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Recent Research Trends of Supercapacitors for Energy Storage Systems (에너지 저장시스템을 위한 슈퍼커패시터 최신 연구 동향)

  • Son, MyungSuk;Ryu, JunHyung
    • Clean Technology
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    • v.27 no.4
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    • pp.277-290
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    • 2021
  • A supercapacitor, also called an ultracapacitor or an electrochemical capacitor, stores electrochemical energy by the adsorption/desorption of electrolytic ions or a fast and reversible redox reaction at the electrode surface, which is distinct from the chemical reaction of a battery. A supercapacitor features high specific power, high capacitance, almost infinite cyclability (~ 100,000 cycle), short charging time, good stability, low maintenance cost, and fast frequency response. Supercapacitors have been used in electronic devices to meet the requirements of rapid charging/discharging, such as for memory back-up, and uninterruptible power supply (UPS). Also, their use is being extended to transportation and large industry applications that require high power/energy density, such as for electric vehicles and power quality systems of smart grids. In power generation using intermittent power sources such as solar and wind, a supercapacitor is configured in the energy storage system together with a battery to compensate for the relatively slow charging/discharging time of the battery, to contribute to extending the lifecycle of the battery, and to improve the system power quality. This article provides a concise overview of the principles, mechanisms, and classification of energy storage of supercapacitors in accordance with the electrode materials. Also, it provides a review of the status of recent research and patent, product, and market trends in supercapacitor technology. There are many challenges to be solved to meet industrial demands such as for high voltage module technologies, high efficiency charging, safety, performance improvement, and competitive prices.

Analysis the Use of Concrete Fine Aggregates of Coal Gasification Slag (콘크리트용 잔골재로서 석탄가스화 용융슬래그(CGS)의 활용성 분석)

  • Park, Kyung-Taek;Han, Min-Cheol;Hyun, Seung-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.101-108
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    • 2019
  • This study is analysis of the utilization as a concrete fine aggregate on CGS, a by-product of Integrated coal gasification combined cycle(IGCC). That is, in KS F 2527 "Concrete aggregate," properties of 1~12times to CGS were evaluated, focusing on quality items corresponding to natural aggregate sand(NS) and melted slag aggregate sand(MS). As a result, the distribution of grain shape, safety and expansion were all satisfied with KS standards by physical properties, but the quality was unstable at 7~12times of water absorption ratio and absolute dry density. The particle size distribution was unstable due to asymmetry distribution of coarse particles, and particles were too thick for 7~12times. The passing ratio of 0.08mm sieve was also out of the KS standard at part factor of 7~12times, but chloride content, clay contents, coal and lignite were all satisfactory. Meanwhile, chemical composition was satisfactory except for $SO_3$ in 1~6times, and content and amount of harmful substances were all within the specified value except for F in 7~12times. As a result of SEM analysis, the surface quality and porosity were 7~12times more than 1~6times, and it was the quality was degraded. Therefore, it is necessary to reduce the quality deviation by using separate measures in order to utilize it as concrete aggregate in the future, and if it is premixed with fine quality aggregate, it will contribute positively to solve aggregate supply shortage and utilize circulation resources.

Development and Evaluation of Artificial Lightweight Soil Using Bottom Ash (바텀애시를 활용한 인공경량토양의 개발 및 성능 평가)

  • Kim, Chul-Min;Kim, Min-Woo;Cho, Gun-Young;Choi, Na-Rae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.252-258
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    • 2018
  • A larger energy consumption and concentration of population induced green house gas glowing and heat island effect in the urban space. Roof green system was a effect method to reduce green house gas and heat concentration in the city. Therefore, construction of this system was increasing. Most of lightweight soil used in roof green system was perlite, but this caused dust and skin disease. So it needed to develop another new lightweight soli for roof green system. Meanwhile, a thermoelectric power plant generated bottom ash as a by-product. According to previous research, bottom ash could be used for artificial lightweight soil with 60 wt% of mixing rate. But this study was proceed to develop a artificial lightweight soil using bottom ash with higher mixing rate by 65 wt% and different organic ingredients. First, physical and chemical properties of bottom ash was investigated. Then test according to landscaping design standard was proceeded for various artificial lightweight soil mix types using bottom ash, bark, compost and coco peat. As a result, the artificial lightweight soil with 65% of bottom ash, 30% of bark and 5% of compost was suitable for low and middle range of soil standard.

A Study on the Risk of Spontaneous ignition to Butadiene Popcorn Polymer (Butadiene Popcorn Polymer의 자연발화 위험성에 관한 연구)

  • Koo, Chae-Chil;Lee, Jung-Suk;Choi, Jae-Wook
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.1-8
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    • 2019
  • This study was conducted to investigate the possibility of spontaneous ignition in Butadiene popcorn polymer, which is used as raw material and product in a chemical plant. A component analysis, thermogravimetric analysis, thermal stability analysis, spontaneous ignition point measurement and accelerated velocity calorimetric analysis were performed. As a result of analysis, various kinds of flammable components were measured and thermogravimetric analysis showed a weight loss of 95.6% in air and 89.2% in nitrogen. As a result of the thermal stability analysis, heat generation started at $88^{\circ}C$ in the air atmosphere, and the heat generation rate increased sharply in the vicinity of the natural ignition point ($220^{\circ}C$). The heat generation started at about $70^{\circ}C$ in nitrogen atmosphere, and the two exothermic peak values were observed up to $450^{\circ}C$. As a result of accelerated rate calorimetry, there was no exothermic phenomenon, and the lowest ignition temperature was $211.7^{\circ}C$ as a result of analysis of natural ignition point. Based on the results obtained from the thermal stability evaluation, it is considered that the possibility of inducing the thermal deformation of the column by the heat of reaction is sufficient.

Comparative Analysis of the Flavor Compounds in Cultivated Chrysanthemum indicum L. (국내 육성 감국의 품종별 향기성분 비교 분석)

  • Oh, Kyeong Yeol;Goo, Young Min;Jeong, Won Min;Sin, Seung Mi;Kil, Young Sook;Ko, Keon Hee;Yang, Ki Jeung;Kim, Jin-Hyo;Lee, Dong Yeol
    • Journal of Life Science
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    • v.28 no.12
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    • pp.1523-1528
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    • 2018
  • This study investigated the chemical composition of four Korean cultivated Chrysanthemum indicum L. (Gamguk 1 ho, Gamguk 2 ho, Gamguk 3 ho, and Wonhyang) which are used in the food and fragrance industries to identify their volatile flavor compounds. These compounds were analyzed using headspace GC-MS from plant samples cultivated in the same region of Korea (Sancheong-gun, Gyeongsangnam-do). A total of 23 compounds were identified, eight of which were common across the four cultivars. The major flavor components in the three Gamguk plants were identified as 3-carene, camphene, ${\beta}$-phellandrene, eucalyptol and (+)-camphor. Eleven compounds, including (+)-camphor at 31.40%, were identified in Gamguk 1 ho. Gamguk 2 ho was found to contain 12 flavor compounds, predominant of which was camphene at 25.60%. Thirteen compounds including (+)-camphor (26.88%) were identified in Gamguk 3 ho, while 17 were detected in the Wonhyang cultivar, including trans-piperitol (47.33%), sabinene, and ${\gamma}$-terpinyl acetate. These results indicate differences in the type and ratio of functional volatile flavor ingredients in Chrysanthemum indicum L. cultivars which is highly valuable as material for fragrance product development.

Estimation of Structural Safety for PolyEthylene (PE) Floating Platforms with API & AISC Standards (API & AISC 기준을 적용한 PolyEthylene (PE) 부유식 플랫폼의 구조 안전성 검토)

  • Seo, Kwang-Cheol;Nam, Taek-Kun;Park, Joo-Shin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.2
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    • pp.237-243
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    • 2019
  • Floating platforms made of PE (PolyEthylene) are often located in shallows of seas, rivers or lakes. They are widely used for marine pensions, marine pontoons, marine bridges, etc. These products are characterized by good flexibility, recyclability, chemical resistance and weatherability with corrosion resistance. Existing PE floating platforms have a simple structure in which one pipe is fastened to one bracket, but this has limited application, even if a user modifies the arrangement. Therefore, we developed a structure that allows buoyancy pipes of various sizes to be fastened to one bracket and verified the structural safety of the product using the finite element method. From the results of structural analysis for buoyancy pipes of different diameters, the maximum stress ratio was 0.78 compared with allowable criteria of 1.0, which represented sufficient safety for a model with 500 mm diameter pipes. Based on the results of this study, further research to evaluate the structural safety of various floating platforms can be carried out in the further; it will also be necessary to establish related evaluation criteria.

Component and Phase Analysis of Calcium Silicate Cement Clinker by Raw Materials Mix Design (원료 배합에 따른 칼슘 실리케이트 시멘트 클링커의 성분 및 상 분석)

  • Lee, Hyang-Sun;Song, Hun
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.3
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    • pp.251-258
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    • 2022
  • In the cement industry, in order to reduce CO2 emissions, technology for raw materials substitution and conversion, technology for improving process efficiency of utilizing low-carbon new heat sources, and technology for collecting and recycling process-generated CO2 are being developed. In this study, we conducted a basic experiment to contribute to the development of CSC that can store CO2 as carbonate minerals among process-generated CO2 capture and recycling technologies. Three types of CSC clinker with different SiO2/(CaO+SiO2) molar ratios were prepared with the clinker raw material formulation, and the characteristics of the clinker were analyzed. As a result of analysis and observation of CSC clinker, wollastonite and rankinite were formed. In addition, as a result of the carbonation test of the CSC paste, it was confirmed that calcite was produced as a carbonation product. The lower the SiO2/(CaO+SiO2) molar ratio in the CSC clinker chemical composition, the lower the wollastonite production amount, and the higher the rankinite production amount. And the amount of calcite production increased with the progress of carbonation of the CSC paste specimen. It is judged that rankinite is more reactive in mineralizing CO2 than wollastonite.

Characteristics of Fluoride-based Anti-stain Chemicals Made from Industrial By-product (II) -Fungicidal Effectiveness against Isolated Fungi Through Laboratory Evaluation and Field Evaluation- (산업 부산물을 이용하여 제조한 플루오르화합물계 목재 방미제의 특성 (II) - 분리 균주에 대한 목재 방미효력 및 야외 효력 평가 -)

  • Lee, Jong-Shin
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.2
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    • pp.82-89
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    • 2004
  • Two kinds of chemicals (RNF-3 and RNF-4) with high anti-mold effectiveness against stored fungi causing fungal discoloration was selected from among the six kinds of fluoride-based chemicals in the preceding study. In this study, the anti-mold test using 16 species fungi isolated from the softwood lumbers which were fungal discolored and field test in the sawmill was carried out to prove the feasibility for practical using of selected chemicals.For the isolated fungi, the RNF-3 consist of F and Cu showed high mycelial growth control in the PDA medium and fungicidal effectiveness in the japanese red pine (Pinus densiflora), korean pine (Pinus koraiensis) and radiata pine (Pinus radiata) when the concentration was 2% or more. However the RNF-4 consist of F only was not effective compared with RNF-3 because of mycelial growth in the PDA medium and wood treated with 2% or more chemical solution. The RNF-3 also showed a strong anti-mold effectiveness because there was no fungal discoloration for the radiata pine boards treated by 2% and 10 min. soaking in the field test. These results mean that RNF-3 can be used as domestic anti-stain chemicals for prevention of fungal discoloration of the softwood lumber

Tuning of the Interparticle interactions in ultrafine ferrihydrite nanoparticles

  • Knyazev, Yuriy V.;Balaev, Dmitry A.;Yaroslavtsev, Roman N.;Krasikov, Aleksandr A.;Velikanov, Dmitry A.;Mikhlin, Yuriy L.;Volochaev, Mikhail N.;Bayukov, Oleg A.;Stolyar, Sergei V.;Iskhakov, Rauf S.
    • Advances in nano research
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    • v.12 no.6
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    • pp.605-616
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    • 2022
  • We prepared two samples of ultrafine ferrihydrite (FH) nanoparticle ensembles of quite a different origin. First is the biosynthesized sample (as a product of the vital activity of bacteria Klebsiella oxytoca (hereinafter marked as FH-bact) with a natural organic coating and negligible magnetic interparticle interactions. And the second one is the chemically synthesized ferrihydrite (hereinafter FH-chem) without any coating and high level of the interparticle interactions. The interparticle magnetic interactions have been tuned by modifying the nanoparticle surface in both samples. The coating of the FH-bact sample has been partially removed by annealing at 150℃ for 24 h (hereinafter FH-annealed). The FH-chem sample, vice versa, has been coated (1.0 g) with biocompatible polysaccharide (arabinogalactan) in an ultrasonic bath for 10 min (hereinafter FH-coated). The changes in the surface properties of nanoparticles have been controlled by XPS. According to the electron microscopy data, the modification of the nanoparticle surface does not drastically change the particle shape and size. A change in the average nanoparticle size in sample FH-annealed to 3.3 nm relative to the value in the other samples (2.6 nm) has only been observed. The estimated particle coating thickness is about 0.2-0.3 nm for samples FH-bact and FH-coated and 0.1 nm for sample FH-annealed. Mössbauer and magnetization measurements are definitely shown that the drastic change in the blocking temperature is caused by the interparticle interactions. The experimental temperature dependences of the hyperfine field hf>(T) for samples FH-bact and FH-coated have not revealed the effect of interparticle interactions. Otherwise, the interparticle interaction energy Eint estimated from the hf>(T) for samples FH-chem and FH-annealed has been found to be 121kB and 259kB, respectively.

Sensitivity analysis on the length of credit period for an inventory model with stock dependent consumption rate (재고 종속형 수요를 고려한 재고모형의 신용 거래 기간에 따른 민감도 분석)

  • Shinn, Seong-Whan
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.6
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    • pp.655-660
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    • 2022
  • This paper analyzes the problem of the economic order quantity (lot size) of a retailer in a two-stage supply chain consisting of a supplier, a retailer(distributor), and a customer. In this two-stage supply chain, the supplier permits the retailer to defer payment for a certain fixed period of time for the purchase cost to be paid by the retailer as a price differentiation strategy with his competitor. In addition, in the case of customer goods such as food and grain, it is common to see that end-customer demand is generally depend on the level of inventory displayed by the retailer. From this perspective, this paper analyzes the inventory problem of retailers under the assumption that the supplier may allow a certain period to suspend payments for the purchase of goods and the end customer demand is a function of the retailer's inventory level increasing with size. In this regard, we need to analyze how much the length of the grace period for product purchase costs affect the retailer's lot-sizing policy. Therefore, we formulate the retailer's annual net profit and analyze the effect of the length of credit period on the retailer's inventory policy numerically.