Journal of Photoscience

Korean Society of Photoscience (한국광과학회)
권호 표지

Synthesis of a Porphyrin Derivative Covalently linked to Nickel Aza-macrocycle Cemplex

  • Shin, Eun-Ju (Department of Chemistry, Sunchon National University) ;
  • Kwak, Chee-Hun (Department of Chemistry, Sunchon National University)
  • Published : 2002.03.01
Download PDF
⟨ Previous Next ⟩

Abstract

A porphyrin derivative covalently tinted to Ni aria-macrocycle complex has been prepared. Absorption spectrum of porphyrin-Ni aria-macrocycle dyad (λ$\^$max/$\sub$a/=227 nm) was observed to similar to a sum of those of tetratolylporphyrin (λ$\^$max/$\sub$a/=419 nm) and Ni aza-macrocycle (λ$\^$max/$\sub$a/=227 nm), indicating no electronic interaction between porphyrin and Ni aza-macrocycle moieties. Fluorescence quantum yield of dyad (${\Phi}$$\sub$f/= 0.10) was same to that of tetratolylporphyrin (${\Phi}$$\sub$f/= 0.10). Photoinduced intramolecular electron transfer or energy transfer from excited porphyrin moiety to Ni(II) aza-macrocycle moiety should be very inefficient in dyad.

Keywords

References

  1. Chem. Rev. v.92 Photoinduced electron transfer in supramolecular systems for artificial photosynthesis Wasielewski, M. R.
  2. Acc. Chem. Res. v.26 Molecular mimicry of photosynthetic energy and electron transfer Gust, D.;T. A. Moore;A. L. Moore
  3. Supramolecular Photochemistry Towards a supramolecular photochemistry: assembly of molecular components to obtain photochemical molecular devices Balzani, V.;L. Moggi;F. Scandola;Balzani, V.(ed.);D. Reidel(ed.)
  4. Chem. Rev. v.94 Ruthenium(Ⅱ) and osmium(Ⅱ) bis(terpyridine) complexes in covalently-linked multicomponent systems: Synthesis, electrochemical behavior, absorption spectra, and photochemical and photophysical properties Sauvage, J.-P.;J.-P. Collin;J.-C. Chambron;S. Guillerez;C. Coudret;V. Balzani;F. Barigelletti;L. de Cola;L. Flamigni
  5. Chem. Rev. v.96 Luminescent and redox-active polynuclear transition metal complexes Balzani, V.;A. Juris;M. Venturi;S. Campagna;S. Serroni
  6. Acc. Chem. Res. v.22 Chemical approaches to artificial photosynthesis Meyer, T. J.
  7. Photochemistry of Polypyridine and Porphyrin Complexes Kalyanasundaram, K.
  8. J. Photochem. Photobiol. B v.58 Photochemistry of supramolecular systems containing $C_{60}$ Gust, D.;T. A. Moore;A. L. Moore
  9. Angew. Chem. Int. Ed. Engl. v.30 The high-yield synthesis and characterization of the first porphyrin-cyclam dinucleating ligand and its iron(Ⅱ)/copper(Ⅱ) complex Bulach, V.;D. Mandon;R. Weiss
  10. J. Am. Chem. Soc. v.114 Triplet and singlet energy transfer in carotene-porphyrin dyads: role of the linkage bonds Gust, D.;T. A. Moore;A. L. Moore;C. Devadoss;P. A. Liddell;R. Hermant;R. A. Nieman;L. J. Demanche;J. M. Degraziano;I. Gouni
  11. J. Phys. Chem. v.97 Photoinduced electron transfer in a porphyrin dyad Gust, D.;T. A. Moore;A. L. Moore;L. Leggett;S. Lin;J. M. Degraziano;R. M. Hermant;D. Nicodem;P. Craig;G. R. Seely;R. A. Nieman
  12. J. Am. Chem. Soc. v.113 Long-lived photoinitiated charge separation in carotene-diporphyrin triad molecules Gust, D.;T. A. Moore;A. L. Moore;F. Gao;D. Luttrull;J. M. DeGraziano;X. C. Ma;L. R. Makings;S.-J. Lee;T. T. Trier;E. Bittersmann;G. R. Seely;S. Woodward;R. V. Bensasson;M. Rougee;F. C. De Schryver;M. Van der Auweraer
  13. J. Kor. Chem. Soc. v.42 Preparation, properties and solution behavior of (8-(4-methylene piperidine)-1,3,6,8,10,13,15-heptaaza tetracyclo $[13.1.1.1^{13,15}]$ octadecanenickel (Ⅱ) perchlorate Seo, M. S.;H. Park;C.-H. Kwak
  14. J. Phys. Chem. v.91 Triplet-triplet energy transfer in a copper(Ⅱ) porphyrin-free-base prophyrin dimer Ohno, O.;Y. Ogasawara;M. Asano;Y. Kajii;Y. Kaizu;K. Obi;H. Kobayashi
  15. J. Phys. Chem. v.91 Pulse radiolytic and electrochemical investigations of intramolecular electron transfer in carotenoporphyrins and carotenoporphyrinquinone triads Land, E.J.;D. Lexa;R. V. Bensasson;D. Gust;T. A. Moore;A. L. Moore;P. A. Liddell;G. A. Nemeth