• 한국전기전자재료학회논문지
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• 제22권5호
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• pp.390-396
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• 2009

The present research was focused to investigate the quality of non-polar SiC substrates grown by a conventional PVT method for optoelectronic applications. The half part of the PVT-grown 6H-SiC crystal boules was sliced along a-direction and m-direction to extensively analyze non-polar planes and then remaining part of that was sliced along the basal plane to produce wafers. The non-polar SiC m-plane and a-plane exhibited apparent peaks around 2 theta=$120^{\circ}$((3-300) plane) and 2 theta=$60^{\circ}$ ((11-20) plane), respectively. FWHM values of m-plane measured along a-direction and c-direction were 60 arc see and 57 arcsec respectively, a-plane measured along m-direction and c-direction were 41 arcsec and 51 arcsec respectively. The typical absorption spectra of SiC crystals indicated that each of SiC crystals were the 6H-SiC with fundamental absorption energy of about 3.04 eV. Non-polar planes contained no micropipe on etched surface. The carrier concentration and mobility of non-polar SiC wafers have estimated by Raman spectrum. It was observed that the carrier mobility is low in the area far from seed crystal with compared to other places.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.3021-3024
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• 2009

$Zn_2Ti_{1-x}Fe_xO_4\;(0\;{\leq}\;x\;{\leq}\;0.7)$ photocatalysts were synthesized by polymerized complex (PC) method and investigated for its physico-chemical as well as optical properties. $Zn_2Ti_{1-x}Fe_xO_4$ can absorb not only UV light but also visible light region due to doping of Fe in the Ti site of $Zn_2TiO_4$ lattice because of the band transition from Fe 3d to the Fe 3d + Ti3d hybrid orbital. The photocatalytic activity of Fe doped $Zn_2TiO_4$ samples for hydrogen production under UV light irradiation decreased with an increase in Fe concentration in $Zn_2TiO_4$. Consequently, there exists an optimized concentration of iron for improved photocatalytic activity under visible light (${\lambda}{\leq}$420 nm)

• 한국표면공학회지
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• 제36권1호
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• pp.27-33
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• 2003

Pulsed magnetron sputtering of graphite target was employed for deposition of diamond-like carbon (DLC) films. Time-resolved probe measurements of magnetron discharge plasma have been performed. It was shown that the pulsed magnetron discharge plasma density ($∼10^{17}$ $m^{-3}$ ) is close to that of vacuum arc cathode sputtering of graphite. Raman spectroscopy was sed to examine DLC films produced at low ( $U_{sub}$ / < 1 kV) pulsed bias voltages applied to the substrate. It has been shown that maximum content of diamond-like carbon in the coating (50-60%) is achieved at energy per deposited carbon atom of $E_{c}$ =100 eV. In spite of rather high percentage of $sp^3$-bonded carbon atoms and good scratch-resistance, the films showed poor adhesion because of absence of ion mixing between the film and the substrates. Electric breakdowns occurring during the deposition of the insulating DLC film also thought to decrease its adhesion.

• 한국표면공학회지
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• 제50권5호
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• pp.339-344
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• 2017

Highly corrosion resistance performance of CrAlSiN coatings were obtained by applying ultrathin $Al_2O_3$ thin films using atomic layer deposition (ALD) method. CrAlSiN coatings were prepared on Cr adhesion layer/SUS304 substrates by a hybrid coating system of arc ion plating and high power impulse magnetron sputtering (HiPIMS) method. And, ultrathin $Al_2O_3$ passivation layer was deposited on the CrAlSiN/Cr adhesion layer/SUS304 sample to protect CrAlSiN coatings by encapsulating the whole surface defects of coating using ALD. Here, the high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and energy dispersive X-ray spectrometry (EDX) analysis revealed that the ALD $Al_2O_3$ thin films uniformly covered the inner and outer surface of CrAlSiN coatings. Also, the potentiodynamic and potentiostatic polarization test revealed that the corrosion protection properties of CrAlSiN coatings/Cr/SUS304 sample was greatly improved by ALD encapsulation with 50 nm-thick $Al_2O_3$ thin films, which implies that ALD-$Al_2O_3$ passivation layer can be used as an effect barrier layer of corrosion.

• 자원리싸이클링
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• 제9권4호
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• pp.3-15
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• 2000

전기로 더스트 중에 함유된 Zn, Pb, Cl, Fe, Cu 및 Cd의 건식 환원반응기구를 규몽하고자 탄소뿔 첨가한 더스트 Briquette를 제조하여 Ar 가스 분위기 하의 $800^{\circ}C$ ~ $1100^{\circ}C$반응온도에서 실험을 행하였다. 탄소에 의한 Zn 화합물으 환원반응은 온도상승에 따라 민감하게 나타났으며 반응초기에는 화학반응에 의한 음속단계로 활성화에너지 값은 약 120.6 kl/mole이었다. 한편, Pb와 Cl은 $PbCl_2$의 형태로 휘발되었으며 이들의 휘발제거율은 거의 일치하였다. 또한, 환원제를 첨가하지 않는 경우가 환원제 첨가시 보다 휘발제거율이 빨라 Pb의 대부분은 염화휘발에 의해 제거됨을 알 수 있었다. Cu는 염화휘발에 의해 최대 약 30% 제거되고 나머지 대부분은 Fe와 함께 더스트 중에 잔존하여 Cd은 $1000^{\circ}C$에서 15분만에 거의 100%의 휘발제거율을 나타내었다.

• 한국강구조학회 논문집
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• 제23권4호
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• pp.483-491
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• 2011

본 연구에서는 구조용강재의 샤르피 충격시험(Charpy Impact Test)을 통해 저온에서의 충격 인성(Impact Toughness) 평가를 실시하여 사용 가능 온도를 파악함으로써 강재의 극한지 적용성을 검토하였다. 본 시험에 사용된 강재는 용접구조용강 중 현재 가장 널리 쓰이는 강종인 SM490B와 TMCP (Thermo-Mechanical Control Process)법에 의해 제조된 고강도 강재인 SM570-TMC이다. 또한, 본 시험결과와의 비교를 위해 남극 세종기지 건설시 사용실적이 있는 일반구조용강인 SS400에 대해서도 시험을 수행하였다. 대부분의 강구조물은 용접에 의해 제작되므로, 강재의 극한지 적용성 검토를 위해 용접시험판을 제작하여 모재(Base Metal), 용접금속(Weld Metal) 및 열양향부(Heat Affected Zone)에 대해서 충격시험을 실시하였다. 단, SS400의 경우에는 용접구조용강재가 아니므로 모재에 대해서 충격시험을 실시하였다. 대상 강재의 샤르피 충격시험을 통해서 저온에서의 충격흡수에너지 값을 구하고 이를 강재의 항복응력에 따른 충격흡수에너지의 기준값과 비교함으로써 강재의 사용온도를 결정하였으며, 이를 통해서 구조용강재의 극한지 적용성을 검토하였다.

• Radiation Oncology Journal
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• 제9권2호
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• pp.343-350
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• 1991

종양모양에 거의 일치하는 선량분포를 얻기위해 다층부정형필터를 이용하는 방법을 보였으며, 필터의 재질은 Lipowitz (일명 cerrobend alloy) 금속체를 이용하였다. 선속내 필터의 놓임은 일차선의 감쇄와 함께 조직내 산란선 기여율의 변화가 예상되므로 필터의 두께에 따른 SMR의 변화가 계산에 이용되어야 된다. 이에 본 연구의 계산선량은 실측치의 $3\%$이내에서 잘 일치됨을 알 수 있었다. 다층부정형필터를 이용한 펜톰의 원호조사의 선량평 가는 동일 필터에 의한 고정조사의 선량분포가 적용되었으며, 가상종양에 거의 일치하는 선량분포를 얻을수 있었다. 한편, 컴퓨터모의계산된 선량과 열발광산량계(teflon-embedded TLD)의 실측선량은 비교적${\pm}5\%$ 범위내에서 잘 일치됨을 알 수 있었으며, 이 치료방법은 현재 차폐체로 많이 이용되고 있는 Lipowitz 금속체를 사용함으로써 보다 쉽게 응용되어질 것으로 생각된다.

• International Journal of Ocean System Engineering
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• 제2권2호
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• pp.106-115
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• 2012

In the present study, TiN and CrN films were coated by arc ion plating equipment onto aluminum alloy substrate, A2024. The film thickness was about 4.65 ${\mu}m$. TiN and CrN films were analyzed by X-ray diffraction and energy dispersive X-ray equipments. The Young's modulus and the micro-Vickers hardness of aluminum substrate were modified by the ceramic film coatings. The difference in Young's modulus between substrate and coating film would affect on the wear resistance. The critical load, Lc, was 75.8 N for TiN and 85.5 N for CrN. It indicated from the observation of optical micrographs for TiN and CrN films that lots of cracks widely propagated toward the both sides of scratch track in the early stage of MODE I. TiN film began to delaminate completely at MODE II stage. The substrate was finally glittered at MODE III stage. For CrN film, a few crack can be observed at MODE I stage. The delamination of film was not still occurred at MODE II and then was happened at MODE III. This agrees with critical load measurement which the adhesive strength was greater for CrN film than for TiN film. Consequently, it was difficult for CrN to delaminate because the adhesive strength was excellent against Al substrate. The wear process, which the film adheres and the ball transfers, could be enhanced because of the increase in loading. The wear weight of ball was less for CrN than for TiN. This means that the wear damage of ball was greater for TiN than for CrN film. It is also obvious that it was difficult to delaminate because the CrN coating film has high toughness. The coefficient of friction was less for CrN coating film than for TiN film.

• 한국재료학회지
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• 제29권2호
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• pp.97-105
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• 2019

In the current steel structures of high-rise buildings, high heat input welding techniques are used to improve productivity in the construction industry. Under the high heat input welding, however, the microstructures of the weld metal (WM) and heat-affected zone (HAZ) coarsen, resulting in the deterioration of impact toughness. This study focuses mainly on the effects of fine TiN precipitates dispersed in steel plates and B addition in welding materials on grain refinement of the HAZ microstructure under submerged arc welding (SAW) with a high heat input of 200 kJ/cm. The study reveals that, different from that in conventional steel, the ${\gamma}$ grain coarsening is notably retarded in the coarse grain HAZ (CGHAZ) of a newly developed steel with TiN precipitates below 70 nm in size even under the high heat input welding, and the refinement of HAZ microstructure is confirmed to have improved impact toughness. Furthermore, energy dispersive spectroscopy (EDS) and secondary-ion mass spectrometry (SIMS) analyses demonstrate that B is was identified at the interface of TiN in CGHAZ. It is likely that B atoms in the WM are diffused to CGHAZ and are segregated at the outer part of undissolved TiN, which contributes partly to a further grain refinement, and consequently, improved mechanical properties are achieved.

• 대한건축학회논문집:계획계
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• 제36권2호
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• pp.79-86
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• 2020

In order to accommodate the increase in urban population due to government-led national planning and economic growth, many buildings such as houses and business building were supplied. Although the building law was revised and managed to manage the supplied buildings, for the sake of economic benefit, there have been buildings that are enlarged or reconstructed without declaring building permits. In order to manage these buildings, on-site surveys were conducted. but it has many personnel consumption. To solve this problem, a method of using a satellite image and a manned aircraft is utilized, but it is diseconomical and a renewal cycle is long. In addition, it is not utilized to the height, and although it is judged by the shading of the building, it has limitations that it must be calculated individually. In this study, height of the building was calculated by using the unmanned aerial vehicle with low personnel consumption, and the accuracy was verified by comparison with the building register and measured value. In this study, spatial information was constructed using a fast unmanned aerial vehicle with low manpower consumption and the building height was calculated based on this. The accuracy by comparing the calculated building height with the building register and the actual measurement.