• Journal of the Korean Electrochemical Society
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• v.8 no.4
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• pp.181-185
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• 2005

Lithium cobalt oxide thin film cathode, having thickness of $2.9{\mu}m$ with area of $4cm^2$, was deposited on platinum patterned alumina substrate by radio frequency magnetron sputtering. Li/Co molar ratio, which is an important factor for battery performance, was measured as a function of argon working pressure and applied R.F. power. Constant current charge and discharge performances were characterized with high rate discharge and cycling behavior. Using AC impedance analysis, internal resistance of the thin film battery was measured and simulated by proposed equivalent circuit model.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.33 no.2
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• pp.179-184
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• 2009

The Fuel Test Loop(FTL) which is capable of an irradiation testing under a similar operating condition to those of PWR(Pressurized Water Reactor) and CANDU(CANadian Deuterium Uranium reactor) nuclear power plants has been developed and installed in HANARO, KAERI(Korea Atomic Energy Research Institute). It consists of In-Pile Section(IPS) and Out-of Pile System(OPS). The IPS, which is located inside the pool is divided into 3-parts; the in-pool pipes, the IVA(IPS Vessel Assembly) and the support structures. The test fuel is loaded inside a double wall, inner pressure vessel and outer pressure vessel, to keep the functionality of the reactor coolant pressure boundary. The IVA is manufactured by local company and the functional test and verification were done through pressure drop, vibration, hydraulic and leakage tests. The brazing technique for the instrument lines has been checked for its functionality and performance. An IVA has been manufactured by local technique and have finally tested under high temperature and high pressure. The IVA and piping did not experience leakage, as we have checked the piping, flanges, assembly parts. We have obtained good data during the three cycle test which includes a pressure test, pressure and temperature cycling, and constant temperature.

• Resources Recycling
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• v.19 no.4
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• pp.51-57
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• 2010

As a recycling of Si sludge from Si wafer process, a Si-SiC-CuO-C composite material was synthesized and investigated as an anode material for lithium batteries. The Si sludge consisted of Si, SiC, machine oil, and metallic impurities. The oil and metal impurities was removed by organic washing, magnetic separation, and acid washing. The Si-SiC-CuO-C composite from the recovered Si-SiC mixture was prepared by high-energy mechanical milling. According to the electrochemical tests such as charge-discharge capacity and cycling behavior, it showed the improved cycle performance. The SiC and CuO-related phases were presumed to restrain the volume expansion of the anode and Fe, however, should be removed below 10 ppm prior to synthesis of the composite because it caused the capacity loss of the active material itself.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.2
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• pp.623-631
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• 2018

In this study, the degree of deterioration of concrete was investigated in the laboratory under conditions of carbonation and freeze-thaw cycling, which are the major causes of the deterioration of its performance. In this test, the carbonated concrete was subjected to combined freeze-thaw deterioration tests for up to 300 cycles, and its dynamic elastic modulus and compressive strength were measured. The evaluation of the effect of the water-binder ratio on normal concrete subjected to combined carbonization and freezing-thawing showed that its resistibility against such combined deterioration decreased more rapidly in the concrete with a water-binder ratio of 55 % compared with that having a water-binder ratio of 35 %. In the case where the concrete was blended with a mineral admixture consisting of fly ash and blast furnace slag at the same water-binder ratio, it showed an increase of its resistibility against combined deterioration.

• Journal of Korean Society of Steel Construction
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• v.15 no.4 s.65
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• pp.359-368
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• 2003

Design and detailing requirements of seismic provisions for Concentrically Braced Frames (CBF) were specified based on the premise that bracing members with large KL/r and low b/t have superior seismic performance. However, relatively few tests have been done to investigate the cyclic behavior of CBF. Therefore, the question lies on whether the compression member of CBF plays as significant a role as what has been typically assumed by design providers. In this paper, existing experimental data were reviewed to quantify the extent of hysteretic energy achieved by bracing members in past compression tests as well as the extent of degradation of the compression force given repeated cycling loading.

• The Journal of Advanced Prosthodontics
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• v.10 no.4
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• pp.300-307
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• 2018

PURPOSE. To investigate the fatigue and fracture resistance of computer-aided design and computer-aided manufacturing (CAD/CAM) ceramic molar crowns on dental implants and human teeth. MATERIALS AND METHODS. Molar crowns (n=48; n=8/group) were fabricated of a lithium-disilicate-strengthened lithium aluminosilicate glass ceramic (N). Surfaces were polished (P) or glazed (G). Crowns were tested on human teeth (T) and implant-abutment analogues (I) simulating a chairside (C, crown bonded to abutment) or labside (L, screw channel) procedure for implant groups. Polished/glazed lithium disilicate (E) crowns (n=16) served as reference. Combined thermal cycling and mechanical loading (TC: $3000{\times}5^{\circ}C/3000{\times}55^{\circ}C$; ML: $1.2{\time}10^6$ cycles, 50 N) with antagonistic human molars (groups T) and steatite spheres (groups I) was performed under a chewing simulator. TCML crowns were then analyzed for failures (optical microscopy, SEM) and fracture force was determined. Data were statistically analyzed (Kolmogorow-Smirnov, one-way-ANOVA, post-hoc Bonferroni, ${\alpha}=.05$). RESULTS. All crowns survived TCML and showed small traces of wear. In human teeth groups, fracture forces of N crowns varied between $1214{\pm}293N$ (NPT) and $1324{\pm}498N$ (NGT), differing significantly ($P{\leq}.003$) from the polished reference EPT ($2044{\pm}302N$). Fracture forces in implant groups varied between $934{\pm}154N$ (NGI_L) and $1782{\pm}153N$ (NPI_C), providing higher values for the respective chairside crowns. Differences between polishing and glazing were not significant ($P{\geq}.066$) between crowns of identical materials and abutment support. CONCLUSION. Fracture resistance was influenced by the ceramic material, and partly by the tooth or implant situation and the clinical procedure (chairside/labside). Type of surface finish (polishing/glazing) had no significant influence. Clinical survival of the new glass ceramic may be comparable to lithium disilicate.

• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.126-131
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• 2007

The durability problem of Prussian blue in non-aqueous $Li_+$-based electrolytes has been due to the degradation of the Prussian blue electrode matrix during the insertion/extraction processes by $Li_+$. In this work, we designed and synthesised the Prussian blue without reducing the electrochromic performance in non-aqueous $Li_+$-based electrolytes. Prussian blue was electrodeposited on a glass which has ITO coating, and the coating solution is a mixture solution of $FeCl_3\;and\;K_3Fe(CN)_6$ with deionized water added HCl, KCl, and LiCl, respectively. The durability of Prussian blue was evaluated by an in-situ transmittance measurement during a continuous and pulse potential cycling test, and measured by electroactive layer thickness due to evaluating the degradation.

• Journal of Electrochemical Science and Technology
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• v.11 no.1
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• pp.33-40
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• 2020

We present a new and facile design of a high-performance Li-S cell by integrating a Li₂S-impregnated glass fiber separator together with a common sulfur cathode. We find that a considerable amount of Li₂S is consumed amidst the first charge, and most of Li₂S disappears at the end of the second charge. During the charge process, additional sulfur material is formed and contributes to a significant enhancement of the discharge capacity (~1400 mAh/g), compared with a control cell (~1260 mAh/g) without Li₂S. Moreover, the Li₂S containing cell exhibits much higher cycling stability (a 31% increase from ~840 to ~1100 mAh/g in the 100th cycle) and rate capability (a 30% increase from ~580 to ~750 mAh/g at 2 C) than the control cell. Our results indicate that adopting Li₂S-containing separator is highly effective to improving the electrochemical performances of Li-S cells.

• Journal of Electrochemical Science and Technology
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• v.11 no.1
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• pp.92-98
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• 2020

SnO₂-based high-capacity anode materials are attractive candidate for the next-generation high-performance lithium-ion batteries since the theoretical capacity of SnO₂ can be ideally extended from 781 to 1494 mAh g^-1. Here 3D etched Cu foam is applied as a current collector for electron path and simultaneously a substrate for the SnO₂ coating, for developing an integrated electrode structure. We fabricate the 3D etched Cu foam through an auto-catalytic electroless plating method, and then coat the SnO₂ onto the self-supporting substrate through a simple sol-gel method. The catalytic dissolution of Cu metal makes secondary pores of both several micrometers and several tens of micrometers at the surface of Cu foam strut, besides main channel-like interconnected pores. Especially, the additional surface pores on etched Cu foam are intended for penetrating the individual strut of Cu foam, and thereby increasing the surface area for SnO₂ coating by using even the internal of Cu foam. The increased areal capacity with high structural integrity upon cycling is demonstrated in the SnO₂-coated 3D etched Cu foam. This study not only prepares the etched Cu foam using the spontaneous chemical reactions but also demonstrates the potential for electroless plating method about surface modification on various metal substrates.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.2
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• pp.160-171
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• 2013

$LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ powder for cathode materials in lithium rechargeable batteries was treated by atmospheric plasma containing hydrogen to investigate the relationship between charge/discharge performance and physical/chemical changes of materials. Hydrogen plasma at atmosphere pressure was irradiated on the surface of active materials, and the change for their crystal structure, surface morphology, and chemical composition were observed by XRD, SEM-EDS and titration method, respectively. The crystal structure and surface morphology of $H_2$ plasma-treated powders were not changed but their chemical compositions were slightly varied. For charge/discharge test, $H_2$ plasma affected initial capacity and rate capability of active materials but continuous cycling was not subject to plasma treatment. Therefore, it was observed that $H_2$ plasma treatment affected the surface of materials and caused the change of chemical composition.