• Title/Summary/Keyword: dielectric anomaly

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Dielectric properties of A-site defect perovskite La1/3NbO3 single crystal (A-자리 결함 perovskite La1/3NbO3 단결정의 유전특성)

  • Sohn, Jeong-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.6
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    • pp.249-253
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    • 2010
  • After the specimen of A-site defect perovskite $La_{1/3}NbO_3$ single crystal was manufactured, the dielectric properties were studied between the temperature range of 10 and 800 K. The dielectric anomaly appeared at 50 K and 650 K, and, at about 650 K, the thermal hysteresis of dielectric constant was shown. The ac-conductivity of bulk showed the lowest activation energy of 0.43 eV at 560~690 K. Based on the results, it is assumed that the dielectric anomaly at 50K and 650 K was due to the antiparallel shift of $Nb^{5+}$-ion and the rearrangement of $Nb^{3+}$-ion, respectively.

Electrical Transport Properties of Gd0.33Sr0.67FeO3 Ceramics (Gd0.33Sr0.67FeO3 세라믹스의 전기전도 특성)

  • Jung, Woo-Hwan
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.131-135
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    • 2006
  • In this study, the dielectric, magnetic and transport properties of $Gd_{0.33}Sr_{0.67}FeO_3$ have been analyzed. The dielectric loss anomaly was found to be around 170 K. The activation energy corresponding to relaxation process of this dielectric anomaly was 0.17 eV. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dielectric relaxation peak observed is correlated with polaron hopping between $Fe^{3+}\;and\;Fe^{4+}$ ions. The electrical resistivity displayed thermally activated temperature dependence above 200 K with an activation energy of 0.16 eV. In addition, the temperature dependence of thermoelectric power and resistivity suggests that the charge carrier responsible for conduction is strongly localized.

Dielectric Constant with $SiO_2$ thickness in Polycrystalline Si/ $SiO_2$II Si structure (다결정 Si/ $SiO_2$II Si 적층구조에서 $SiO_2$∥ 층의 두께에 따른 유전특성의 변화)

  • 송오성;이영민;이진우
    • Journal of Surface Science and Engineering
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    • v.33 no.4
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    • pp.217-221
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    • 2000
  • The gate oxide thickness is becoming thinner and thinner in order to speed up the semiconductor CMOS devices. We have investigated very thin$ SiO_2$ gate oxide layers and found anomaly between the thickness determined with capacitance measurement and these obtained with cross-sectional high resolution transmission electron microscopy. The thicknesses difference of the two becomes important for the thickness of the oxide below 5nm. We propose that the variation of dielectric constant in thin oxide films cause the anomaly. We modeled the behavior as (equation omitted) and determined $\varepsilon_{bulk}$=3.9 and $\varepsilon_{int}$=-4.0. We predict that optimum $SiO_2$ gate oxide thickness may be $20\AA$ due to negative contribution of the interface dielectric constant. These new results have very important implication for designing the CMOS devices.s.

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Dielectric and conductivity properties of defect double Perovskite La1/3TaO3 single crystal (결함 이중 Perovskite La1/3TaO3 단결정의 유전 및 전도특성)

  • Sohn, Jeong-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.6
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    • pp.215-219
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    • 2020
  • After the specimen of A-site defect double Perovskite La1/3TaO3 single crystal was manufactured, the dielectric properties have been studied between the temperature range of 10 and 800 K. Under 500 K, a paraelectric behavior has been shown, and above 550 K, a dielectric anomaly and a thermal history of dielectric constant has been shown. An activation energy by measurement of ac-conductivity has been the largest with 1.83 eV in the areas below 560 K, 0.35 eV in the areas of 560~690 K, and 0.28 eV in the areas of high temperature above 690 K. From these results, it is assumed that in the areas below 500 K, La3+-ion and vacancy-site are arranged in disorder to maintain a paraelectric phase. And in the areas near 560 K with the highest activation energy, a dielectric anomaly is attributes to rearrangement of La3+-ion due to conduction to vacancy-site or jumping.

Dielectric Constant Anomaly near the Consolute Point of a binary Mixture of MEEP and water (상전이 온도 근처에서 관찰되는 MEEP-물로 구성된 두 종류 섞임체의 유전상수 비정상성)

  • Cho, Chang-Ho;Seo, Young-Seok;Kim, Sei-Chang;Kim, Young-Baek
    • The Journal of Natural Sciences
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    • v.8 no.1
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    • pp.17-22
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    • 1995
  • Dielectric constant was measured near the consolute point of a binary mixture of water and Poly[bis(methoxyethoxyethoxy)phosphazene], MEEP. Dielectric constant changed incontinously at phase separation temperature plotted against the concentration to abtain coexistence curve. The critical temperatures and the critical concentration were $71^{\circ}C$, 5.5% as determined from the coexistence curve, respectivley. The critical exponent of dielectric constant, $\theta$, was 0.85. The dependence of dielectric constant on frequency is discussed in this report.

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Three-Dimensional High-Frequency Electromagnetic Modeling Using Vector Finite Elements (벡터 유한 요소를 이용한 고주파 3차원 전자탐사 모델링)

  • Son Jeong-Sul;Song Yoonho;Chung Seung-Hwan;Suh Jung Hee
    • Geophysics and Geophysical Exploration
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    • v.5 no.4
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    • pp.280-290
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    • 2002
  • Three-dimensional (3-D) electromagnetic (EM) modeling algorithm has been developed using finite element method (FEM) to acquire more efficient interpretation techniques of EM data. When FEM based on nodal elements is applied to EM problem, spurious solutions, so called 'vector parasite', are occurred due to the discontinuity of normal electric fields and may lead the completely erroneous results. Among the methods curing the spurious problem, this study adopts vector element of which basis function has the amplitude and direction. To reduce computational cost and required core memory, complex bi-conjugate gradient (CBCG) method is applied to solving complex symmetric matrix of FEM and point Jacobi method is used to accelerate convergence rate. To verify the developed 3-D EM modeling algorithm, its electric and magnetic field for a layered-earth model are compared with those of layered-earth solution. As we expected, the vector based FEM developed in this study does not cause ny vector parasite problem, while conventional nodal based FEM causes lots of errors due to the discontinuity of field variables. For testing the applicability to high frequencies 100 MHz is used as an operating frequency for the layer structure. Modeled fields calculated from developed code are also well matched with the layered-earth ones for a model with dielectric anomaly as well as conductive anomaly. In a vertical electric dipole source case, however, the discontinuity of field variables causes the conventional nodal based FEM to include a lot of errors due to the vector parasite. Even for the case, the vector based FEM gave almost the same results as the layered-earth solution. The magnetic fields induced by a dielectric anomaly at high frequencies show unique behaviors different from those by a conductive anomaly. Since our 3-D EM modeling code can reflect the effect from a dielectric anomaly as well as a conductive anomaly, it may be a groundwork not only to apply high frequency EM method to the field survey but also to analyze the fold data obtained by high frequency EM method.

Solution of TE Scattering by a Perfectly Conducting Strip Grating Over the Grounded Two Dielectric Layers Applying Fourier-Galerkin Moment Method (Fourier-Galerkin Moment Method를 이용한 접지된 2개 유전체층 위의 완전도체띠 격자구조에 의한 TE 산란의 해)

  • Yoon, Uei-Joong
    • Journal of Advanced Navigation Technology
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    • v.16 no.4
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    • pp.635-640
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    • 2012
  • In this paper, The TE (Transverse Electric) scattering problems by a perfectly conducting strip grating over a grounded two dielectric layers are analyzed by applying the conductive boundary condition and the FGMM (Fourier-Galerkin Moment Method) known as a numerical procedure, then the induced surface current density is expanded in a series of the multiplication of the unknown coefficient and the exponential function as a simple function. Generally, the reflected power gets increased according as the relative permittivity ${\epsilon}_{r2}$ and the thickness of dielectric layer $t_2$ of the region-2 in the presented structure gets increased, respectively. The sharp variations of the reflected power are due to resonance effects were previously called wood's anomaly, the numerical results show in good agreement with those of the existing papers.