• Title/Summary/Keyword: Y-coupling

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External Magnetic Field Influence on Exchange Coupling Oscillations in Ultrathin Fe/Au/Tb Film Structures

  • Pogoryelov, Ye.
    • Journal of Magnetics
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    • v.9 no.4
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    • pp.97-100
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    • 2004
  • In the present work exchange coupling between ultrathin Fe ($8{\AA}$) and Tb ($12{\AA}$) layers separated by Au spacer of varied thickness ($3-20{\AA}$) was studied. Anomalous Hall effect measurements showed weakly damped oscillating dependence of the Hall conductivity as a function of Au spacer thickness. Disagreement of the observed damping with the RKKY model of interlayer exchange coupling was explained by the influence of external magnetic field on the behaviour of exchange coupling oscillations. It was confirmed by Hall-like effect measurements at zero applied magnetic field and also illustrated by corresponding estimations.

Palladium-Catalyzed Coupling between Quinolone Moieties and Heteroaryl Stannes - Synthesis of C-7 heteroaryl Quinolone Derivatives - (팔라듐 촉매를 이용한 퀴놀론핵과 Heteroaryl Stannes의 결합 - C-7 heteroaryl 쿼놀론 유도체의 합성 -)

  • 남상훈;함원훈;김기수;임태균;양재권
    • YAKHAK HOEJI
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    • v.37 no.6
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    • pp.615-620
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    • 1993
  • The cross-coupling reaction of organo tin reagents with a variety of organic halides, catalyzed by palladium, provides a novel method for generating a carbon-carbon bond. We used this method for the antibacterial agents, and synthesis of new quinolone derivatives which have carbon-carbon bond at C-7 position of general quinolone moieties. Aryl tin, quinolone moieties, and palladium catalyst were refluxed in DMF to afford new quinolone derivatives. This palladium catalyzed coupling reactions have capacity for further synthetic elaboration.

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Nonlinear Virtual Coupling for Stable Haptic Interaction (안정된 햅틱 인터페이스를 위한 비선형가상커플링)

  • 이문환;이두용
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.8
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    • pp.610-615
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    • 2003
  • This paper proposes a nonlinear virtual coupling fur haptic interface, which offers better performance while maintaining stability of the system. The nonlinear virtual coupling is designed based on a human response model. This human response model exploits delay between the human Intention and the actual change of arm impedance. The proposed approach provides with less conservative constraints for the design of stable haptic interface, compared with the traditional passivity condition. This allows increased performance that is verified through experiments.

Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

  • Cho, Chul-Hee;Kim, Chul-Bae;Sun, Myung-Chul;Park, Kwang-Yong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1632-1636
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    • 2003
  • Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

A Study on the Analysis of Steady Magnetic Fields by the Coupling of FEM and BEM (FEM과 BEM의 혼합적용에 의한 정상자계의 해석에 관한 연구)

  • 임달호;김찬오
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.34 no.7
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    • pp.276-282
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    • 1985
  • This study is concerned with the analysis of two-dimensional steady magnetic fields by the coupling of FEM and BEM. FEM(Finite Element Method)is most widely used as a method of numerical analysis and BEM (Boundary Element Method)is a newest method for it. And the results from this coupling method are compared and discussed with those of FEM only. Consequently, it is shown that to obtain the same accuracy of results the coupling method requires less calculating time and dimension than the FEM.

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Concise Synthesis of Flurbiprofen via Palladium-Catalyzed Cross-Coupling Reactions (팔라듐 촉매하 결합반응을 이용한 플루비프로펜의 간결한 합성)

  • Han, Young Taek
    • YAKHAK HOEJI
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    • v.59 no.2
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    • pp.66-69
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    • 2015
  • A concise synthesis of flurbiprofen, a member of the non-steroidal anti-inflammatory 2-arylpropionic acids, has been accomplished. The key feature of this synthesis involves successive palladium-catalyzed cross coupling reactions. In particular, a 2-arylacylate intermediate, which easily converted to the key 2-arylpropionic acid scaffold, was afforded by a versatile palladium-catalyzed cross coupling reaction between diazopropanate and bisphenylboronic acid. This synthetic procedure would facilitate synthesis of the flurbiprofen and anti-inflammatory 2-arylpropionic acid derivatives.

Exchange coupling of Co/NiMn bilayer (Co/NiMn의 교환 자기결합에 관한 연구)

  • 안동환;조권구;주승기
    • Journal of the Korean Magnetics Society
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    • v.10 no.4
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    • pp.171-177
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    • 2000
  • Exchange coupling of Co/NiMn bilayers fabricated by RF magnetron sputtering method was studied. We investigated the variation of exchange coupling field (H$\sub$ex/) for different annealing temperature and time. The maximum exchange coupling field was obtained after 13hr annealing at 300 $^{\circ}C$. With respect to deposition sequence, it was demonstrated that NiMn-top bilayers had higher exchange coupling field than NiMn-bottom bilayers. Ta capping layer was shown to be essential in achieving exchange coupling and Auger Electron Spectroscopy (AES) proved that uncapped NiMn/Co bilayers did not have exchange coupling because of oxygen incorporation into film. We also observed the effect of Ta underlayer on exchange coupling. It was found that Ta underlayer had better not be used for attaining higher exchange coupling. XRD analysis showed that Ta underlayer helped bilayers develop texture, but it was not essential to exchange coupling of Co/NiMn bilayers, which is in contrast to NiFe/NiMn system. Furthermore, the NiMn and Co thickness dependence of exchange coupling has been investigated. The exchange coupling strength reached the maximum above 200 ${\AA}$ NiMn thickness and had inversely proportional relation with Co thickness.

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Mumetal Growing Temperature Effect on the Exchange Coupling of Cu/mumetal/Al Oxide/Co/Cu Multilayers

  • Lee, Y.W.;Lee, T.H.;Kim, C.G.;Kim, C.O.;Yoon, T.S.;Lee, Y.H.
    • Journal of Magnetics
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    • v.7 no.1
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    • pp.14-17
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    • 2002
  • Magnetic multilayers of a ferromagnetic (FM)/insulator (I)/ferromagnetic (FM) structure have been studied to investigate magnetic exchange coupling between two FM layers. As the Mumetal $(Ni_{77}Fe_{14}Mo_{5}Cu_4$ wt%) growth temperature increases, the grain size and the surface roughness increase simultaneously. The smallest coupling field is obtained at $40^\circ{C}$ where the grain size is larger than that of the $20^\circ{C}$ sample. The exchange coupling field increases again at temperatures higher than $40^\circ{C}$ due to increase in the surface roughness of the Mumetal.

The Behavior of Earth Retaining Structures Using p-y Curve with Coupling (p-y 특성곡선의 Coupling을 고려한 토류벽의 거동해석)

  • Kim, Soo Il;Jeong, Sang Seom;Chang, Buhm Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.553-563
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    • 1994
  • The behavior of earth retaining structure was investigated by considering coupling between soil springs in elasto-plastic soil. For the computation of soil reaction, soil on both sides of walls was simplified as e1asto-plastic springs, and the required horizontal displacement to mobilize Terzaghi's active and passive state was applied to construct the p-y curve. Reliability on computer program developed is verified through the comparison between prediction and in-situ measurements. Based on the results obtained, it is found that the prediction by using coupling between soil springs simulates well the general trend observed by the in-situ measurements. It is also found that the horizontal displacement required for the active state gives a very small effect to the displacement of walls in the sandy soil.

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The Resonance of Marine Propulsion Shaft System excited by Diesel Engine (디젤엔진의 가진에 의한 선박용 추진 축계의 공진)

  • Lee, D.C.;Kang, B.Y.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2009.10a
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    • pp.248-253
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    • 2009
  • The propulsion system which apply the diesel engine with reduction gear as prime mover, generally installs the elastic coupling between engine and intermediate shaft, This coupling can isolate the vibratory torque excited by diesel engine, or the excess transient torque and moment occurring by external impact. So, diesel engine and reduction gear can safely operate by elastic coupling. Unfortunately, the elastic coupling for skimmer vessel was repeatedly broken by unknown vibration during the sea trial In this paper, the authors are searching for the possibilities and causes of the elastic coupling failure, via the global vibration measurement and the past incident investigation.

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