• 공업화학
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• 제33권6호
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• pp.574-580
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• 2022

Dendrite 형태의 구리 입자 표면을 은으로 무전해 도금을 하는 과정에서, 치환도금(displacement plating)과 화학 환원도금(reducing electroless plating)을 병용하여 다양한 silver-coated copper (Ag@Cu) 입자들을 제조하였다. Ag@Cu 입자들의 물리화학적 특성은 SEM-EDS, TGA, XPS, XRD 및 BET 등으로 분석하였으며, 환원반응에 의하여 코팅되는 은은 구리 입자 표면에 나노 입자 형태로 형성되는 것을 확인할 수 있었다. Ag@Cu 입자들을 에폭시 수지와 복합화하여 도전성 필름을 제조하고 그의 열적 안정성을 평가하였다. 치환 반응과 환원 반응의 차이가 Ag@Cu 필름의 초기 저항 및 열적 안정성에 미치는 영향에 관하여 연구하였다.

• 한국표면공학회지
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• 제25권2호
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• pp.73-81
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• 1992

The composite coating of suspended inert particles $\alpha$-Al2O3 and copper from acid sulphate bath was investigated at the Rotating Disk Electrode. Effects of rotation speeds of electrode, physical properties of electrolyte, the size and concentration of suspended particles on the codeposition ratio of Al2O3 and the enhancement of mass transfer of copper ions were examined. Particularly, new experimental method for the measurement of the codeposition ratio was suggested and also the characteristics of the composite coating layer were measured by Rutherford Backscattering Spectrometry. Mass transfer of suspended particles system were increased up to 40% more than those of without suspended particles system. Optimum conditions of current density, hydrodynamics of RDE, and particles concentration showing maximum codeposition ratio were appeared in our experimental ranges. It was shown that the suspended inert particles were codeposited mainly near the surface of the composite coating layer.

• Journal of Electrical Engineering and Technology
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• 제12권2호
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• pp.865-873
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• 2017

Converter transformer is the key equipment of high voltage direct current transmission system. The solid suspending particles originating from the process of installation and operation of converter transformer have significant influence on the insulation performance of transformer oil, especially in presence of DC component in applied voltage. Under high electric field, the particles easily lead to partial discharge and breakdown of insulating oil. This paper investigated copper particle effect on the breakdown voltage of transformer oil at combined AC and DC voltage. A simulation model with single copper particle was established to interpret the particle effect on the breakdown strength of insulating oil. The experimental and simulation results showed that the particles distort the electric field. The breakdown voltage of insulating oil contaminated with copper particle decreases with the increase of particle number, and the breakdown voltage and the logarithm of particle number approximately satisfy the linear relationship. With the increase of the DC component in applied voltage, the breakdown voltage of contaminated insulating oil decreases. The simulation results show that the particle collides with the electrode more frequently with more DC component contained in the applied voltage, which will trigger more discharge and decrease the breakdown voltage of insulating oil.

• Korean Chemical Engineering Research
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• 제45권6호
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• pp.560-565
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• 2007

화학환원법을 이용하여 폐동분 수용액에 환원제인 hydrazine을 첨가하여 $0.11{\sim}0.64{\mu}m$ 크기의 Cu 미립자를 제조하였으며, 이 과정 중 hydrazine의 첨가량이 얻어진 분말의 물성에 미치는 영향을 살펴보았다. 또한 분말합성 과정 중 분산제인 polyvinyl alcohol(PVA) 또는 polyvinyl pyrrolidone(PVP) 첨가가 분말의 물성에 미치는 영향도 조사하였다. 1 M 농도의 폐동분 수용액에 hydrazine이 0.8 mol, 1.0 mol 첨가된 경우에는 Cu와 $Cu_2O$의 혼합물을 나타내어 순수한 Cu 분말을 생성하지 못했다. 반면 적당량의 hydrazine(1.2 mol)이 첨가된 경우에는 순수한 Cu 분말이 생성되었다. 또한 얻어진 Cu 분말의 평균크기는 hydrazine과 분산제의 첨가량이 증가함에 따라 감소하였다. 한편 분말의 응집을 억제하는 분산제로서 PVA의 사용이 PVP 보다 더욱 효과적이었다.

• 한국분말재료학회지
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• 제11권5호
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• pp.383-390
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• 2004

In order to investigate behavior of abnormal expansion of the iron-copper compacts, we compared the dilatometric curves of the compacts which mixed the copper powder to the iron powder with those of compacts which mixed the copper powder to the iron-copper alloy powder. The dilatometric curves were obtained below the sintering conditions, which heated up to 115$0^{\circ}C$ by a heating rate of 1$0^{\circ}C$/min, held for 60min at 115$0^{\circ}C$ and cooled down at a rate of 2$0^{\circ}C$/min to room temperature. The dilatometric curves of the compacts showed the different expansion behavior at temperatures above the copper melting point in spite of same chemical composition. All of the compacts of former case showed large expansion, but all of the compacts in latter case showed large contraction. The microstructures of sintered compacts also showed the different progress in alloying of the copper into the iron powder. Namely we could observe the segregation at alloy part of copper into iron powder in case of the sintered compacts, which mixed the copper powder to the iron powder, but could not observe the segregation in compacts which mixed the copper powder to the iron-copper alloy powder. But the penetration of liquid copper into the interstices between solid particles was occurred at both cases. Therefore, the showing of the different dimensional changes in the compacts in spite of same chemical composition is due to more the alloying of copper into iron powder than the penetration of liquid copper into the interstices between solid particles.

• 한국건축시공학회지
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• 제23권4호
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• pp.393-404
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• 2023

본 연구에서는 구리입자를 이용한 항균 UV경화도료를 제조하고 투명성을 평가한 결과 일반 UV경화도료와 동등이상인 90%이상의 전광선투과율을 나타내었다. 실란커플링제로 표면 개질한 구리입자가 20wt% 첨가된 항균 UV경화도료를 코팅한 항균 목질 마루판의 피로 시험 전후의 항균 성능 평가 결과 6시간 후 세균감소율이 99.9% 로 우수한 항균 성능을 나타내었다.

• 공업화학
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• 제29권6호
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• pp.782-788
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• 2018

서브 미크론 구리-은 코어-쉘 Cu@Ag 입자를 초음파화학과 결합된 금속교환 반응으로 합성하고 인쇄용 전자부품을 위한 저렴한 전도성 페이스트 적용을 평가하였다. 코어-쉘의 합성을 위한 반응에서 코어로 사용된 $Cu_2O/Cu$ 복합체의 $Cu_2O$는 초음파화학 반응으로 Cu로 환원되고 Cu 원자는 Ag의 금속교환 반응의 환원제로 작용하여 코어 표면에 Ag가 코팅된 코어-쉘 구조를 얻었다. TEM-EDS와 TG-DSC를 이용하여 서브 미크론 입자의 코어-쉘 구조를 확인하였다. 70 wt% Cu@Ag를 용매에 분산시킨 전도성 페이스트를 결합제와 습윤제를 사용하여 제조하고, 스크린 인쇄법을 사용하여 폴리아미드 필름상에 코팅하였다. Ag 함량이 8 at%와 16 at%인 Cu@Ag 입자를 함유하는 인쇄된 페이스트 필름은 공기 중의 $180^{\circ}C$에서 소결한 후 각각 96.2와 $38.4{\mu}{\Omega}cm$의 낮은 비저항 값을 나타내었다.

• 공업화학
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• 제20권2호
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• pp.201-207
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• 2009

Dodecanol 합성을 위한 methyl dodecanoate의 수소화반응을 위하여 copper chromite를 세라믹법, 공침법 및 개량된 공침법으로 합성하였다. 입자의 형상은 SEM 및 XRD로 확인하였으며 수소화 반응후 얻어진 생성물은 GC, GC/MSD 및 NMR로 분석하였다. 합성된 입자는 (1) 3.2에서 $7.0{\mu}m$ 크기의 구형형태(세라믹법), (2) 50에서 500 nm 크기의 구형이 혼재한 판형태(공침법) 및 (3) 작고 균일한 구형형태(개량된 공침법)를 보였다. 입자의 크기를 제어하기 위하여 PEG, Span 80 및 polyacrylate등 다양한 분산제 용액에서 copper chromite를 합성하였다. PEG (Mw = 4000) 수용액에서 합성한 입자가 30~50 nm 크기로 가장 작고 균일하였으며, $280^{\circ}C$ 및 100 atm에서 촉매의 반응성을 테스트한 결과, dodecanol의 수율은 79.9%로 얻어졌다. 수소화반응에서 촉매의 반응성은 촉매의 크기가 작고 균일할수록 높아지는 경향을 보였다. 최적화된 반응조건인 $280^{\circ}C$ 및 240 atm에서 dodecanol의 수율은 95.5%였다.

• 한국재료학회지
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• 제27권4호
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• pp.221-228
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• 2017

Various morphologies of copper oxide (CuO) have been considered to be of both fundamental and practical importance in the field of electronic materials. In this study, using Cu ($0.1{\mu}m$ and $7{\mu}m$) particles, flake-type CuO particles were grown via a wet oxidation method for 5min and 60min at $75^{\circ}C$. Using the prepared CuO, AlN, and silicone base as reagents, thermal interface material (TIM) compounds were synthesized using a high speed paste mixer. The properties of the thermal compounds prepared using the CuO particles were observed by thermal conductivity and breakdown voltage measurement. Most importantly, the volume of thermal compounds created using CuO particles grown from $0.1{\mu}m$ Cu particles increased by 192.5 % and 125 % depending on the growth time. The composition of CuO was confirmed by X-ray diffraction (XRD) analysis; cross sections of the grown CuO particles were observed using focused ion beam (FIB), field emission scanning electron microscopy (FE-SEM), and energy dispersive analysis by X-ray (EDAX). In addition, the thermal compound dispersion of the Cu and Al elements were observed by X-ray elemental mapping.

• 한국분말재료학회지
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• 제11권2호
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• pp.171-178
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• 2004

Effects of liquid phase and reinforcing particle morphology on the sintering of Al-6 wt％Cu-10 vol％ $Al_2O_3$ or SiC particles were studied in regards to densification, structure and transverse rupture properties. The Al-Cu liquid phase penetrated the boundaries between the aluminum matrix powders and the interfaces with reinforcing particles as well, indicating a good wettability to the powders. This enhanced the densification during sintering and the resulting strength and ductility. Since most of the copper added, however, was dissolved in the liquid phase and formed a brittle $CuAl_2$ phase upon cooling rather than alloyed with the aluminum matrix, the strengthening effect by the copper was not fully realized. Reinforcing particles of agglomerate type were found less suitable for the liquid phase sintering than solid type particles. $Al_2O_3$ and SiC particles protluced little difference on the sintering behavior but their size had a large effect. Repressing of the sintered composites increased density and bending properties but caused debonding at the matrix-particle interfaces and also fracturing of the particles.