 2003
  • Noncovalently linked electron donor-acceptor dyad consisting of zinc tetratolylporphyrin and pyridine appended ruthenium trisbipyridine comlex was prepared, via axial coordination of pyridine moiety in ruthenium trisbipyridine complex on zinc tetratolylporphyrin. For the purpose of comparison, axial coordination of pyridine-appended 2,2'-bipyridine on zinc tetratolylporphyrin was also investigated. The Kvalues were detemined based on absorption of fluorescence studies. The fluorescence of zinc teratolylporphrin was efficiently quenched upon axial coordination of pyridine moiety, prbably due to the photoinduced electron transfer from zinc tetrtolylporphyrin to ruthenium trisbipyridine, supported by free enegy estimation.

The Effect of Feeling Distance on Clothes in the Person Perception (의복의 거잡감이 대인지각에 미치는 영향)

  • 박성순;이경희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.1
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    • pp.31-42
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    • 1994
  • The purpose of this study was to investigate the effect of feeling distance of clothes in the person perception. The specific objectives were: 1) to investigate whether the compositions of clothes affect the rate of detouring, ; 2 ) to investigate whether the gender compositions of dyads affect the rate of detouring, ; 3) to investigate whether the distance between members of dyads affect the rate of detouring. ; 3) to investigate whether the distance between members of dyads affect the rate of detouring. ; 4) to investigate the .effect of the interaction among the compsitions of clothes, the gender compositions, and the distance between members of dyads in the person perception. For this study, two male and two female undergraduates were selected and wore business suit or casual wear as given by the researcher. The distance between members of dyads ranged from 100cm to 170cm with an increment unit of loom. The data from our observation were analysed by x2-test, ANOVA, and MCA. The major findings were ; 1) In male/male dyad, distance perception from clothes were affected by the compositions of clothes at all distance. In maleffemale dyad, when the distance between members of dyad is short, distance perception from clothes were affected by the compositions of clothes modes, 2) When two members of dyad wear business suit, distance perception from clothes were affected by the gender composions of dyads. 3) Distance perception from clothes were affected by distance factors at all the gender compositions of dyads. 4) In the person perception, the most imprtant clue was the distance between members of dyads. The pllysical distance, which was formed by clothes, was between 130cm and 140cm.

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A Multiresolution Wavelet Scattering Analysis of Microstrip Patch antennas (마이크로스트립 패치 안테나의 다중 분해능 웨이블릿 산란해석법)

  • 강병용;주세훈;빈영부;김형훈;김형동
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.5
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    • pp.640-647
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    • 1998
  • Microstrip patch antennas are analyzed by a multiresolution wavelet method. The spectral Green's dyad of the structure is obtained and its joint spatial-spectral domain representations are presented. Based on the joint spatial-spectral domain representation, we show that the spectral-domain wavelets are useful in the analysis of this problem. We obtain the matrix equations of the integral equations of this Green's dyad by using the method of moment(MoM), and efficiently solve the problem using the spectral domain wavelet transform concepts in conjuction with the conjugate gradient method. The results for a single-layered square patch are compared with those of conventional MoM and CG-FFT.

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Patterns of Infant-Father Attachment in the Strange Situation (낯선 상황'에서 영아의 아버지에 대한 애착 유형)

  • 이영환
    • Journal of Families and Better Life
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    • v.11 no.2
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    • pp.40-54
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    • 1993
  • The purpose of this study was to examine the specific nature of early relationship between infant and father. The subject pool for the study consisted of 42 middle-class infant-father days. Infant's ages were 12 moths to 17 months. All were fullterm babies In order to assess the patterns of infant-father attachment each dyad was videotaped in the simulated Strange Situation of Ainsworth et al(1978). In order to assess the paternal sensiti-vity toward the infant's cue,. each dyad was also filmed for a 3-minute Questionnaire Situation Gratification of the Transition to Fatherhood. Also at home mothers completed a report on infant temperament using the Infant Characteristics Questionnaire. Among 42 infants 48% or 20 were classified as securely attached 38% or 16 as anxious-avoi-dant and 14% or 6 as anxious-resistant Using the discriminant function coefficients for combi-ning the paternal sensitivity scores 83% of the infants were correctly classified as A. B. C The patterns of attachment were not found to be significantly different in the paternal childhood experience for attachment relationship to his own parents. Degree of Difficulty and Gratification groups with respect to infant temperamental fussiness.

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Study on the Controlled Gel Formation and Photochromic Properties of a New Cholesterol-bridge-naphthopyran Dyad

  • Sun, Lin;Wang, Guang;Liu, Longbo;Wang, Ai Xia
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1343-1348
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    • 2014
  • A cholesterol-bridge-naphthopyran dyad (NP-MCB) was designed and synthesized. NP-MCB can readily self-assemble into gels under ultrasound-radiation in several organic solvents and the formed gels easily transfer to solution by heat. This reversible process can be repeated many times. Scanning Electron Microscopy results showed that the morphologies of all formed xerogels in different solvents have fibrillar microstructure. The gels formation was due to energy and pressure afforded by the ultrasonic process, resulting in formation of molecular hydrogen bonding and molecular aggregation. NP-MCB displayed the normal photochromism both in solution and gel states. The kinetic results confirm that the colored merocyanine in gels show a slower fading speed than that in solution due to the compact aggregation of NP-MCB molecules in gels. The xerogel film formed in polar gelling solvent had large surface wettability than that in nonpolar gelling solvent.

Matrix and Dyadic Representation of Stress and Strain (응력과 변형률의 Dyad와 행렬에 의한 표현)

  • Kim, Chan-Jung;Jo, Jong-Du
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.2 s.173
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    • pp.489-495
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    • 2000
  • Stress and strain in continuum mechanics have a mathematical form of the second order tensor. it is well-known that the usefulness of tensor components could be explained in a relation with coordin ates system transformation and Mohr's circle could be easily used to make a coordinate system transformation of tensors. However, Mohr's circle is applied mainly to plane problems and its use to three dimensional cases is limitedly employed. In this paper, we propose a matrix and dyadic representation of stress and strain tensors which could equivalently replace the graphical representation of second order tensors. The use of the proposed representation might provide a valuable means for the educational respects as well as research view point.