• Title/Summary/Keyword: diffusion limit

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Limit-current type zirconia oxygen sensor with porous diffusion layer (다공성 확산층을 이용한 한계전류형 지르코니아 산소센서)

  • Oh, Young-Jei;Lee, Chil-Hyoung
    • Journal of Sensor Science and Technology
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    • v.17 no.5
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    • pp.329-337
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    • 2008
  • Simple, small and portable oxygen sensors were fabricated by tape casting technique. Yttria stabilized zirconia containing cordierite ceramics (YSZC) were used as a porous diffused layer of oxygen in pumping cell. Yttria stabilized zirconia (YSZ) solid electrolyte, YSZC porous diffusion layer and heater-patterned ceramic sheets were prepared by co- firing method. Limit current characteristics and the linear relationship of current to oxygen concentration were observed. Viscosity variation of the slurries both YSZ and YSZC showed a similar behavior, but micro pores in the fired sheet were increased with increasing of the cordierite amount. Molecular diffusion was dominated due to the formation of large pores in porous diffusion layer. The plateau range of limit current in porous-type oxygen sensor was narrow than the one of aperture-type oxygen sensor. However limit current curve was appeared in porous-type oxygen sensor even at the lower applied voltage. The plateau range of limit-current was widen as increasing the thickness of porous diffusion layer of the YSZ containing cordierite. Measuring temperature of $600{\sim}650^{\circ}C$ was recommended for limit-current oxygen sensor. Porous diffusion layer-type oxygen sensor showed faster response than the aperture-type one and was stable up to 30 days running without any crack at interface between the layers.

Fatigue properties of nitrided titanium using fluidized bed furnace (유동상로를 이용한 질화처리티타늄의 피로강도 특성)

  • Kim, Min-Gun;Ji, Jueng-Keun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.1
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    • pp.142-147
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    • 1998
  • Rotary bending fatigue tests were carried out on the nitrided titanium in order to investigate the effect of nitriding layer on fatigue limit. Main results obtained are as follows. (1) The fatigue limit of nitrided pure titanium is remarkably reduced because of enlargement of grain size at high heat treating temperature and high stress field created from the elastic interaction in the compound layer. (2) Further test using specimen which was removed nitrified layer gradually, were also conducted and it was found that by removing the compound layer the fatigue limit recovered as the level of basic material and rather increased by coming of a diffusion layer. Therefore it is concluded that the surface compound layer generated by nitriding treatment reduced the fatigue limit but diffusion layer increased it.

Demand Forecasting for New Service using the Diffusion Model (확산모형 (Diffusion Model)을 이용한 새로운 서비스 수요예측)

  • Kim, Gyeong-Taek;Park, Se-Gwon
    • Journal of Korean Institute of Industrial Engineers
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    • v.13 no.1
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    • pp.25-29
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    • 1987
  • When the historical data are available, the diffusion model, which describes the time pattern of the adoption process of a new product or technology or service, has been used as a reasonable predictor in the telecommunication demand forecasting area. This paper shows that the diffusion model is applicable when the historical data are not available. The model used is in the form of a "logistic" function. The parameters of the function are estimated using the questionnaire and the historical data of reference products. From the questionnaire, an initial and an upper limit long run value of the market share are estimated, and the diffusion time to the upper limit value is determined by the relation between the investment and the utility.

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Blow-off and Combustion Characteristics of a Lifted Coaxial Diffusion Flame (동축 확산 부상화염의 Blow-off와 연소 특성)

  • Kwark, Ji-Hyun;Jun, Chung-Hwan;Jang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.8
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    • pp.1089-1096
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    • 2003
  • An experiment was performed to investigate lift-off, blow-off and combustion characteristics of a lifted coaxial diffusion flame according to fuel jet and air velocity. A jet diffusion flame which is attached on the nozzle rim begins to be lifted with increase of air velocity, and finally becomes blow-off at higher air velocity. In experiment, blow-off limit increased with increase of fuel jet velocity, however lift-off occurred at lower air velocity. Flame structure and combustion characteristics were examined by schlieren photos, temperature distributions and emission concentration distributions. Flame temperature became higher at midstream and its RMS became larger at up and downstream with increase of air velocity. Local NO concentration decreased but $CO_2$concentration increased with increase of air velocity, which shows combustion reaction becomes close to be stoichiometric at higher air velocity in spite of lift-off.

Analysis on the non-equilibrium dendritic solidification of a binary alloy with back diffusion (역확산을 고려한 이원합금의 비평형 수지상응고 해석)

  • Jeong, Jae-Dong;Yu, Ho-Seon;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.10
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    • pp.3361-3370
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    • 1996
  • Micro-Macro approach is conducted for the mixture solidification to handle the closely linked phenomena of microscopic solute redistribution and macroscopic solidification behavior. For this purpose, present work combines the efficiency of mixture theory for macro part and the capability of microscopic analysis of two-phase model for micro part. The micro part of present study is verified by comparison with experiment of Al-4.9 mass% Cu alloy. The effect of back diffusion on the macroscopic variables such as temperature and liquid concentration, is appreciable. The effect, however, is considerable on the mixture concentration and eutectic fraction which are indices of macro and micro segregation, respectively. According to the diffusion time, the behavior near the cooling wall where relatively rapid solidification permits short solutal diffusion time, approaches Scheil equation limit and inner part approaches lever rule limit.

A generalized scheil equation for the dendritic solidification of binary alloys (이원합금의 수지상응고에 대한 일반화된 Scheil식)

  • Yu, Ho-Seon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.7
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    • pp.2367-2374
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    • 1996
  • A generalized Scheil equation for the solute redistribution in the absence of the back diffusion during the dendritic solidification of binary alloys is derived, in which coarsening of the secondary dendrite arms is taken into account. The obtained equation essentially includes the original Scheil equation as a subset. Calculated results for typical cases show that the coarsening affects the microsegregation significantly. The eutectic fraction predicted for coarsening is considerably smaller than that for fixed arm spacing. The most important feature of the present equation in comparison with the Scheil equation lies in the fact that there exists a lower limit of the initial composition below which the eutectic is not formed. Based on the generalized Scheil equation and the lever rule, a new regime map of the eutectic formation on the initial composition-equilibrium partition coefficient plane is proposed. The map consists of three regimes: the eutectic not formed, conditionally formed and unconditionally formed, bounded by the solubility and diffusion controlled limit lines.

Temporal and Spatial Spreading Characteristic of Drift Soil due to the Reclamation in the Pusan Port (해양 매립 및 준설토 투기에 따른 부유사 확산의 시.공간적 특성에 관한 연구)

  • 김용원;김종인;윤한삼;홍도웅
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.10a
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    • pp.196-203
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    • 2000
  • In this study, the evaluation method of diffusion characteristics of Suspended Soli&SS) and the generation limit(source and thick) are investigated, which is significantly affecting on marine examined by construction works such as dredging and reclamation. Dispersion characteristics of SS is examined by hydraulic tests and numerical works in consideration with the Pusan Port. Hydraulic model test was performed in 2-D wave flume to find the limit wave conditon of re-suspension of solid as well as the time dependent characteristics of settlement The results obtainded in the study are as follows; 1) The quantituative evaluation af SS is the basic parameter of marine environmental impact assessment in related with the port development The SS increases as the water content of sea bed solid increases and the density decreases. 2) The sea bed solid in Sinsundai area, Pusan Port has the water content range of 83~157% 3) The ratio of suspension velocity against settlement velocity is about 0.25 and SS concentration converges as the wave heigh. 4) The SS increases 2 time when time step increases 3 time(10 sec to 30 sec) in numerical simulation It means that the effect of the time step should be checked in detail to stable. The diffusion The diffusion coefficient are Affiected senstively in the dispersion process while sea ved friction coefficinet have not strong relation in the simulated area

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Nonlinear Behaviors of Pulsating Instabilities in Counterflow Diffusion Flames with Radiation Heat Loss (복사 열손실을 받는 대향류 확산화염의 맥동 불안정성의 비선형 거동)

  • Lee, Su Ryong;Park, Sung Cheon
    • Journal of the Korean Society of Combustion
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    • v.17 no.3
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    • pp.9-16
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    • 2012
  • Nonlinear dynamics of pulsating instability in radiating counterflow diffusion flames is numerically investigated by imposing Damk$\ddot{o}$hler number perturbation. Stable limit-cycle solutions occur in small ranges of Damk$\ddot{o}$hler numbers past bifurcation point of instability. Period doubling cascade and chaotic behaviors appear just before dynamic extinction occurs. Nonlinear dynamics is also studied when large disturbances are imposed to flames. For weak steady flames, the dynamic extinction range shrinks as the magnitudes of disturbances are increased. However, strong steady flames can overcome relatively large disturbances, thereby the dynamic extinction range extending. Stable limit-cycle behaviors reappears prior to dynamic extinction when the steady flames are strong enough.

Linear Stability Analysis of Cellular Counterflow Diffusion Flames with Radiation Heat Loss (복사 열손실을 받는 셀모양 대향류 확산화염의 선형 안정성 해석)

  • Lee, Su Ryong
    • Journal of the Korean Society of Combustion
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    • v.18 no.2
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    • pp.42-50
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    • 2013
  • Linear stability analysis of radiating counterflow diffusion flames is numerically conducted to examine the instability characteristics of cellular patterns. Lewis number is assumed to be 0.5 to consider diffusional-thermal instability. Near kinetic limit extinction regime, growth rates of disturbances always have real eigen-values and neutral stability condition of planar disturbances perfectly falls into quasi-steady extinction. Cellular instability of disturbance with transverse direction occurs just before steady extinction. However, near radiative limit extinction regime, the eigenvalues are complex and pulsating instability of planar disturbances appears prior to steady extinction. Cellular instability occurs before the onset of planar pulsating instability, which means the extension of flammability.