• Bulletin of the Korean Chemical Society
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• 제34권4호
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• pp.1137-1144
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• 2013

$TiO_2$ composites with seven different carbon materials (activated carbons, graphite, carbon fibers, single-walled carbon nanotubes, multi-walled carbon nanotubes, graphene oxides, and reduced graphene oxides) that are virgin or treated with nitric acid are prepared through an evaporation method. The photocatalytic activities of the as-prepared samples are evaluated in terms of $H_2$ production from aqueous methanol solution (photo-catalytic reduction: PCR) and degradation of aqueous pollutants (phenol, methylene blue, and rhodamine B) (photocatalytic oxidation: PCO) under AM 1.5-light irradiation. Despite varying effects depending on the kinds of carbon materials and their surface treatment, composites typically show enhanced PCR activity with maximum 50 times higher $H_2$ production as compared to bare $TiO_2$. Conversely, the carbon-induced synergy effects on PCO activities are insignificant for all three substrates. Colorimetric quantification of hydroxyl radicals supports the absence of carbon effects. However, platinum deposition on the binary composites displays the enhanced effect on both PCR and PCO reactions. These differing effects of carbon materials on PCR and PCO reactions of $TiO_2$ are discussed in terms of physicochemical properties of carbon materials, coupling states of $TiO_2$/carbon composites, interfacial charge transfers. Various surface characterizations of composites (UV-Vis diffuse reflectance, SEM, FTIR, surface area, electrical conductivity, and photoluminescence) are performed to gain insight on their photocatalytic redox behaviors.

• 한국임상수의학회지
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• 제22권3호
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• pp.284-287
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• 2005

A 18-month-old, male Maltese dog with acute seizure was referred to Veterinary Medical Teaching Hospital, Kyungpook National University. Abnormal neurologic findings included a tendency to fall to the left, turn and circle to the right, negative bilateral menace responses and pupillary light reflexes, and diminished responses to facial sensation testing on both sides. Radiographic signs were normal, except for occipital dysplasia. Magnetic resonance imaging of the brain revealed bilateral asymmetric ventriculomegaly, which is more on left side. Cerebral edema was also suspected. The dog died after 9 days from the onset of seizure, and a necropsy was performed. Histopathologically, the brain lesions in the meninges and the cerebral cortex of this dog was presented. There was severe diffuse nonsuppurative inflammation in perivascular area of the meninges and the cerebral white matter. Based on the results, this case was diagnosed as necrotizing meningoencephalitis in Maltese dog.

• 한국태양에너지학회 논문집
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• 제22권3호
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• pp.47-56
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• 2002

The office is an excellent candidate for implementing daylighting techniques because of the relatively high electric lighting power densities and long daytime use pattern. The quantity of light available for a space can be translated in term of the amount of energy savings through a process of a building energy simulation. To get significant energy savings in general illumination, the electric lighting system must be incorporated with a daylight - activated dimmer control. A prototype configuration of an office interior has been established and the integration between the building envelope and lighting and HVAC systems is evaluated based on computer modeling of a lighting control facility. First of all, an energy-efficient luminaire system is designed for both a totally open-plan office interior and a partitioned office. A lighting design and analysis program, Lumen-Micro 2000 predicts the optimal layout of a conventional fluorescent lighting fixture to meet the designed lighting level and calculates unit power density, which translates the demanded amount of electric lighting energy. A dimming control system integrated with the contribution of daylighting has been applied to the operating of the artificial lighting. Annual cooling load due to lighting and the projecting saving amount of cooling load due to daylighting under overcast diffuse sky are evaluated by a computer software, ENER-Win. In brief, the results from building energy simulation with measured daylight illumination levels and the performance of lighting control system indicate that daylighting can save over 70 percent of the required energy for general illumination in the perimeter zones through the year. A 25 % of electric energy for cooling may be saved by dimming and turning off the luminaires in the perimeter zones.

• 한국건설관리학회:학술대회논문집
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• 한국건설관리학회 2007년도 정기학술발표대회 논문집
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• pp.909-914
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• 2007

건설 프로젝트가 점차 대형화, 복잡화, 전문화 되면서 지속적으로 변화하는 건설 환경에 대응할 수 있는 프로젝트 관리 기법 개발에 대한 요구가 증가하고 있다. 건설 프로젝트의 특성상 관리 기법은 건설 현장이나 구조물의 유지 관리 단계에서 발생하는 방대한 양의 정보를 실시간으로 수집하고 처리하여 표현할 수 있어야 한다. 이를 위해 국내외적으로 실시간 3차원 공간 모델링 방법의 개발에 대한 연구가 활발히 진행되고 있으며, 실시간 3D 공간 정보 획득은 모델링을 위한 필수 요소라 할 수 있다. 최근 개발된 플래시 레이다는 실시간으로 주변 환경에 대한 3차원 공간 정보 획득이 가능하도록 하는 장비로 건설 산업에서의 3차원 공간 모델링 시스템에 가장 적합한 기술이라 할 수 있다. 본 논문에서는 보다 정확한 3차원 공간 모델링을 위해 플래시 레이다의 장비 성능을 파악하고, 실험을 통해 이를 이용하여 획득한 3차원 공간 데이터의 정확성을 검증함으로써 건설현장에 대한 장비의 적용성을 검토하고자 한다.

• Korean Journal of Chemical Engineering
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• 제35권11호
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• pp.2283-2289
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• 2018

$TiO_2$ microspheres were successfully synthesised by simple solution phase method by using various amount of titanium butoxide as precursor. The prepared $TiO_2$ were characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance absorption spectra (UV-DRS), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). XRD analysis revealed that the as-synthesized $TiO_2$ microsphere poses an anatase phase. The photocatalytic degradation experiments were carried out with three different dyes, such as methylene blue, brilliant black, reactive red-120 for four hours under UV light irradiation. The results show that $TiO_2$ morphology had great influence on photocatalytic degradation of organic dyes. The experimental results of dye mineralization indicated the concentration was reduced by a high portion of up to 99% within 4 hours. On the basis of various characterization of the photocatalysts, the reactions involved to explain the photocatalytic activity enhancement due to the concentration of titanium butoxide and morphology include a better separation of photogenerated charge carriers and improved oxygen reduction inducing a higher extent of degradation of aromatics.

• Current Applied Physics
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• 제18권11호
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• pp.1422-1425
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• 2018

$NaTa_{1-x}Fe_xO_3$ ($0{\leq}x{\leq}0.40$) nanocubes were synthesized by a relatively low temperature hydrothermal method, using $Ta_2O_5$, $FeCl_3$ and NaOH as the precursors. The UV-vis diffuse reflectance spectra showed that $NaTa_{1-x}Fe_xO_3$ had significant visible-light-absorbing capability, and the absorption edge of $NaTaO_3$ shifted to longer wavelength with the increase of Fe dopants. Moreover, $NaTa_{1-x}Fe_xO_3$ exhibited room-temperature ferromagnetism when $Fe^{3+}$ occupied $Ta^{5+}$ sites in $NaTaO_3$ crystal lattice. The ferromagnetism is mainly attributed to the superexchange interactions between doped $Fe^{3+}$, rather than the contribution of oxygen vacancies caused by Fe doping. Therefore, Fe doping can simultaneously regulate the optical and magnetic properties of $NaTaO_3$ semiconductor, which will enable its potential applications in multifunctional optical-electronics and opticalspintronics devices.

• Advances in nano research
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• 제12권3호
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• pp.291-300
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• 2022

The behavior of hydrogen species on the surface of the catalyst during the Lewis acid transformation to form Brønsted acid sites over the spherical silica-supported WO_x catalyst was investigated. To understand the structure-activity relationship of Lewis acid transformation and hydrogen bonding interactions, we explore the potential of using the in situ diffuse reflection infrared Fourier transform spectroscopy (DRIFTS) with adsorbed ammonia and hydrogen exposure. From the results of in situ DRIFTS measurements, Lewis acid sites on surface catalysts were transformed into new Brønsted acid sites upon hydrogen exposure. The adsorbed NH₃ on Lewis acid sites migrated to Brønsted acid sites forming NH⁴⁺. The results show that the dissociated H atoms present on the catalyst surface formed new Si-OH hydroxyl species - the new Brønsted acid site. Besides, the isolated Si-O-W species is the key towards H-bond and Si-OH formation. Additionally, the H atoms adsorbed surrounding the Si-O-W species of mono-oxo O=WO₄ and di-oxo (O=)₂WO₂ species, where the Si-O-W species are the main species presented on the Inc-SSP catalysts than that of the IWI-SSP catalysts.

• 천문학회보
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• 제46권1호
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• pp.50.2-51
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• 2021

Stars form exclusively in cold and dense molecular clouds. To fully understand star formation processes, it is hence a key to investigate how molecular clouds form out of the surrounding diffuse atomic gas. With an aim of shedding light in the process of the atomic-to-molecular transition in the interstellar medium, we analyze Arecibo HI emission and absorption spectral pairs along with TRAO/PMO 12CO(1-0) emission spectra toward 58 lines of sight probing in and around molecular clouds in the solar neighborhood, i.e., Perseus, Taurus, and California. 12CO(1-0) is detected from 19 out of 58 lines of sight, and we report the physical properties of HI (e.g., central velocity, spin temperature, and column density) in the vicinity of CO. Our preliminary results show that the velocity difference between the cold HI (Cold Neutral Medium or CNM) and CO (median ~ 0.7 km/s) is on average more than a factor of two smaller than the velocity difference between the warm HI (Warm Neutral Medium or WNM) and CO (median ~ 1.7 km/s). In addition, we find that the CNM tends to become colder (median spin temperature ~ 43 K) and abundant (median CNM fraction ~ 0.55) as it gets closer to CO. These results hints at the evolution of the CNM in the vicinity of CO, implying a close association between the CNM and molecular gas. Finally, in order to examine the role of HI in the formation of molecular gas, we compare the observed CNM properties to the theoretical model by Bialy & Sternberg (2016), where the HI column density for the HI-to-H2 transition point is predicted as a function of density, metallicity, and UV radiation field. Our comparison shows that while the model reproduces the observations reasonably well on average, the observed CNM components with high column densities are much denser than the model prediction. Several sources of this discrepancy, e.g., missing physical and chemical ingredients in the model such as the multi-phase ISM, non-equilibrium chemistry, and turbulence, will be discussed.

• 천문학회보
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• 제46권2호
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• pp.40.3-41
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• 2021

Minor mergers leave behind long lived, but extremely faint and extended tidal features including tails, streams, loops and plumes. These act as a fossil record for the host galaxy's past interactions, allowing us to infer recent accretion histories and place constraints on the properties and nature of a galaxy's dark matter halo. However, shallow imaging or small homogeneous samples of past surveys have resulted in weak observational constraints on the role of galaxy mergers and interactions in galaxy assembly. The Rubin Observatory, which is optimised to deliver fast, wide field-of-view imaging, will enable deep and unbiased observations over the 18,000 square degrees of the Legacy Survey of Space and Time (LSST), resulting in samples of potentially of millions of objects undergoing tidal interactions. Using realistic mock images produced with state-of-the-art cosmological simulations we perform a comprehensive theoretical investigation of the extended diffuse light around galaxies and galaxy groups down to low stellar mass densities. We consider the nature, frequency and visibility of tidal features and debris across a range of environments and stellar masses as well as their reliability as an indicator of galaxy accretion histories. We consider how observational biases such as projection effects, the point-spread-function and survey depth may effect the proper characterisation and measurement of tidal features, finding that LSST will be capable of recovering much of the flux found in the outskirts of L* galaxies at redshifts beyond local volume. In our simulated sample, tidal features are ubiquitous In L* galaxies and remain common even at significantly lower masses (M*>10^10 Msun). The fraction of stellar mass found in tidal features increases towards higher masses, rising to 5-10% for the most massive objects in our sample (M*~10^11.5 Msun). Such objects frequently exhibit many distinct tidal features often with complex morphologies, becoming increasingly numerous with increased depth. The interpretation and characterisation of such features can vary significantly with orientation and imaging depth. Our findings demonstrate the importance of accounting for the biases that arise from projection effects and surface-brightness limits and suggest that, even after the LSST is complete, much of the discovery space in low surface-brightness Universe will remain to be explored.

• 반도체디스플레이기술학회지
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• 제22권3호
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• pp.28-35
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• 2023

Moiré patterns emerge due to the interference between the non-emission area of the LED screen and the grid line in an image sensor of a video recording device when taking a video in the presence of the LED screen. To reduce the moiré intensity, we have fabricated an anti-moiré filter using hollow glass microspheres (HGMs) by slot-die coating. The LED screen has a large non-emission area because of a large pitch (distance between LED chips), causing more severe moiré phenomenon, compared with a display panel having a very narrow black matrix (BM). It is shown that HGMs diffuse light in such a way that the periodicity of the screen is broken and thus the moiré intensity weakens. To quantitatively analyze its moiré suppression capability, we have calculated the spatial frequencies of the moiré fringes using fast Fourier transform. It is addressed that the moiré phenomenon is suppressed and thus the amplitude of each discrete spatial frequency term is reduced as the HGM concentration is increased. Using the filter with the HGM concentration of 9 wt%, the moiré fringes appeared depending sensitively on the distance between the LED screen and the camera are almost completely removed and the visibility of a nature image is enhanced at a sacrifice of luminance.