• 제목/요약/키워드: chloride Ion diffusion coefficient

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전기화학적 촉진법에 의한 콘크리트의 염화물이온 확산계수 평가에 관한 실험적 연구 (An Experimental Study on Evaluation of Coefficient of Chloride Diffusion by Electrochemical Accelerated Test in Concrete)

  • 조봉석;김갑수;김재환;김용로;권영진;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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    • pp.705-710
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    • 2003
  • In this study, to confirm the diffusion coefficient of chloride ion is affected by the concentration of NaCl solution, capacity of voltage, time of an electric current, the diffusion coefficient of chloride ion in concrete was investigated through an electrochemical accelerated test. and the results of these test were compared with the diffusion coefficient of chloride ion by test of sodium chloride solution digestion. As the results of this study, the diffusion coefficient of chloride ion wasn't affected by the concentration of NaCl solution, capacity of voltage, time of an electric current within the range of this study and was similar to the diffusion coefficient of chloride ion by test of sodium chloride solution digestion.

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철근콘크리트의 부식에 영향을 미치는 물질 투과성능에 관한 실험적 연구 (An experimental study on Influence of Permeability on corrosion of reinforced Concrete)

  • 김용로;김영덕;조봉석;장종호;권영진;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.62-65
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    • 2003
  • In this study, to confirm corrosion of reinforced concrete affected by carbonation, chloride ion diffusion, absorption ratio, air permeability, measured carbonation velocity coefficient, chloride ion diffusion coefficient, absorption coefficient, air permeability coefficient. Corrosion velocity under environment of complex deterioration. And than compared corrosion velocity with these coefficients. As the results of this study, the correlation coefficient between chloride ion diffusion coefficients and absorption coefficient was revealed that it is very high. As well, an increase in carbonation, chloride ion diffusion also increases corrosion velocity. It showed that corrosion velocity was affected by the carbonation, chloride ion diffusion, absorption ratio, air permeability. Generally, data on the development of these coefficient made with none, organic B, organic A, inorganic B, and inorganic A is shown. It showed that coating of surface prevent steel bar from deteriorating.

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Two Dimensional Chloride Ion Diffusion in Reinforced Concrete Structures for Railway

  • Kang, Bo-Soon;Shim, Hyung-Seop
    • International Journal of Railway
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    • 제4권4호
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    • pp.86-92
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    • 2011
  • Chloride ion diffusion at the corner of rectangular-shaped concrete structures is presented. At the corner of rectangular-shaped concrete, chloride ion diffusion is in two-dimensional process. Chloride ions accumulate from two orthogonal directions, so that corrosion-free life of concrete structures is significantly reduced. A numerical procedure based on finite element method is used to solve the two-dimensional diffusion process. Orthotropic property of diffusion coefficient of concrete is considered and chloride ion profile obtained from numerical analysis is used to produce transformed diffusion coefficient. Comparisons of experimental data are also carried out to show the reliability of proposed numerical analysis. As a result of two-dimensional chloride diffusion, corrosion-free life of concrete structure for railway is estimated using probability of corrosion initiation. In addition, monographs that produces transformed diffusion coefficient and corrosion-free life of concrete structure are made for maintenance purpose.

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혼합계시멘트를 사용한 콘크리트의 염화물이온 침투 및 확산특성 (The Penetration and Diffusivity of Chloride ion into Concrete using Blended Cement)

  • 양승규;김동석;엄태선;이종열
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.489-492
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    • 2006
  • A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon and numerous methods have been proposed to determine the diffusion coefficient of chloride ion quickly. In this study, electrically accelerated experiments were carried out in order to evaluate diffusion coefficient of the chloride ion into concrete. The methods were diffusion cell test method in which the voltage of 15V(DC) was applied. The type of cement is blended cement in which the admixtures of blast-furnace slag and fly ash were used. In conclusion, the diffusion coefficient of chloride ion is much affected according to mineral admixtures and the diffusion coefficient of ternary blended cement showed very low values. it is presumably said that this result is due to highly densified pore structures by the aid of slag substitution and pozzolanic activity of fly ash.

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고로슬래그미분말 혼입 콘크리트의 양생재령이 염소이온 확산계수에 미치는 영향에 관한 연구 (A study on the Effect of Curing time on the Chloride ion Diffusion Coefficient in Concrete with Portland Cement and Ground Granulated blast-furnace slag)

  • 이우진;이한승;송수상
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.249-252
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    • 2004
  • Chloride ion diffusion is the most important thing of occuring deterioration in RC structure. According to establish data, the curing time in concrete reduce the chloride ion diffusion coefficient. The purpose of this study is to make clear through experience on the effect of curing time on the chloride ion diffusion coefficient in concrete with Portland cement and ground granulated blast-furnance slag and a propose the standard of chloride ion diffusion coefficient in concrete.

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콘크리트 중의 염화물 확산평가를 위한 전기화학적 촉진시험법 (Electrochemical Acceletated Test for Evaluation of Chloride Diffusion in Concrete)

  • 문한영;김홍삼;이승태;정호섭;최두선
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 가을 학술발표회논문집(I)
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    • pp.409-412
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    • 2000
  • Many researchers have been trying to evaluate the diffusion coefficient of chloride ion in concrete by using qualitative and quantitative electro-migration tests. Up to now, however, there has been no sufficient method to closely determine the diffusion coefficient of chloride ion through electro-migration test. In this paper, the diffusion coefficient of chloride ion in concrete was investigated through an electro-migration test, that is, AASHTO T 277, Dhir's method, Tang's method and Andrade's method. And the results of these test were compared with each other.

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염소이온 확산계수의 확률변수 평가 (Estimation of Probability Valuable for Diffusion Coefficient of Chloride Ion)

  • 배수호;이광명;김지상;정상화
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.515-518
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    • 2005
  • In recent years, many research works have been carried out in order to obtain a more controlled durability and long-term performance of concrete structures exposed to chloride environments. In particular, the development of new procedures for probability-based durability analysis and design has been proved to be very valuable. To carry out the procedures described above, the statistical properties of design valuables such as diffusion coefficient of chloride ion, surface chloride concentration, and chloride threshold value etc. should be known. For this purpose, this paper presents the statistical properties of the diffusion coefficient of chloride ion such as mean value and standard deviation with water-cement(w/c) ratio and curing conditions, respectively. It was observed from the test that the standard deviation for the diffusion coefficient of chloride ion was found to be small with decrease in the w/c ratio irrespective of curing conditions and that of standard curing was found to be smaller than that of field curing.

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고로슬래그미분말 혼합 콘크리트의 염소이온 확산특성 (Characteristic of Chloride Ion Diffusion in Concrete Containing GGBF)

  • 문한영;김홍삼;김진철;최두선
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.793-796
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    • 2001
  • Physical properties of concrete, Such as, compressive strength, permeable pore and penetration depth of chloride ion were investigated. And to investigate the effect of containing GGBF in concrete, the diffusion coefficient of chloride was measured through an electro- migration test. The diffusion coefficient of chloride was decreased with increase of replacement ratios of GGBF when compared to OPC. Relation coefficients between physical properties of concrete and diffusion coefficient of chloride were more than 0.9.

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콘크리트의 염소이온 확산특성에 미치는 시멘트 종류의 영향 (Influence of Cement Type on the Diffusion Characteristics of Chloride Ion in Concrete)

  • 박재임;배수호;이광명;김지상;차수원
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.573-576
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-binder(W/B) ratio, age, cement type and constituents, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of cement type on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. For this purpose, the diffusion characteristics in concrete with cement type such as ordinary portland cement(OPC), binary blended cement(BBC), and ternary blended cement(TBC) were estimated for the concrete with W/B ratios of 32% and 38%, respectively. It was observed from the test that the difussion characteristics of BBC containing OPC and ground granulated blast-furnace slag was found to be most excellent of the cement type used in this study.

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Modeling of ion diffusion coefficient in saturated concrete

  • Zuo, Xiao-Bao;Sun, Wei;Yu, Cheng;Wan, Xu-Rong
    • Computers and Concrete
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    • 제7권5호
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    • pp.421-435
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    • 2010
  • This paper utilizes the modified Davis model and the mode coupling theory, as parts of the electrolyte solution theory, to investigate the diffusivity of the ion in concrete. Firstly, a computational model of the ion diffusion coefficient, which is associated with ion species, pore solution concentration, concrete mix parameters including water-cement ratio and cement volume fraction, and microstructure parameters such as the porosity and tortuosity, is proposed in the saturated concrete. Secondly, the experiments, on which the chloride diffusion coefficient is measured by the rapid chloride penetration test, have been carried out to investigate the validity of the proposed model. The results indicate that the chloride diffusion coefficient obtained by the proposed model is in agreement with the experimental result. Finally, numerical simulation has been completed to investigate the effects of the porosity, tortuosity, water-cement ratio, cement volume fraction and ion concentration in the pore solution on the ion diffusion coefficients. The results show that the ion diffusion coefficient in concrete increases with the porosity, water-cement ratio and cement volume fraction, while we see a decrease with the increasing of tortuosity. Meanwhile, the ion concentration produces more obvious effects on the diffusivity itself, but has almost no effects on the other ions.