• Journal of the Korean Ceramic Society
• /
• v.31 no.11
• /
• pp.1271-1282
• /
• 1994

The surface of commercial alumina fibers used for reinforcing the MCFC matrix has been coated with ${\gamma}$-LiAlO2 being the same material as the matrix, by the sol-gel method in order to enhance the corrosion resistivity of alumina fibers. Stable LiAlO2 complex polymeric sols for coating was synthesized by mixing aluminum alkoxide polymeric sols with LiNO3 solution. It was found that the LiAlO2 polymeric sol prepared by adding the mixed chelate of acethylacetone and triethanolamine (the mole ratio of AA/TEA = 0.125/0.75) to the 1 mole of the aluminum alkoxide had the excellent stability and coating behavior. The crystalline structure of the dried gel from the ${\gamma}$-LiAlO2 sol was completely transformed into the ${\gamma}$-LiAlO2 at $600^{\circ}C$. The optimum viscosity of the sol for coating the alumina long fibers was 30~40 cP, while it was 12~20 cP in case of the short fiber coating. The ${\gamma}$-LiAlO2 coated alumina fibers without defects fully densified when heat-treated at 120$0^{\circ}C$.

• Journal of the Korean Society of Safety
• /
• v.9 no.1
• /
• pp.28-30
• /
• 1994

Ultrasonic for MoSi$_2$/Y. C. Kim, C. K. Namkoong/MoSi$_2$in the silicides has excellence in the oxidation and corrosion resistence. When the solid state bonding sintered-MoSi$_2$/metal or the thermal sprayed coating by powder-MoSi$_2$on the metal are carried out, the defects may be occured at the bonded surface. So, the method for evaluating the existence of the defects by non-destructive inspection is strongly desired. Here, the characteristics of ultrasonic for sintered-MoSi$_2$are elucidated and the possibility of the detection of defects using by ultrasonic is investigated.

• Electrical & Electronic Materials
• /
• v.8 no.5
• /
• pp.633-639
• /
• 1995

Dropouts in magnetic media are a primary quality deficiency which is detrimental to magnetic signal quality and thus the major impediment to error-free recording, especially in high density digital recorders. The specific form of defects and causes found to be responsible for signal dropouts occurring in magnetic tape were studied. Dropout occurred when the RF signal falls to low level due to the various types of surface defects. However, the fall in the level of the RF signal in gravure roll coated tapes was most often caused by foreign particles adhering to the magnetic tape. It was also shown from the present study that scattered particles trapped under the tape surface or put on the top can lift it as it crosses the head, creating a spherical tent shaped defect and causing a temporary signal drop. Dropout producing substances were identified through optical and microchemical analyses. The results were correlated with measured electrical signal losses combined with analytical microscopy to clarify source identification of defects.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1994.04a
• /
• pp.158-162
• /
• 1994

Test results to evaluate the mechanical properties of epoxy-coated bars and corrosion protection characteristics of epoxy coating on the bars are described. The results show good adhesion and abrasion resistance satisfying the requirements in relevant standards. The test results also show that for a coating thickness ranging from 150${\mu}{\textrm}{m}$ to 300${\mu}{\textrm}{m}$, satisfactory results are obtained regarding bendability. Cautions shall be required when bending epoxy-coated bars at a high bending degree and at a low temperature. The results of accelerated corrosion tests show good corrosion resistance. However, surface defects from the steel itself and insufficient blast-clean process form weak points resulting blistering or disbonding of the coating. The use of epoxy-coated bars is expected to help protect corrosion of reinforcement and extend the service life of reinforced concrete structures.

• Corrosion Science and Technology
• /
• v.16 no.3
• /
• pp.151-159
• /
• 2017

The MA8 alloy (formula Mg-Mn-Се) has been shown to have greater corrosion stability than the VMD10 magnesium alloy (formula Mg-Zn-Zr-Y) in chloride-containing solutions by Scanning Vibrating Electrode Technique (SVET) and by optical microscopy, gravimetry, and volumetry. It has been established that the crucial factor for the corrosion activity of these samples is the occurrence of microgalvanic coupling at the sample surface. The peculiarities of the kinetics and mechanism of the corrosion in the local heterogeneous regions of the magnesium alloy surface were investigated by localized electrochemical techniques. The stages of the corrosion process in artificial defects in the coating obtained by plasma electrolytic oxidation (PEO) at the surface of the MA8 magnesium alloy were also studied. The analysis of the experimental data enabled us to determine that the corrosion process in the defect zone develops predominantly at the magnesium/coating interface. Based on the measurements of the corrosion rate of the samples with PEO and composite polymer-containing coatings, the best anticorrosion properties were displayed by the composite polymer-containing coatings.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2018.05a
• /
• pp.279-280
• /
• 2018

The waterproofing material can be roughly divided into a coating material and a sheet waterproofing material. In the case of coating waterproofing materials, sheet waterproofing materials, which are easy to use in terms of workability and quality control, have been recently used because of their incomplete use of coating thickness, long curing time and poor blending due to in situ blending. However, in the case of the sheet waterproofing material, since the sheet overlapping portion is inevitably generated, various defects (breakage due to the behavior) are frequently observed. Therefore, it is imperative to establish fundamental measures to minimize this.

• Corrosion Science and Technology
• /
• v.14 no.5
• /
• pp.218-225
• /
• 2015

The electrochemical behaviors of various metals with and without diamond-like-carbon (DLC) coating in 3.5 wt% NaCl solution were investigated. The effect of hydrodynamic conditions was focused by employing a rotating disc electrode (RDE). The experimental results showed that each bare metal had a more positive corrosion potential and a higher corrosion rate due to enhanced oxygen transport at the higher rotating speed of the RDE. DLC coating caused a substantial increase in the corrosion resistance of all metals studied. However, localized corrosion was still found in the DLC-coated metal at sites where deposition defects existed. Surface morphology examination was performed after the electrochemical test to confirm the roles of hydrodynamic conditions and DLC coating.

• Journal of Powder Materials
• /
• v.26 no.5
• /
• pp.421-431
• /
• 2019

In this study, the formation, microstructure, and wear properties of Colmonoy 88 (Ni-17W-15Cr-3B-4Si wt.%) + Stellite 1 (Co-32Cr-17W wt.%) coating layers fabricated by high-velocity oxygen fuel (HVOF) spraying are investigated. Colmonoy 88 and Stellite 1 powders were mixed at a ratio of 1:0 and 5:5 vol.%. HVOF sprayed self-fluxing composite coating layers were fabricated using the mixed powder feedstocks. The microstructures and wear properties of the composite coating layers are controlled via a high-frequency heat treatment. The two coating layers are composed of ${\gamma}-Ni$, $Ni_3B$, $W_2B$, and $Cr_{23}C_6$ phases. Co peaks are detected after the addition of Stellite 1 powder. Moreover, the WCrB2 hard phase is detected in all coating layers after the high-frequency heat treatment. Porosities were changed from 0.44% (Colmonoy 88) to 3.89% (Colmonoy 88 + ST#1) as the content of Stellite 1 powder increased. And porosity is denoted as 0.3% or less by inducing high-frequency heat treatment. The wear results confirm that the wear property significantly improves after the high-frequency heat treatment, because of the presence of well-controlled defects in the coating layers. The wear surfaces of the coated layers are observed and a wear mechanism for the Ni-based self-fluxing composite coating layers is proposed.

• Korean Journal of Materials Research
• /
• v.31 no.12
• /
• pp.704-709
• /
• 2021

In the flux used in the batch galvanizing process, the effect of the component ratio of NH₄Cl to ZnCl₂ on the microstructure, coating adhesion, and corrosion resistance of Zn-Mg-Al ternary alloy-coated steel is evaluated. Many defects such as cracks and bare spots are formed inside the Zn-Mg-Al coating layer during treatment with the flux composition generally used for Zn coating. Deterioration of the coating property is due to the formation of AlCl_x mixture generated by the reaction of Al element and chloride in the flux. The coatability of the Zn-Mg-Al alloy coating is improved by increasing the content of ZnCl₂ in the flux to reduce the amount of chlorine reacting with Al while maintaining the flux effect and the coating adhesion is improved as the component ratio of NH₄Cl to ZnCl₂ decreases. Zn-Mg-Al alloy-coated steel products treated with the optimized flux composition of NH₄Cl·3ZnCl₂ show superior corrosion resistance compared to Zn-coated steel products, even with a coating weight of 60 %.

• Corrosion Science and Technology
• /
• v.12 no.6
• /
• pp.288-294
• /
• 2013

When the automotive body enters an electrocoating tank while applying an electric current, its steel surface is exposed to a very low induced current. Consequently, surface defects of coating may arise if the steel surface has lack of electric uniformity due to local defects such as local oxide. In this study, we investigated the preceding assessment methods to evaluate steel susceptibility of the low induced current during electrocoating before mass production. Prior to general electrocoating, we applied low constant voltage such as 3V or low constant current densities such as $0.35mA/cm^2$ and $0.50mA/cm^2$. In result, we confirmed that such methods were efficient for assessing steel susceptibility of low induce current during electrocoating.