• Transactions of the Korean hydrogen and new energy society
• /
• v.18 no.1
• /
• pp.32-39
• /
• 2007

CO oxidation and selective CO oxidation of $La_xCe_{1-x}Co_yCu_{1-y}O_{3-{\alpha}}$ perovskite(x=1, 0.9, 0.7. 0.5; y=1, 0.9, 0.7, 0.5) were investigated. For CO oxidation, catalytic activities were studied according to different preparation conditions such as pH and calcination temperature. The influence of the change of the $O_2$ concentration for selective CO oxidation was studied, too. The substitution of Ce for La improved the catalytic activity for CO oxidation and selective CO oxidation and best activity was observed for $La_{0.7}Ce_{0.3}CoO_3$ prepared at pH 11 and calcined at $600^{\circ}C$. The temperature of 90% CO conversion for CO oxidation using $La_{0.7}Ce_{0.3}CoO_3$ was $230^{\circ}C$. In contrast to the enhancement effect by Ce substitution, the partial substitution of Cu for Co in $LaCo_yCu_{1-y}O_{3-{\alpha}}$ decreased catalytic activities for CO oxidation reaction compared to that using $LaCoO_3$. For selective CO oxidation, the best CO conversion was 66% at $230^{\circ}C$ for $La_{0.7}Ce_{0.3}CoO_3$. The CO conversion of $La_{0.7}Ce_{0.3}CoO_3$ was greatly increased from 66% to 91% as increasing $O_2$ concentration from 1% to 2%.

• Journal of the Korean Magnetics Society
• /
• v.25 no.5
• /
• pp.139-143
• /
• 2015

The surface magnetism of the CsCl structured Co binary compounds, CoX (X = Ti, V, Nb) (001) surface was studied with the calculated electronic structure data obtained by the full-potential linearized augmented plane-wave (FLAPW) method. The magnetic moment of the surface Co atom of the Co-terminated CoTi(001) system was $1.19{\mu}_B$, which is enhanced compared with that of the Co atom in the center layer. The magnetic moment of the surface V atom in the V terminated the CoV(001) system was $1.64{\mu}_B$, which is more than twice of the center layered V atom. The magnetic moment of surface Co atom in the Co terminated CoV(001) system has the value of $1.34{\mu}_B$, little bit smaller than the bulk value. The magnetism was disappeared in the Co terminated CoNb(001) system, and the magnetic moment of the surface Nb atom in the Nb terminated CoNb(001) system was $0.26{\mu}_B$ which is little bit decreased compared to the center layer value.

• International Journal of Computer Science & Network Security
• /
• v.22 no.10
• /
• pp.191-200
• /
• 2022

Constrained Application Protocol (CoAP) is a standardized protocol by the Internet Engineering Task Force (IETF) for the Internet of things (IoT). IoT devices have limited computation power, memory, and connectivity capabilities. One of the significant problems in IoT networks is congestion control. The CoAP standard has an exponential backoff congestion control mechanism, which may not be adequate for all IoT applications. Each IoT application would have different characteristics, requiring a novel algorithm to handle congestion in the IoT network. Unnecessary retransmissions, and packet collisions, caused due to lossy links and higher packet error rates, lead to congestion in the IoT network. This paper presents an adaptive congestion control protocol for CoAP, Adaptive Congestion Control with a Backoff algorithm (ACCB). AACB is an extension to our earlier protocol AdCoCoA. The proposed algorithm estimates RTT, RTTVAR, and RTO using dynamic factors instead of fixed values. Also, the backoff mechanism has dynamic factors to estimate the RTO value on retransmissions. This dynamic adaptation helps to improve CoAP performance and reduce retransmissions. The results show ACCB has significantly higher goodput (49.5%, 436.5%, 312.7%), packet delivery ratio (10.1%, 56%, 23.3%), and transmission rate (37.7%, 265%, 175.3%); compare to CoAP, CoCoA+ and AdCoCoA respectively in linear scenario. The results show ACCB has significantly higher goodput (60.5%, 482%,202.1%), packet delivery ratio (7.6%, 60.6%, 26%), and transmission rate (40.9%, 284%, 146.45%); compare to CoAP, CoCoA+ and AdCoCoA respectively in random walk scenario. ACCB has similar retransmission index compare to CoAp, CoCoA+ and AdCoCoA respectively in both the scenarios.

• Proceedings of the Korean Radioactive Waste Society Conference
• /
• 2018.11a
• /
• pp.295-296
• /
• 2018

• Journal of Korean Society of Environmental Engineers
• /
• v.36 no.3
• /
• pp.185-191
• /
• 2014

In this paper, absorption and reaction characteristics of low $CO_2$ and alkanolamines were investigated. As MEA concentrations increase 1, 2 and 3 wt%, $CO_2$ loadings decrease 0.34 mol-$CO_2/mol$-absorbent, 0.32 mol-$CO_2/mol$-absorbent and 0.3 mol-$CO_2/mol$-absorbent, respectively. Also, $CO_2$ loadings decrease from 0.32 mol-$CO_2/mol$-absorbent, 0.30 mol-$CO_2/mol$-absorbent and 0.28 mol-$CO_2/mol$-absorbent as AMP concentrations increase 1, 2 and 3 wt%. Experimental results with blending solutions show that $CO_2$ loading was the highest, 0.52 mol-$CO_2/mol$-absorbent, when 0.5 wt% MEA and 0.5 wt% AMP were blended.

• Tribology and Lubricants
• /
• v.38 no.4
• /
• pp.162-169
• /
• 2022

Cobalt-chromium (CoCr)-based alloys have been used for wear applications because of their excellent mechanical properties and wear resistance. With growing concern over environmental problems, CoCr alloys are expected to be used for various tribological applications in degraded lubrication states. To expand the applicability of the materials, data should be accumulated across a broad spectrum of experimental parameters. In this work, the friction and wear characteristics of cobalt-chromium-tungsten (CoCrW) and cobalt-chromium-molybdenum (CoCrMo) alloys are investigated experimentally. The tests are conducted using a pin-on-reciprocating-plate tribotester in dry lubrication. CoCrW and CoCrMo are used as pin and plate materials to investigate the effect of the counter material. The results show that the friction coefficients between CoCrW and CoCrMo generally range from 0.4 to 0.5. The friction coefficient between the CoCrW pin and plate is found to be slightly small. However, the total wear between the CoCrW pin and plate is found to be the largest. In contrast, the total wear between the CoCrW pin and plate is relatively small. Furthermore, CoCrW may cause a faster wear progression of CoCrMo, especially for the case in which CoCrMo is used as the pin material. The results of this work provide a better understanding of the tribological properties of CoCrW and CoCrMo alloys. In addition, this work provides a practical guideline for the use of CoCrW and CoCrMo from the tribological design viewpoint.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.08a
• /
• pp.166-166
• /
• 2012

We examined the distribution of Co ions of ferromagnetic n-type Zn(1-x)Co(x)O semiconducting films with the Co concentrations of 0.03~0.07 using x-ray absorption fine structure (XAFS) measurements at the Co and Zn K edges. Extended XAFS (EXAFS) revealed that Co ions mainly occupied the zinc sites of the films. X-ray absorption near edge structure (XANES) spectra demonstrated that the pre-edge peak of the Co K edge was substantially affected by the second neighboring Co ions at the zinc sites due to hybridizing of the Co 4p conduction electrons with the Co 3d bounded electrons. From XANES and EXAFS analysis using ab initio calculations, we found that Co ions uniformly occupied the zinc sites of the Zn (0.93) Co (0.07)O film, whereas the Co ions of the Zn (0.97) Co (0.03)O and Zn (0.95) Co (0.05)O films were substituted at localized zinc sites. The ferromagnetic properties of the Zn (0.93) Co(0.07)O film could be induced by direct interaction between the magnetic dipoles of the Co ions with a mean distance of 4.3 A or by Co 4p electron mediation.

• Journal of the Korean Chemical Society
• /
• v.34 no.2
• /
• pp.159-164
• /
• 1990

Absolute configuration of optically active [Co(EDDS)]- (EDDS = ethylenediaminedisuccinate) complex was determined as Λ-form by octant rule and spectroscopic data, and the stereoselective ionic association of Λ-[Co(EDDS)]- and racemic-$[Co(en)^3]_{3+}$ occurs preferrentially between Λ$-[Co(EDDS)]-$ and Δ$-[Co(en)3]3+$. The stereoselective electron-transfer reaction between Λ-[Co(EDDS)]- and racemic-$[Co(en)_3]^{2+}$ has produced 14% e.e (e.e = enantiomeric excess) of Δ$[Co(en)_3]^{3+}$ through the stereoselective ion pairing.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2005.05a
• /
• pp.1036-1037
• /
• 2005

• Journal of Energy Engineering
• /
• v.19 no.3
• /
• pp.182-187
• /
• 2010

This study was the effect of inserting CO tube on $NO_x$ and CO emission characteristics in a compact combustion chamber. In detail, $NO_x$ and CO emission characteristics with changing of distance due to inserting CO tube between a burner and a main heat exchanger were investigated. For this study, the commercial program, FLUENT with GRI 2.11 detail reaction mechanism, was used for the numerical study and a commercial heat exchanger was tested for the experimental study. As results, when the CO tube was inserted between a burner and a main heat exchanger, it was verified that $NO_x$ and CO emissions was decreased simultaneously as CO tube was closed to a burner and the distance between CO tube and a main heat exchanger was increased.