• Title/Summary/Keyword: acid strength

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Engineering Properties of Steel Fiber Reinforced High Performance Concrete

  • Kim Young Ik;Sung Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.46 no.7
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    • pp.55-67
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    • 2004
  • In this paper, the flowability, strengths, impact resistance and sulfuric acid resistance of steel fiber reinforced high performance concrete (SFHPC) for the steel fiber content and fly ash and blast furnace slag as admixtures were presented. For evaluating flowability particularly, tests of slump flow, box-type passing ability and L-type filling ability were performed. The slump flow of SFHPC was some decreased with increase of the steel fiber content. At the box-type passing ability, the difference of box height of SFHPC is greatly increased with increasing the fiber content. The L-type filling ability of SFHPC was not excellent above $0.75\% of the steel fiber content. Also, the compressive strength of SFHPC was decreased with increase of the steel fiber content, but the flexural strength of SFHPC was much higher than that of the concrete without the steel fiber. At the impact resistance, drop number of SFHPC for reaching final fracture was increased with increase of the fiber content. Also, the drop number for reaching initial fracture of lmm was increased with increase of the fiber content. At the sulfuric acid resistance, 4-week weight change of SFHPC with the steel fiber was almost similarity that of HPC without the steel fiber and was in the range of 73.6 to 81.5.

Evaluation of cement mortars blended with copper alloy slag (구리 합금 슬래그를 혼합한 시멘트 모르타르의 특성)

  • Lee, Jung-Il;Hong, Chang Woo;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.1
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    • pp.39-43
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    • 2015
  • The cement mixtures such as flyash, iron-slag and silica fume have been actively studied in order to increase the quality of concrete. In this study, the grinded copper-slag with different proportion was added to portland cement. The physical properties of the cement mortars, (i.e.) flowability, absorption, compressive strength and flexural strength, were investigated for the potential application to the cement. Also, the influence of the acid on the chemical resistance of the cement mortars with copper-slag was evaluated by monitoring the weight variation of the cement mortars under 5 % sulfuric acid for 28 days.

Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack (알칼리 활성화 슬래그 시멘트 모르타르의 내황산성)

  • Min, Kyung-San;Lee, Seung-Heun
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

Preparation and Swelling Characteristics of Hydrogel from Microbial Poly(${\gamma}-glutamic acid$) by ${\gamma}$-Irradiation

  • Choi, Seong-Hyun;Whang, Kyung-Sook;Park, Jong-Soo;Choi, Woo-Young;Yoon, Min-Ho
    • Macromolecular Research
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    • v.13 no.4
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    • pp.339-343
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    • 2005
  • Microbial hydrogel was prepared by ${\gamma}-irradiation$ of poly(${\gamma}-glutamic acid$) (PGA) which was produced from Bacillus subtilis BS 62 and it's physico-chemical characteristic was examined. The hydrogel, prepared from 10% PGA with the dose of 48 kGy, was swollen up to 1,370 times of specific water content as dry weight basis. The hydrogels obtained above the dose of 48 kGy appeared to have higher compressive strength but lower specific water content. The period to reach a swelling equilibrium for the hydrogel in deionized water at the temperature range of 4 to $45^{\circ}C$ was about 10 h. The swollen hydrogel was shrunk in ionic solutions with the increase of ionic strength, and the rate of shrinkage was greater in calcium chloride solution than in sodium chloride. Specific water content of the hydrogel was quickly decreased at $80^{\circ}C$, showing a thennally hydrodegradable property.

Biodegradable sheath-core biphasic monofilament braided stent for bio-functional treatment of esophageal strictures

  • Han, Cheol-Min;Lih, Eugene;Choi, Seul-Ki;Bedair, Tarek M.;Lee, Young-Jae;Park, Wooram;Han, Dong Keun;Son, Jun Sik;Joung, Yoon Ki
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.396-406
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    • 2018
  • In this study, a polydioxanone (PDO) and poly(L-lactic acid) (PLLA) sheath-core biphasic monofilament was designed to develop an esophageal stent with improved mechanical properties and controlled biodegradability. The radial force of PDO/PLLA sheath-core stent was 10.24 N, while that of PDO stent was 5.64 N. Deteriorations of tensile strength, elastic modulus and elongation during degradation test were also delayed on PDO/PLLA group. Hyaluronic acid-dopamine conjugate and $BaSO_4/PDO$ conjugate coating layers provided improved tissue adhesion strength and reasonable X-ray contrast, respectively. Taken all together, the sheath-core filaments with tissue adhesive and radiopaque properties will be useful in designing esophageal stents.

Changes in Acid Graft Ratio and Al-CPP Lamination Peel Strength by Polyolefin Reaction Conditions (폴리올레핀의 반응 조건별 산변성도 변화 및 Al-CPP 라미네이션 박리강도 변화)

  • Jong Hyun Park;Hong Jun Chae
    • Journal of Adhesion and Interface
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    • v.25 no.1
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    • pp.152-156
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    • 2024
  • We conducted research on a two-component epoxy adhesive material based on acid graft polyolefin using maleic anhydride to address the lack of formability due to epoxy adhesives' hard segments. To understand the graft efficiency according to reaction conditions, we conducted studies based on polyolefin molecular weight, initiator half-life, and initiator concentration for each process. The maleic anhydride grafted polyolefin produced was used as an adhesive material for aluminum and CPP film lamination after mixing with epoxy hardener. The graft efficiency in the solution process was approximately 30% superior to that in the melt process, and an increase in graft ratio confirmed an increase in peel strength.

Strength and conversion characteristics of DeNOx catalysts with the addition of dispersion agent (분산제 첨가에 따른 탈질촉매의 강도세기 및 전환특성)

  • Lee, Hyun Hee;Park, Kwang Hee;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.12
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    • pp.6575-6580
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    • 2013
  • Various modified SCR catalysts were prepared and tested to improve the strength of catalysts for use under severe conditions. The SCR catalysts were modified with a binder and dispersion agent, and tested at the fixed bed reactor. FT-IR and $H_2$-TPR were used to analyze the degree of hydrogen use and ammonia adsorption by the modified catalysts. In the case of the SCR catalysts coated with 2.3g of the binder, 4.7g of ethanol, and 0.1g of dispersion agent, the strength of catalyst was increased by approximately 12%. On the other hand, despite the enhancement of strength, the activities of the SCR catalysts were decreased by 2-10%. When the mixed solution composed of binder, dispersion agent and $SiO_2$ solution was precipitated on the catalyst, the $NO_x$ conversion of the catalyst was decreased slightly. The Bronsted acid site and Lewis acid site worked as the activators for the SCR reaction, and were decreased by $SiO_2$.

Mechanical Properties and Microstructure of the Leucite-Reinforced Glass-Ceramics for Dental CAD/CAM

  • Byeon, Seon-Mi;Song, Jae-Joo
    • Journal of dental hygiene science
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    • v.18 no.1
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    • pp.42-49
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    • 2018
  • The computer-aided design/computer-aided manufacturing (CAD/CAM) system was introduced to shorten the production time of all-ceramic restorations and the number of patient visits. Among these types of ceramic for dental CAD/CAM, they have been processed into inlay, onlay, and crown shapes using leucite-reinforced glass-ceramics to improve strength. The purpose of this study was to observe the mechanical properties and microstructure of leucite-reinforced glass-ceramics for dental CAD/CAM. Two types of leucite-reinforced glass-ceramic blocks (IPS Empress CAD, Rosetta BM) were prepared with diameter of 13 mm and thickness of 1 mm. Biaxial flexural testing was conducted using a piston-on-three-ball method at a crosshead speed of 0.5 mm/min. Weibull statistics were used for the analysis of biaxial flexural strength. Fracture toughness was obtained using an indentation fracture method. Specimens were observed by field emission scanning electron microscopy to examine the microstructure of the leucite crystalline phase after acid etching with 0.5% hydrofluoric acid aqueous solution for 1 minute. The results of strength testing showed that IPS Empress CAD had a mean value of $158.1{\pm}8.6MPa$ and Rosetta BM of $172.3{\pm}8.3MPa$. The fracture toughness results showed that IPS Empress CAD had a mean value of $1.28{\pm}0.19MPa{\cdot}m^{1/2}$ and Rosetta BM of $1.38{\pm}0.12MPa{\cdot}m^{1/2}$. The Rosetta BM sample exhibited higher strength and fracture toughness. Moreover, the crystalline phase size and ratio were increased in the Rosetta BM sample. The above results are expected to elucidate the basic mechanical properties and crystal structure characteristics of IPS Empress CAD and Rosetta BM. Additionally, they will help develop leucite-reinforced glass-ceramic materials for CAD/CAM.

Effect of In Vitro Degradation on the Weight Loss and Tensile Strength of PLA/PEG Melt Blend Fiber (In Vitro 분해가 PLA/PEG 용융블렌드 섬유의 무게감량률 및 인장강도에 미치는 영향)

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.581-587
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    • 2009
  • PLA/PEG blend fibers composed of poly (lactic acid) (PLA) and poly (ethylene glycol) (PEG) were prepared via melt blending and spinning for bioabsorbable filament sutures. The blend fibers hydrolyzed with the immersion in a phosphate buffer solution at pH 7.4 and $37\;^{\circ}C$ for 1~8 weeks. The effects of blending time, blend composition, and hydrolysis time on the weight loss and tensile strength of the hydrolyzed blend fibers were investigated. After hydrolysis, the weight loss of the blend fibers increased with increasing PEG content, blending time, and hydrolysis time. The tensile strength and tensile modulus of the blend fibers decreased with increasing PEG content, blending time, and hydrolysis time. Therefore, it can be concluded that the weight loss of the PLA/PEG blend fibers was less than 0.9% even at hydrolysis time of 2 weeks and their strength retentions were over 90%.

Physical and Mechanical Properties of Light Red Meranti Treated with Boron Preservatives

  • Man Djun LEE;Ridge Wei Cheong TANG;Zeno MICHAEL;Miqdad KHAIRULMAINI;Azmi ROSLAN;Ahmad Faidzal KHODORI;Hazim SHARUDIN;Pui San LEE
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.2
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    • pp.157-174
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    • 2024
  • This study investigates the influence of varying concentrations of boric acid (BA) preservative on the physical and mechanical properties of light red meranti (LRM) found in Sarawak. LRM or Shorea leprosula samples were treated with various concentrations of BA via the dip diffusion method using American Society for Testing and Materials (ASTM) standards. The physical property, particularly the retention rate and mechanical properties, bending strength, modulus of elasticity (MOE), tensile and compression strength parallel to grain of impregnated and control samples were tested to determine the effects of BA preservative. The retention rate was found to increase with increasing BA concentration and higher surface area to volume ratio. The mechanical properties in terms of the MOE and tensile strength parallel to grain were found to be greater than those of the control samples, whereas the bending strength and tensile strength parallel to grain were lower. Amongst the results, only the retention rate and MOE showed significant interaction effects at 5% level of significance between all factors tested (samples size and BA concentration for retention rate and BA concentration for MOE).