• Title/Summary/Keyword: distribution of $O_3$

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Resistance distribution in large area thin film type SFCLS (박막형 대면적 초전도 한류소자에서의 저항 분포)

  • 김혜림;최효상;현옥배
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.89-93
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    • 2002
  • We investigated the resistance distribution n 4"diameter SFCLS. $YBa_2CU_3O_7$ films coated in-situ with a gold layer were patterned into 3 mm wide 142 cm long meander lines by Photolithography. The limiters were tested with simulated fault currents. The resistance was uniform all over the film except at the edge. At lower source voltages, CFCLs did not quench simultaneously and the resistance distribution was less uniform. Compared with 2" diameter SFCLS 4" SFCLS had similar values and time dependence of resistivity at similar electric fields The resistance distribution was more uniform in 4" SFCLS. The area at the edge where the distribution was not uniform was around 3 mm wide in SFCLs of both sizes. The experimental results were quantitatively explained with a heat transfer concept.

Dynamics of OH Production in the Reaction of O(1D2) with Cyclopropane

  • Jang, Sungwoo;Jin, Sung Il;Kim, Hong Lae;Kim, Hyung Min;Park, Chan Ryang
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1706-1712
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    • 2014
  • The OH($X^2{\Pi}$, ${\upsilon}^{\prime\prime}=0,1$) internal state distribution following the reaction of electronically excited oxygen atom ($O(^1D_2)$) with cyclo-$C_3H_6$ has been measured using laser-induced fluorescence, and compared with that following the reaction of $O(^1D_2)$ with $C_3H_8$. The overall characteristics of the OH internal energy distributions for both reactions were qualitatively similar. The population propensity of the ${\Pi}(A^{\prime})$ ${\Lambda}$-doublet sub-level suggested that both reactions proceeded via an insertion/elimination mechanism. Bimodal rotational population distributions supported the existence of two parallel mechanisms for OH production, i.e., statistical insertion and nonstatistical insertion. However, detailed analysis revealed that, despite the higher exoergicity of the reaction, the rotational distribution of the OH following the reaction of $O(^1D_2)$ with $C_3H_8$ was significantly cooler than that with cyclo-$C_3H_6$, especially in the vibrational ground state. This observation was interpreted as the effect of the flexibility of the insertion complex and faster intramolecular vibrational relaxation (IVR).

Interface trap density distribution in 3D sequential Integrated-Circuit and Its effect (3차원 순차적 집적회로에서 계면 포획 전하 밀도 분포와 그 영향)

  • Ahn, TaeJun;Lee, Si Hyun;Yu, YunSeop
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.12
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    • pp.2899-2904
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    • 2015
  • This paper introduces about the effect on $I_{DS}-V_{GS}$ characteristic of transistor that interface trap charge is created by damage due to heat in a 3D sequential inverter. A interface trap charge distribution in oxide layer in a 3D sequential inverter is extracted using two-dimensional device simulator. The variation of threshold voltage of top transistor according to the gate voltage variation of bottom transistor is also described in terms of Inter Layer Dielectric (ILD) length of 3D sequential inverter, considering the extracted interface trap charge distribution. The extracted interface trap density distribution shows that the bottom $HfO_2$ layer and both the bottom and top $SiO_2$ layer were relatively more affected by heat than the top $HfO_2$ layer with latest process. The threshold voltage variations of the shorter length of ILD in 3D sequential inverter under 50nm is higher than those over 50nm. The $V_{th}$ variation considering the interface trap charge distribution changes less than that excluding it.

Magnetic Properties of Cu-Zn Ferrites (Cu-Zn 훼라이트의 자기적 성질)

  • 이충섭;이찬영;김철성;지상희
    • Journal of the Korean Magnetics Society
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    • v.3 no.1
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    • pp.18-22
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    • 1993
  • The cationic distributions and magnetic properties of $Cu_{x}Zn_{1-x}Fe_{2}O_{4}(0{\leq}x{\leq}1)$ have been studied by X-ray diffraction and $M\"{o}ssbauer$ spectroscopy. The crystal structures are cubic spinels in the range $0{\leq}x{\leq}0.9$. The ionic distribution of ${(Zn_{1-x}Fe_{x})}_{A}{[Zn_{x}Fe_{2-x}]}_{B}O_{4}$, where x=0.1. The distribution of $Fe^{3+}$ ions was extracted from the $M\"{o}ssbauer$ spectra below Curie temperature in the whole range $0{\leq}x{\leq}1$. The number of $Fe^{3+}$ ions in the tetrahedral sites and Curie temperature of Cu-Zn ferrite increase with increasing Cu-concentration.

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Preparation of Flaky α-Al2O3 Crystals by Transition Metal Salts Addition (전이금속염 첨가에 의한 판상 α-Al2O3 결정체 제조)

  • Song, Hyo-Kyung;Park, Byung-Ki;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.384-390
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    • 2005
  • [ ${\alpha}-Al_2O_3$ ] precursor was synthesised by sol-gel method using aluminum sulfate, sodium sulfate and sodium carbonate as law materials. The flaky ${\alpha}-Al_2O_3$ crystals were prepared by heating using precursor about $1,050^{\circ}C$. In this study, the effect of some transition-metal sulfate ($FeSO_4,\;SnSO_4,\;ZnSO_4$) addition have been investigated. When iron sulfate was added, it could see that act on impurities in crystal growth process. In case of tin sulfate, distribution of Platelets was very broad. When flaky ${\alpha}-Al_2O_3$ crystals were prepared zinc sulfate addition, thickness, size, and distribution of platelets was suited to industrial application. The average diameter of flaky ${\alpha}-Al_2O_3$ crystals was about 20 $\mu$m, and its thickness was about 0.3 $\mu$m. Increasing addition of zinc sulfate, thickness of ${\alpha}-Al_2O_3$ platelet was decreased.

Distribution Behavior of Bi and Pb Between Molten PbO-SiO2 Slag and Bi (용융(熔融) PbO-SiO2계(系) 슬래그와 Bi 사이의 Bi와 Pb의 분배거동(分配擧動))

  • Kim, Se-Jong;Kim, Eung-Jin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.21 no.5
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    • pp.65-71
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    • 2012
  • The equilibrium distribution of bismuth and lead between molten PbO-$SiO_2$ slag and bismuth phase was studied in the temperature range of $775^{\circ}C$ to $850^{\circ}C$ in a MgO crucible. The oxygen partial pressure of atmosphere was controlled by $P_{CO2}/P_{CO}$ ratio. The value of $(%PbO)_{slag}/[%Pb]_{metal}$ increased with increasing $SiO_2$ content of slag, and the value of $(%Bi_2O_3)_{slag}/[%Bi]_{metal}$ decreased with increasing $SiO_2$ content of slag. The concentration of Pb in metal increased with increasing temperature. These experimental results agreed well with the thermodynamic prediction.

Effect of particle size distribution on the magnetidc properties of hexagonal strontium ferrite (육방정 스트론튬 페라이트의 자기적 특성에 미치는 입도 분포의 영향)

  • 송창열;신용덕
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.324-331
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    • 1995
  • 0.36[wt%l $SiO_{2}$ and 0.1[wt%] $H_{3}$B $O_{3}$ were added to strontium ferrite magnets of the magnetoplumbite phase SrO.5.7F $e_{2}$ $O_{3}$ to hinder grain growth and accelerate sintering, respectively. This experiment was carried out to investigate effect of particle size distribution as a function of milling time(20, 30, 40, 50, 60, 70 hours) on the magnetic properties of SrO.5.7F $e_{2}$ $O_{3}$ ferrite magnet. The B-H curve, density and the degree of orientation were measured. And the microstructure of ferrite magnets was examined with a SEM. The optimal conditions and properties of the typical sample are the following : The milling time was 60 hours. Magnetic and physical properties are $B_{r}$=4, 000[G], $_{b}$ $H_{c}$=3, 330[Oe], (BH)max=3.786[MGOe], $_{I}$ $H_{c}$=3, 525[Oe], density=5.0063[g/c $m^{3}$] and orientation factor f=0.813.0.813.3.3.

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Interpretation of Hydrothermal Synthesis of BaTiO3 Powder (BaTiO3 분말의 수열합성 해석)

  • Oh, Jung Kang;Seo, Kyung Won
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.509-514
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    • 1999
  • In Preparing $BaTiO_3$ powder under hydrothermal conditions, effects of reaction period feedstock concentration and mixing rate on crystallinity, mean size and size distribution of particles were studied. Experimental results showed that the particle size became smaller with its narrow distribution as the reaction period and mixing rate increased, but feedstock concentration decreased in contrast with the results based on the classical nucleation-growth model. From these results, $BaTiO_3$ particles seem to be prepared hydrothermally through a multiple reaction procedure that includes dissolution, precipitation, hydrolysis-condensation, aggregation, diffusion and transformation.

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Microstructure and Electrical Properties of Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 Ceramics Modified with Yttria (Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3계에 Yttria 첨가시 미세구조와 전기적 물성변화에 관한 연구)

  • 김창삼;이응상
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.263-269
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    • 1987
  • It is investigated that the determination of the correlation between the change of microstructure and electrical properties. Yttria is added to the compositiojn of rhombohedral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system. Average grian size, lattice parameters and distribution of yttrium are characterized by XRD, SEM and EDS. Electrical properties are determined by measurement of Curie temperature, piezoelectric properties and hysteresis loops. The results are as follows; 1. Both lattice parameters, a and ${\alpha}$, are changed by addition of yttria to the composition of rhomboheadral region in Pb(Mg1/3Nb2./3)O3-PbTiO3-PbZrO3 ternary system and Curie temperature is proportional to the values at (90-${\alpha}$).

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Characterization of Size distribution of Anion Species in Atmospheric Aerosols (대기에어로졸중 음이온성분에 대한 입경분포의 변화특성)

  • 최금찬;박정호;임경택
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.2
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    • pp.124-129
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    • 1994
  • Aerosol size distribution was determined using Anderson sampler for the anions( sulfate nitrate and chloride ) and TSP. Ionic species concentration and size distribution have been investigated in the daytime and nightime individually. Size classified samples were extracted with distilled water and analyzed for C $l^{[-10]}$ , N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$, by ion chromatography. The size distribution of these ions and TSP was analyzed to investigate the seasonal and diurnal variation of concentrations as follows: (1)Size distribution of TSP showed bi- modal type in the daytime, but indicated tri-mode distribution in the nightime without any seasonal variation. (2)Sulfate concentrations were higher in fine- mode both in the daytime and nightime but fraction of sulfate was higher in coarse-mode during the Yellow Sand Period. (3)Nitrate and Chloride ions are dominant in fine-mode in winter while dominant in coarse-mode in the summer.

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