• Nuclear Engineering and Technology
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• v.54 no.5
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• pp.1560-1569
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• 2022

Liquid fueled molten salt reactors (MSRs) have seen renewed interest because of their inherent safety features, higher thermal efficiency and potential for efficient thorium utilisation for power generation. Thorium fluoride is one of the salts used in liquid fueled MSRs employing Th-U cycle. In the present study, ThF₄ was prepared by hydro-fluorination of ThO₂ using anhydrous HF gas. Process parameters viz. bed depth, hydrofluorination time and hydrofluorination temperature, were optimized for the preparation of ThF₄ in a static bed reactor setup. The products were characterized with X-Ray diffraction and experimental conditions for complete conversion to ThF₄ were established which also corroborated with the yield values. Hydrofluorination of ThO₂ at 450 ℃ for half an hour at a bed depth of 6 mm gave the best result, with a yield of about 99.36% ThF₄. No unconverted oxide or any other impurity was observed. Rietveld refinement was performed on the XRD data of this ThF₄, and Chi2 value of 3.54 indicated good agreement between observed and calculated profiles.

• Proceedings of the Optical Society of Korea Conference
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• 2000.02a
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• pp.20-21
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• 2000

헤르츠가 최초로 무선통신의 가능성을 보인 이후 인류는 수 킬로헤르츠 (kHz)의 주파수를 이용하기 시작하여 메가헤르츠 (MHz) 대역에서 라디오, 텔레비젼, 음성 통신 등의 엄청난 기술적 발전으로 문명에 기여해 왔다. 이 MHz 대역이 포화하기 시작하자 더 높은 주파수의 기술을 연구하여 개인 휴대통신, 위성통신 등에 기가헤르츠 (GHz) 대역을 활용하였다. 반면에 빛이라 불리는 매우 높은 주파수의 전자기파는 뢴트겐이 X-ray를 투시 촬영기에 이용한 이래 광통신 등이 발명되어 가시광선에서 적외선까지 더 낮은 주파수 쪽으로 발전·활용되어 왔다. 이러한 광파와 마이크로 전자기파 사이의 테라헤르츠 (THz)주파수 대역 (또는 원적외선 영역 혹은 T-ray라 불림)은 많은 잠재적인 응용분야에도 불구하고 용이한 신호원의 부재로 기초적인 연구도 미비한 상태이다 (그림1 참조). (중략)

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.268-274
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• 1992

An attempt to improve the second harmonic generation (SHG) efficiency of MAP (methyl (2,4-dinitrophenyl)aminopropanoate) by modifying the substituents on the amino group of MAP is described. Several MAP analogues have been prepared using optically active amino acids alanine, phenylalanine and serine, and their SHG efficiencies measured. None of the MAP analogues exhibited SHG efficiencies as high as that of MAP. X-ray crystal structures of three MAP analogues have been determined. In the crystal structures of two of them, which were the derivatives of phenylalanine, two crystallographically-independent molecules existing in the asymmetric unit are aligned almost antiparallel. These structures are consistent with the very low SHG efficiencies of these compounds. On the other hand, the crystal structure of a serine derivative reveals substantial alignment of the dinitroaniline chromophore along the polar axis. However, the angle of 86.2° between the molecular charge tranfer axis and the polar axis of the crystal is still far away from the optimum value of 54.74° for the phase-matchable SHG. The structure is consistent with the SHG efficiency of this compound which is much higher than those of the phenylalanine derivatives but still lower than that of MAP. This study demonstrates the importance of the orientation of molecules in the crystal lattice in determining secod-order nonlinear optical properties of crystalline materials.

• Korean Journal of Materials Research
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• v.28 no.6
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• pp.317-323
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• 2018

Crystal structure of the $L1_2$ type $(Al,X)_3Ti$ alloy (X = Cr,Cu) is analyzed by X-ray diffractometry and the nonuniform strain behavior at high temperature is investigated. The lattice constants for the $L1_2$ type $(Al,X)_3Ti$ alloys decrease in the order of the atomic number of the substituted atom X, and the hardness tends to increase. In a compressive test at around 473K for $Al_{67.5}Ti_{25}Cr_{7.5}$, $Al_{65}Ti_{25}Cr_{10}$ and $Al_{62.5}Ti_{25}Cu_{12.5}$ alloys, it is found that the stress-strain curves showed serration, and deformation rate dependence appeared. It is assumed that the generation of serration is due to dynamic strain aging caused by the diffusion of solute atoms. As a result, activation energy of 60-95 kJ/mol is obtained. This process does not require direct involvement. In order to investigate the generation of serrations in detail, compression tests are carried out under various conditions. As a result, in the strain rate range of this experiment, serration is found to occur after 470K at a certain critical strain. The critical strain increases as the strain rate increases at constant temperature, and the critical strain tends to decrease as temperature rises under constant strain rate. This tendency is common to all alloys produced. In the case of this alloy system, the serration at around 473K corresponds to the case in which the dislocation velocity is faster than the diffusion rate of interstitial solute atoms at low temperature.

• Journal of Welding and Joining
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• v.29 no.2
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• pp.56-63
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• 2011

his paper aimed to understand the residual stress in the dissimilar metal welds of nuclear power plant. Two kinds of residual stress were considered, which caused by welding and machining. Residual stress due to mechanical machining was measured by hole-drilling technique and x-ray diffraction method for the SA508 and F316L. Weld residual stress at dissimilar metal weld between SA508 and F316L was evaluated by FEA. Residual stress profiles were obtained for the inside surface and through thickness of welds. Machining effect was also analyzed by FEA. According to the residual stress measurement, it was observed that mechanical machining can generate tensile stress on the surface of the test material. However, FEA results showed that mechanical machining did not increase the tensile stress on the surface of weld region. Further study with more elaborate measurement and numerical analysis is required to identify the effect of machining on residual stress in the dissimilar metal weld region.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.51.2-51.2
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• 2019

Multi-wavelength observations become very popular in astronomy. Even though there are some correlations among different sensor images, it is not easy to translate from one to the other one. In this study, we apply a deep learning method for image-to-image translation, based on conditional generative adversarial networks (cGANs), to solar images. To examine the validity of the method for scientific data, we consider several different types of pairs: (1) Generation of SDO/EUV images from SDO/HMI magnetograms, (2) Generation of backside magnetograms from STEREO/EUVI images, (3) Generation of EUV & X-ray images from Carrington sunspot drawing, and (4) Generation of solar magnetograms from Ca II images. It is very impressive that AI-generated ones are quite consistent with actual ones. In addition, we apply the convolution neural network to the forecast of solar flares and find that our method is better than the conventional method. Our study also shows that the forecast of solar proton flux profiles using Long and Short Term Memory method is better than the autoregressive method. We will discuss several applications of these methodologies for scientific research.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.135-140
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• 2008

An electrochemical generation of ozonized water was investigated by using ${\beta}-PbO_2$ as an anode and tap water as an anolyte. According to the potentiometric ozone detection which utilizes potential differences arisen from a chemical reaction of ozone and iodide, increasing tendency of ozone concentration on electrolysis time could be observed to show the maximum value of 8 ppm at an electrolysis time of 10 min. Ozone could be generated promptly even at an electrolysis time of 10 sec., suggesting great advantages of this electrochemical process in terms of simplicity and readiness that might be applied directly to practical uses including medical and/ or food industries. Influences of electrolysis on the properties and surface conditions of a $PbO_2$ electrode were also discussed from the results of cyclic voltammetry, scanning electron microscope, and X-ray diffractometer.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.2
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• pp.173-180
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• 2015

The purpose of this study was to fabricate a ferric nitrate impregnated activated carbon, and the performance for hydrogen sulfide by adsorption was evaluated. Sodium hydroxide was utilized to control pH in the process during generation of ferric hydroxide on the surface of the carbon. Critical mixing duration for generation of ferric hydroxide on the carbon was 48 hrs at pH 1 of the solution, in which the chemical adsorption of hydrogen sulfide was enhanced. The adsorption capacity of the impregnated carbon increased up to 0.10 g hydrogen sulfide/g carbon, which was 4.3 times higher than that of the raw carbon. Presence of FeOOH on the surface of the impregnated carbon was examined by X-ray diffraction.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.11a
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• pp.699-702
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• 2004

Next generation lithography technologies, such as EBL(Electron Beam Lithography), X-ray lithography, SPL(Scanning Probe Lithography), have been studied widely for getting over line width limitation of photolithography. Among the next generation lithography technologies, SPL has been highlighted because of its high resolution advantage. But is also has problem which are slow processing time and sample size limitation. The purpose of this study is complement of present SPL system. Brand new SPL system was made. SPL test was performed with the system in ultra thin PMMA(polymethlymethacrylate) film.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.72-81
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• 2024

In this study, DEIPA was used for enhancing cementitious performance of bottom ash replaced cement. By applying the partial or no-known crystal structure method to X-ray diffraction data, the amounts of amorphous bottom ash and calcium silicate hydrate(C-S-H) could be separated and quantified. In the sample without DEIPA, the bottom ash hardly reacted, resulting in low compressive strength. However, the addition of DEIPA not only altered the hydration behavior of the cement but also enhanced the pozzolanic reaction between bottom ash and calcium hydroxide, leading to the generation of additional C-S-H. This resulted in high compressive strength not only in the early stages but also in the later stages. Therefore, with the addition of DEIPA during the pulverization of the bottom ash, the reactivity of the bottom ash was significantly improved. Hence, there is potential in the development of bottom ash replacement cement.