• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.11a
• /
• pp.273-274
• /
• 2023

In this study, ultrasonic pulse velocity was analyzed to evaluate the high-temperature mechanical properties of concrete mixed with non-sintered hwangto. The W/B of the specimens was set at 0.41, the percentage of non-sintered hwangto admixture was set at two levels of 15,30%. The target temperature of the specimen is set to 6 levels of 20, 100, 200, 300, 500, 700 ℃, and the heating rate is set to 1℃/min. The result showed that the amount of non-sintered hwangto incorporated into the concrete tends to results in lower compressive strength. Ultrasonic pulse velocity showed similar trends, but differed in some areas.

• Journal of the Korea Institute of Building Construction
• /
• v.14 no.1
• /
• pp.110-117
• /
• 2014

The objective of this study is to investigate an effect of curing temperature on autogenous shrinkage of high strength cement mortar with 0.15 of W/B incorporating fly ash and silica fume in terms of equivalent age. The contents of fly ash and silica fume are varied from 10% to 30%. Non linear regression model applying equivalent age was used to estimate the autogenous shrinkage evolution. To obtain apparent activation energy($E_a$), setting time method by Pinto and existing method were calculated and compared respectively. Test results showed that use of silica fume increased autogenous shrinkage while use of fly ash decreased it. It was also found that poor agreements were obtained when $E_a$ by setting time was applied. But, application of existing $E_a$ resulted in a good agreement between calculated autogenous shrinkage and measured one.

• Applied Chemistry for Engineering
• /
• v.9 no.3
• /
• pp.317-321
• /
• 1998

X-type Zeolite for the gas separation was prepared by hydrothermal methods and the zeolite was ion-exchanged with KCl, $CaCl_2$, $YCl_3$ and $InCl_3$ in order to investigate the effect of ions on the properties of molecular sieves. Adsorption isotherms of $CO_2$ on ion exchanged X-type zeolites and those of $O_2$ and $N_2$ on the synthesized zeolite were measured at $25^{\circ}C$ using a volumetric method and the adsorption characteristics were compared with each other. Model parameters for the Langmuir, Freundlich and Toth equations were regressed for the measured adsorption isotherms. In order to confirm the applicability of the zeolite on $CO_2-PSA$ processes, breakthrough tests and process simulation were undertaken. It was found that the X-type zeolite could be a potential adsorbent in recovering $CO_2$ from flue gas.

• Magazine of the Korea Concrete Institute
• /
• v.11 no.1
• /
• pp.141-148
• /
• 1999

Recently, high performance concrete developed has a good quality at fresh and hardened state, but high binder contents results in spending much money on manufacturing and many cracks by drying and autogenous shrinkage, Therefore, in this paper, not only prevention of cracks caused by drying and autogenous shrinkage, but improvement of quality and accomplishment of economy by applying F.A(fly ash), S.F(silica fume) and CSA(calcium sulfa aluminate) expansive additives as an inorganic admixtures in W/B 35% are discussed. According to the experimental results, when 5% of CSA expansive additives and 15:5(F.A:S.F)are replaced at unit cement content, high performance concrete with both good fluidity at fresh state and high compressive strength, compensation of drying and autogenous shrinkage at hardened state are accomplished.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• v.y2004m10
• /
• pp.71-76
• /
• 2004

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for $3\sim4$ replacement ratios under W/B ratios ranged from 0.40 to 0.55. Specimens were immersed in $3.6\%$ NaCl solution for 330 days, and penetration depth, water soluble chloride contents and acid soluble chloride contents were measured in 28, 91, 182 and 330 days. Then, diffusion coefficient were calculated using total chloride contents. As a results. the kinds of mineral admixture and replacement ratios had a great effect on the resistance property of the concrete to chloride ion invasion compared with the plain concrete. And the optimal replacement ratios of mineral admixture had a limitation for each admixtures. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures and the penetration depth from the concrete skin. Chloride diffusion coefficient of each concretes decreased with the time elapsed. and the diffusion coefficients of the concrete immersed salt water for 330 days had a establishment with the compressive strength measured before immersing.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.445-448
• /
• 2008

It is essential that concrete component is made up with aggregate, cement and water. But today, Public concern is increasing of a variety structure and ocean environmental, resource recycle. Also, According to heat of hydration rising, Concrete is make a causative of concrete-crack. Concrete-crack cause a falling-off in quality of concrete. consequently, High-performance concrete is evaluated by concrete material properties and carbonation resistance with different admixture(fixing fly-ash 20%), granulated blast furnace slag replacement ratio (30%, 45%) different W/B (26%, 30%, 34%) and XRD(X-ray Diffraction) analysis.

• Journal of the Korea Institute of Building Construction
• /
• v.19 no.5
• /
• pp.421-429
• /
• 2019

The changes in the resistance to chloride ingress of concrete using a ground granulated blast furnace slag (GGBFS) according to curing conditions were examined. The curing conditions were divided in air-dry curing and under-water curing. Three concrete mixures with the GGBFS replacement ratio of 0%(control), 30%, and 60% were prepared. For tests, evaluations of concrete compressive strength, and chloride ion diffusion coefficient were performed. As the GGBFS replacement ratio increased, the concrete compressive strength of the in air-dry cured specimens decreased compared to under-water cured specimens. When the chloride ion diffusion coefficient was measured, the chloride ion diffusion coefficient decreased as the GGBFS replacement ratio increased. However, the diffusion coefficient of the in air-dry cured specimen was increased up to 111% compared with the under-water cured specimen.

• Journal of the Korean Chemical Society
• /
• v.42 no.2
• /
• pp.190-196
• /
• 1998

A new sampling and size exclusion chromatography (SEC) method for the analysis of underivatized cellulose are established. In this method, cellulose materials are first dissolved in N-methylmorpholine N-oxide (NMMO) and diluted by adding dimethyl sulfoxide (DMSO) to make the sample solutions of about 0.1% in 50/50 NMMO/DMSO (w/w). Sample solutions are analyzed using a glucose-treated divinylbenzene (DVB) SEC column and DMSO containing 0.05M LiBr and 2.5 blank as the eluant. The flow rate was constant at 1 mL/min and the whole SEC system including the column was heated at $80^{\circ}C$ to reduce the viscosity of DMSO. Addition of 0.05 M LiBr eliminated SEC baseline drifting, and addition of 2.5 blank seems to reduce the interaction between the sample and the column packing. SEC molecular weights were determined using a calibration curve constructed from a series of narrow pullulan standards, and they were used to measure the degree of degradation during two different pulp-to-sponge processings.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.533-536
• /
• 2008

This study is the application of phosphate magnesia cement for solidification of soils. The object of the study is the application of the pavment of the farm roads. The new pavement method must be environmental, ecologic and durable. So, for solidification of farm road's soil, we use magnesia cement as quick setting, high strength materials. At magnesia phosphate cement, mixing ratio of mono ammonium phosphate and magnesia is 4:6 and w/b is 50 wt%, it show 14 MPa of compressive strength, and high hydration heat. Solidified soils that mixing ratios of magnesia cement and soil are 4:6 and 5:5 have very high durability for freezing and thawing.

• Journal of the Korea Concrete Institute
• /
• v.24 no.3
• /
• pp.233-240
• /
• 2012

Hybrid SHCC is being researched actively for its excellent performance in controlling macro and micro cracks using macro and micro fibers, respectively. However, a significant autogenous shrinkage of SHCC is expected since it possesses high unit cement volume in its mix proportion, resulting in autogenous shrinkage cracks. Therefore, this study was performed to evaluate mechanical property of shrinkage-reducing type hybrid SHCC mixed together with steel fiber and PE fiber with excellent micro/macro crack controlling performance. In order to evaluate mechanical property of shrinkage-reducing type hybrid SHCC, replacement ratios of 0% and 10% of expansive admixture and water to binder ratios of 0.45, 0.3, and 0.2 were considered as variables. Then, shrinkage, compressive, flexural, and direct tensile tests were performed. The test results showed that mix proportion with W/B 0.3 significantly improved mechanical performance by using 10% replacement of expansive admixture.