• International Journal of Safety
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• v.6 no.1
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• pp.16-21
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• 2007

Carbon nanotubes hold much promise as future materials for safe storage of hydrogen. In this paper, hydrogen transport mechanisms in single-walled carbon nano-tubes (SWNTs) for various temperatures and chiral indices were studied using molecular dynamics simulation method. The SWNT models of zigzag (10,0), chiral (10,5) and armchair (10,10) with hydrogen molecules inside were simulated at temperatures ranging from 253K to 373K. Movements of hydrogen molecules ($H_2$) inside a SWNT were analyzed using mean-square displacements and velocity autocorrelation functions.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.226-230
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• 2005

This paper presents the actuation performance of a conducting shape memory polyurethane (CSMPU) actuator. We introduced a concept of shape memory polyurethane activated by electric power while conventional shape memory polyurethanes are activated by external heat source. A conducting shape memory polyurethane actuator was manufactured by adding cabon nano-tube to conventional shape memory polyurethane. The main problem of the previous CSMPU was bad dispersion of carbon nano-tubes in polyurethane. In this paper, we have tried to find manufacturing method to solve the dispersion problem. With a lot of elaborative works, we have developed conducting shape memory polyurethane actuator with good electrical performance. The actuation performance of the developed conducting shape memory polyurethane actuator was measured and assessed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.10
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• pp.1090-1094
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• 2004

Studies on porous oxide electrode, dye and electrolyte for dye-sensitized solar cells have been intensively carried out until now. However, counter electrode have not been much studied so far. Accordingly, it is needed to investigate new counter electrode materials with superior catalyst property and to substitute for Pt electrode. In this case, carbon nano-tubes (CNTs) are one of alternatives for counter electrodes as following merits: low resistivity, excellent electron emission property, large surface area and low cost due to development of mass production technique. Such advantages gave us to select multiwalled CNTs (MWCNT) as counter electrode for dye-sensitized solar cell. Also, cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of both CNT electrode and Pt electrode. It was found that sheet resistance of CNT electrode was similar to that of Pt electrode, also, electrochemical properties of CNT electrode was superior to that of Pt electrode on the basis on the measurement of CV and impedance spectrum. It was found that CNT is likely to be a very promising electrode material for dye solar cells.

• Korean Journal of Materials Research
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• v.23 no.12
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• pp.737-744
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• 2013

We demonstrated size control of Au nanoparticles by heat treatment and their use as a catalyst for single-walled carbon nanotube (SWNTs) growth with narrow size distribution. We used uniformly sized Au nanoparticles from commercial Au colloid, and intentionally decreased their size through heat treatment at 800 oC under atmospheric Ar ambient. ST-cut quartz wafers were used as growth substrates to achieve parallel alignment of the SWNTs and to investigate the size relationship between Au nanoparticles and SWNTs. After the SWNTs were grown via chemical vapor deposition using methane gas, it was found that a high degree of horizontal alignment can be obtained when the particle density is low enough to produce individual SWNTs. The diameter of the Au nanoparticles gradually decreased from 3.8 to 2.9 nm, and the mean diameter of the SWNTs also changed from 1.6 to 1.2 nm for without and 60 min heat treatment, respectively. Raman results reconfirmed that the prolonged heat treatment of nanoparticles yields thinner tubes with narrower size distribution. This work demonstrated that heat treatment can be a straightforward and reliable method to control the size of catalytic nanoparticles and SWNT diameter.

• Advances in nano research
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• v.14 no.6
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• pp.521-525
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• 2023

This paper concerned with the vibration of double walled carbon nanotubes (CNTs) as continuum model based on Timoshenko-beam theory. The vibration solution obtained from Timoshenko-beam theory provides a better presentation of vibration structure of carbon nanotubes. The natural frequencies of double-walled CNTs against half axial wave mode are investigated. The frequency decreases on decreasing the half axial wave mode. The shape of frequency arcs is different for various lengths. It is observed that model has produced lowest results for C-F and highest for C-C. A large parametric study is performed to see the effect of half axial wave mode on frequencies of CNTs. This numerically vibration solution delivers a benchmark results for other techniques. The comparison of present model is exhibited with previous studies and good agreement is found.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.20 no.9
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• pp.104-109
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• 2021

Tactile sensors and integrated circuits that detect external stimuli have been developed for use in various industries. Most tactile sensors have been developed using the MEMS(micro electro-mechanical systems) process in which metal electrodes and strain sensors are applied to a silicon substrate. However, tactile sensors made of highly brittle silicon lack flexibility and are prone to damage by external forces. Flexible tactile sensors based on polydimethylsiloxane and using a multi-walled carbon nano-tube mixture as a pressure-sensitive material are currently being developed as an alternative to overcome these limitations. In this study, a manufacturing process of pressure-sensitive materials with low initial electrical resistance is developed and applied to the fabrication of flexible tactile sensors. In addition, flexible tactile sensors are developed with pressure-sensitive materials dispensed on a substrate with flexible mechanical properties. Finally, a study is conducted on the change in electrical resistance of pressure-sensitive materials according to the modulus of elasticity of the substrate.

• Composites Research
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• v.29 no.6
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• pp.353-357
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• 2016

An appropriate way to fabricate a hybrid composite containing evenly dispersed carbon nano tubes(CNTs) is to stacking B-stage resin films that contain evenly dispersed CNTs and various reinforcing fiber layers alternatively. In the present study, B-stage resin films are manufactured via shear mixing and three-roll milling. CNT dispersion in resin via these two processes are evaluated by SEM on their fracture surfaces. For more efficient process, the dispersivities are evaluated according to the number of calendering passes. Samples are made for different number of passes during calendering, and their dispersions are evaluated via SEM fractographs as well as by measuring their electrical conductivities. Additionally, the optimal process conditions are obtained by measuring the electrical conductivity and evaluating their dispersivity of the samples prepared by gap mode and force mode.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.34 no.1
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• pp.56-64
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• 2006

This paper presents the development and application of a conducting shape memory polyurethane (CSMPU) actuator. While conventional shape memory polyurethanes were activated by external heat source, conducting shape memory polyurethanes introduced in 2004 are activated by electric power. Conducting shape memory polyurethane actuators were manufactured by adding carbon nano tube to conventional shape memory polyurethane. The main problem of the CSMPU developed in 2004 was bad dispersion of carbon nano tubes. In this paper, we tried to find how to solve the dispersion problem, and with a lot of elaborative works, conducting shape memory polyurethane actuators which had better electrical characteristics were developed. Then the actuation performance of the conducting shape memory polyurethane actuators was also measured and assessed. Finally, the possibility of applications were examined through the installation to Micro Air Vehicle.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.195-196
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• 2021

The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.

• Structural Engineering and Mechanics
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• v.88 no.2
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• pp.109-115
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• 2023

In this paper, frequencies of zigzag structure of carbon nanotubes isinvestigated based on Donnell shell theory. These tubes are wrapped with the ring supports in the axial direction. The fundamental frequency curves displayed in article show the dependence of vibrations attributes to zigzag single walled carbon nanotubes. Various zigzag indices are introduced against the variation of length to predict the vibration. Also, the influence of ring supports is sketched with proposed structure for frequency analysis. The frequencies of zigzag tube decreases as the length increases. It is observed that the frequencies decreases with ring support and have higher frequencies without ring. The problem is formulated using Partial Differential Equation. Three expressions of modal deformation displacement functions is used for the elimination of temporal variation to form the solution in the eigen from. For the stability of present study the results are compared with experimentally and numerically in the open text.