Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

  • Cho, Chul-Hee (Department of Chemical Engineering, Chung-Ang University) ;
  • Kim, Chul-Bae (Department of Chemical Engineering, Chung-Ang University) ;
  • Sun, Myung-Chul (Department of Chemical Engineering, Chung-Ang University) ;
  • Park, Kwang-Yong (Department of Chemical Engineering, Chung-Ang University)
  • Published : 2003.11.20
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Abstract

Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

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References

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