• Title/Summary/Keyword: conductivity measurement

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Performance Evaluation of Platinum Dispersed Self-humidifying Polymer Electrolyte Membrane Prepared by Using RF Magnetron Sputter

  • Kwak, Sang-Hee;Yang, Tae-Hyun;Kim, Chang-Soo;Yoon, Ki-Hyun
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.118-122
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    • 2003
  • The performance evaluation on Pt loading in the self-humidifying polymer electrolyte membrane for Polymer Electrolyte Mem-Brane Fuel Cell(PEMFC) was investigated by using single cell test and measurement of membrane resistance. The self-humidifying membrane comprised two membranes made of perfluorosulfonylfluroride copolymer resin and fine Pt particles tying between them, coated by sputtering. From the results of performance characteristics of self-humidifying membrane cell with different Pt loading, a single cell using self-humidifying membrane with 0.15 mg/$\textrm{cm}^2$ Pt loading showed better performance than that with the others over entire current density. Also, a single cell with 0.15 mg/$\textrm{cm}^2$ Pt loading had a lower resistance value than the other cells under externally nonhumidifying condition. It is indicated that the water produced in the membrane cell with 0.15 mg/$\textrm{cm}^2$ Pt loading showed a higher provision to maintain ionic conductivity of the membrane than the other cells. The optimum amount of Pt particles embedded in the membrane for self-humidifying PEMFC was determined to be about 0.15 mg/$\textrm{cm}^2$.

Complex Formation between 3CaO.$Al_2O_3$ and Sodium Gluconate (3CaO.$Al_2O_3$와 글루콘산 나트륨간의 착체형성)

  • 김창은;이승헌;이승규
    • Journal of the Korean Ceramic Society
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    • v.27 no.7
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    • pp.883-890
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    • 1990
  • Although various theories have been presented on the mechanism of setting retardation of 3CaO·Al2O3, this phenomenon has not yet been defined. The present investigation was initiated in order to solve the mechanism from the view point of coordination chemistry. The solubility of Ca(OH)2 in aquous solution of soldium gluconate was abnormally high, and was proportional to the concentration of sodium gluconate. These phenomena were attributed to the soluble complex formation, that is, (1 : 1)Ca complex formation between calcium ion and gluconate ion. The author's proposal was further confirmed by the results of electrical conductivity measurement. The formation of calcium complex was also supported by IR spectra and DTA. When sodium gluconate was dissolved in 3CaO·Al2O3 suspension, calcium complex and aluminum complex were formed. As an experimental evidence, the asymmetric stretching vibration of carboxyl group in sodium gluconate was observed to be shifted to lower frequency from 1625cm-1 to 1585cm-1 characteristically. The characteristic exothermic peaks of the complexs at 430℃ and 700℃ observed in DTA curve also suggest the formation of the complexs between sodium gluconate and 3CaO·Al2O3.

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Non-Invasive in vivo Loss Tangent Imaging: Thermal Sensitivity Estimation at the Larmor Frequency

  • Choi, Narae;Kim, Min-Oh;Shin, Jaewook;Lee, Joonsung;Kim, Dong-Hyun
    • Investigative Magnetic Resonance Imaging
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    • v.20 no.1
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    • pp.36-43
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    • 2016
  • Visualization of the tissue loss tangent property can provide distinct contrast and offer new information related to tissue electrical properties. A method for non-invasive imaging of the electrical loss tangent of tissue using magnetic resonance imaging (MRI) was demonstrated, and the effect of loss tangent was observed through simulations assuming a hyperthermia procedure. For measurement of tissue loss tangent, radiofrequency field maps ($B_1{^+}$ complex map) were acquired using a double-angle actual flip angle imaging MRI sequence. The conductivity and permittivity were estimated from the complex valued $B_1{^+}$ map using Helmholtz equations. Phantom and ex-vivo experiments were then performed. Electromagnetic simulations of hyperthermia were carried out for observation of temperature elevation with respect to loss tangent. Non-invasive imaging of tissue loss tangent via complex valued $B_1{^+}$ mapping using MRI was successfully conducted. Simulation results indicated that loss tangent is a dominant factor in temperature elevation in the high frequency range during hyperthermia. Knowledge of the tissue loss tangent value can be a useful marker for thermotherapy applications.

SPICE Modeling for Thermoelectric Modules (열전 모듈의 SPICE 모델링)

  • Park, Soon-Seo;Cho, Sung-Kyu;Baatar, Nyambayar;Kim, Shi-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.4
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    • pp.7-12
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    • 2010
  • We have developed a SPICE compatible model of thermoelectric devices, and a parameter extracting technique only by electrical and temperature measurement by using Harman method was proposed. The proposed model and parameter extraction technique do not require experimental data from thermal conductivity measurements. The maximum error between extracted parameters extracted by proposed method and conventional method was about 14%, which is not a severe mismatch for real application. The proposed model is applicable to design of both for thermoelectric coolers and thermo electric generators.

Development of an insulation performance measurement unit for full-scale LNG cargo containment system using heat flow meter method

  • Lee, Jin-sung;Kim, Kyung-su;Kim, Yooil
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.10 no.4
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    • pp.458-467
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    • 2018
  • Efforts have been made in this paper to develop the measuring device for the insulation performance of full scale NO96 LNG CCS. The facility was designed to maintain environmental conditions which are similar to operation conditions of full scale LNG CCS. In the facility, the heat sink boundary was kept cryogenic temperature by cold chamber which contains liquefied nitrogen and heat source boundary was made by external case heated by natural convection. Heat Flow Meter method (HFM) was applied to this facility, hence Heat Flux Sensors (HFS) were attached to specimen. The equivalent thermal conductivity of full scale NO96 unit box was targeted to measure and PUF of same size was used for the calibration test. Additionally, the finite element analysis was carried out to check the performance of the developed test facility and experimental results were also compared with those predicted by the numerical method.

Parametric Study of Methanol Chemical Vapor Deposition Growth for Graphene

  • Cho, Hyunjin;Lee, Changhyup;Oh, In Seoup;Park, Sungchan;Kim, Hwan Chul;Kim, Myung Jong
    • Carbon letters
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    • v.13 no.4
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    • pp.205-211
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    • 2012
  • Methanol as a carbon source in chemical vapor deposition (CVD) graphene has an advantage over methane and hydrogen in that we can avoid optimizing an etching reagent condition. Since methanol itself can easily decompose into hydrocarbon and water (an etching reagent) at high temperatures [1], the pressure and the temperature of methanol are the only parameters we have to handle. In this study, synthetic conditions for highly crystalline and large area graphene have been optimized by adjusting pressure and temperature; the effect of each parameter was analyzed systematically by Raman, scanning electron microscope, transmission electron microscope, atomic force microscope, four-point-probe measurement, and UV-Vis. Defect density of graphene, represented by D/G ratio in Raman, decreased with increasing temperature and decreasing pressure; it negatively affected electrical conductivity. From our process and various analyses, methanol CVD growth for graphene has been found to be a safe, cheap, easy, and simple method to produce high quality, large area, and continuous graphene films.

Performance Evaluation of a $SF_6$ Gas Circuit Breaker with Experimental Investigation (초고압 $SF_6$ 가스 차단기의 실험적 차단성능 평가)

  • Jeong, Y.W.;Park, H.T.;Oh, I.S.
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.96-99
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    • 2005
  • In this study, we build system and techniques of evaluating the interruption performance of the GCB with experimental method. We constructed a simplified synthetic test circuit of which ability is up to 245kV, 50kA BTF test. And We composed a model test circuit breaker with puffer assisted self blasting type GCB. With this circuit breaker, we carried out the experiment of no load and SLF90. During the tests, we measured the several factors such as stroke, pressure, arc temperature, the voltage and current near the current zero and dI/dt, dV/dt. Arc conductivity before 200ns before current zero which is one of the indexes of the thermal recovery of a GCB was measured. With these kinds of measurement, we could estimate the performance of a GCB fundamentally. Futhermore these results were used to adjust the arc modeling with CFD(computational fluid dynamics) and we could increase the plausibility of the analytical method.

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Evaluation of effects of textile wastewater on the quality of cotton fabric dye

  • Kaykioglu, Gul;Ata, Reyhan;Tore, Gunay Yildiz;Agirgan, Ahmet Ozgur
    • Membrane and Water Treatment
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    • v.8 no.1
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    • pp.1-18
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    • 2017
  • In this study, reuse of biologically treated wastewater of denim washing and dyeing industry has been evaluated by membrane technologies. After that experiments were carried out at laboratory scale in textile dyeing unit by using obtained permeate water samples on 100% cotton based raw fabric belonging to examined industry. During membrane experiments, two different UF (UC100 and UC030) and two different NF (NP010 and NP030) were evaluated under alternative membrane pressures. In permeate water obtained on selected samples, conductivity at the range of $1860-2205{\mu}S/cm$, hardness at the range of 60 to 80 mg/L, total color at the range of 2.4 to 7.6 m-1 and COD at the range of 25-32 mg/L was determined. The following analyzes were performed for the dyed fabrics: perspiration fastness, rub fastness, wash fastness, color fastness to water, color fastness to artificial light, color measurement through the fabric. According to analysis results, selected permeate water have no negative impact on dyeing quality. The study showed that membrane filtration gave good performance for biologically treated textile wastewater, and NF treatment with UF pre-treatment was suitable option for reuse of the effluents.

Development of a Fully-Controlled Plant Growth System(II) - An Integrated Control System - (완전제어형 실험용 작물생육장치의 개발(II) - 복합 환경제어 시스템 -)

  • Shim, K.D.;Ryu, K.H.;Noh, S.H.;Hong, S.H.
    • Journal of Biosystems Engineering
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    • v.17 no.4
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    • pp.344-353
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    • 1992
  • This study was carried out to develop a fully-controlled plant growth system for studying the effects of environmental factors on plant growth. The plant growth system consists of the growth chamber, the measurement system for sensing and signal conditioning the environmental factors and the control system which includes control algorithm required for optimum operation and on-line monitoring. The results of the study on the performance of the controlled plant growth system are summarized as follows : 1. Under the light intensity of 18,000~20,000 lux, the temperature was controlled in the range of $22{\pm}0.4^{\circ}C$, the relative humidity of $70{\pm}5%$ respectively. 2. The $CO_2$ concentration was controlled in the range of $1,000{\pm}40ppm$(from 1st to 4th day) and $1,500{\pm}40ppm$(from 4th to 9th day). 3. The electric conductivity(EC) and pH of the nutrient solution were controlled in the range of $1.9{\pm}0.2mS/cm$ and $6.8{\pm}0.5pH$ respectively. 4. Under the above environmental conditions, the average fresh weight of leaf lettuce increased from 10g to 74g in 9 days with 24 hour lighting.

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Measurement of an Ion Concentration in Drinking Water by lon Chromatography (Ion Chromatography에 의한 음료수중 음이온 함량에 관한 연구)

  • Kim Hyung-Suk
    • Journal of environmental and Sanitary engineering
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    • v.4 no.1 s.6
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    • pp.7-15
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    • 1989
  • According to the increase of population and development of industrialization air and water pollution problems are still keeping going to great nuisance to human activities. Specially man should drink 2l clean water to maintain our health every day, but we afraid of drink the city tap water because of the contaminants like heavy metals, bacteria trihalomethane, etc. In the analysis of the anions in potable water, we usually adapt the Standard methods for the Examination of Water and Wastewater. But this method is tedious and time consuming, so the Ion Chromatography method is now used in research of water quality. Author worked with Ion Chromatography in measuring the anions in drinking water by attaching conductivity dector to normal High Performance Liquid Chromatograph. Low-capacity ion-exchange coulmn and dilute eluents, 0.00M phthalic aic was used in this study. The concentration of chloride ion was 1.55 ppm$\~$3 8.81ppm, nitrate ion was 5.45 ppm$\~$18.27ppm, and sulfate ion was 19.64 ppm$\~$28.86 ppm. The phosphate ion was detected only in Apt. tap water as 167.99 ppm whose amount was supposed to be used as a water pipe cleaner.

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