• Title/Summary/Keyword: Time-Temperature Parameter

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Equilibrium, Kinetic and Thermodynamic Parameter Studies on Adsorption of Acid Black 1 Using Coconut Shell-Based Granular Activated Carbon (야자각계 입상 활성탄의 Acid Black 1 염료 흡착에 대한 평형, 동역학 및 열역학 파라미터의 연구)

  • Lee, Dong-Chang;Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.590-598
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    • 2016
  • In this study, the adsorption behavior from aqueous solution as well as kinetic and thermodynamic parameters of Acid Black 1 were investigated through batch reaction using coconut shell based granular steam activated carbon. The effects of various adsorption parameters such as pH, initial concentration, contact time, temperature were studied. To confirm the effect of pH, pHpzc measurements were analyzed followed by measuring removal efficiencies of Acid Black 1 at the pH range from 3 to 11. Experimental equilibrium adsorption data were fitted using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich adsorption isotherm. The conformity of adsorption reaction for pseudo first and second order model were evaluated through kinetic analysis. Values of enthalpy change and activation energy were also investigated through thermodynamic analysis and it was confirmed that the adsorption process was endothermic. The spontaneity of adsorption process was evaluated using the values of entropy and Gibbs free energy changes.

Finding Optimal Conditions for the Densification Process of Carbon Materials (탄소 소재 치밀화 공정의 밀도향상을 위한 최적 조건 설정)

  • Kwon, Choonghee;Yang, Jaekyung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.40 no.3
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    • pp.76-82
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    • 2017
  • Recently, the material industry in the world has started appreciating the value of new materials that can overcome the limitation of steel material. In particular, new materials are expected to play a very important role in the future industry, demonstrating superior performance compared to steel in lightweight materials and ability to maintain in high temperature environments. Carbon materials have recently increased in value due to excellent physical properties such as high strength and ultra lightweight compared to steel. However, they have not overcome the limitation of productivity and price. The carbon materials are classified into various composites depending on the purpose of use and the performance required. Typical composites include carbon-glass, carbon-carbon, and carbon-plastic composites. Among them, carbon-carbon composite technology is a necessary technology in aviation and space, and can be manufactured with high investment cost and technology. In this paper, in order to find the optimal conditions to achieve productivity improvement and cost reduction of carbon material densification process, the correlation between each process parameters and results of densification is first analyzed. The main process parameters of the densification process are selected by analyzing the correlation results. And then a certain linear relationship between major process variables and density of carbon materials is derived by performing a regression analysis based on the historical production result data. Using the derived casualty, the optimal management range of major process variables is suggested. Effective process operation through optimal management of variables will have a great effect on productivity improvement and manufacturing cost reduction by shortening the lead time.

A study on the robust design for quality improvement of Wet Etchant manufacturing process (식각액(Wet Etchant)제조공정의 품질향상을 위한 강건설계에 대한 연구)

  • Choi, Yong-Seok;Hwang, Deock-Hyeong;Cho, Kwang-Hee;Oh, Sun-Il;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.14 no.1
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    • pp.155-165
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    • 2012
  • This essay talks about research of robust design for quality improvement of production procedure of Wet Etchant. It suggested the optimum design method in consideration of specific capability value that is the way to maximize the quality of product in the production system by using Daguchi parameter design method while finding factors affecting product quality with analysis of production system of product A from producer D. Also, it set long term of 6months as noise factor and let it to be the robust design that can find the optimum condition of control factor that is dull to the changes of each month, that is the change in noise factor. The control factor which affects the product quality is decided as combination method, temperature of raw material, combination time and as there are too many possibilities for combination methods, we performed 4 methods first based on previous research data then derived three ways with product that passed SPEC and set as the factor. As a result of application of optimum production procedure suggested in this essay to the actual production process with its standardization, there was a effect of drop of more than 10particles in comparison to the particle number of previous product and also it brought the effect that resulted the stable number of particle of under 30 that is what the client company suggested.

Observation and Compensation of Voltage Distortion of PWM VSI for PMSM using Adaptive Control Method (영구자석 동기전동기 구동을 위한 전압원 인버터의 적응제어기법을 이용한 전압 왜곡 관측 및 보상)

  • Kim Hag-Wone;Youn Myung-Joong;Kim Hyun-Soo;Cho Kwan-Youl
    • The Transactions of the Korean Institute of Power Electronics
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    • v.10 no.1
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    • pp.52-60
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    • 2005
  • Generally, a voltage difference or voltage distortion exists between the reference voltage and the practical voltage applied to a motor in a pulse width modulated(PWM) voltage source inverter(VSI). This voltage distortion varies with the operating conditions such as the temperature, DC link voltage, and phase current level. Also the voltage distortion affects the machine current distortion, torque pulsations, and control performance. In this paper, the voltage distortion in a PWM VSI is analyzed and a new on-line estimation method based on the model reference adaptive system(MRAS) is proposed to compensate the time varying voltage distortion, while considering the parameter variations for a permanent magnet synchronous motor (PMSM). The simulation and experimental results show the effectiveness of the proposed voltage difference observer and the compensation method.

Removal of toxic hydroquinone: Comparative studies on use of iron impregnated granular activated carbon as an adsorbent and catalyst

  • Tyagi, Ankit;Das, Susmita;Srivastava, Vimal Chandra
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.474-483
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    • 2019
  • In this study, iron (Fe) impregnated granular activated carbon (Fe-GAC) has been synthesized and characterized for various properties. Comparative studies have been performed for use of Fe-GAC as an adsorbent as well as a catalyst during catalytic oxidation of hydroquinone (HQ). In the batch adsorption study, effect of process parameter like initial HQ concentration ($C_o=25-1,000mg/L$), pH (2-10), contact time (t: 0-24 h), temperature (T: $15-45^{\circ}C$) and adsorbent dose (w: 5-50 g/L) have been studied. Maximum HQ adsorption efficiency of 75% was obtained at optimum parametric condition of: pH = 4, w = 40 g/L and t = 14 h. Pseudo-second order model best-fitted the HQ adsorption kinetics whereas Langmuir model best-represented the isothermal equilibrium behavior. During oxidation studies, effect of various process parameters like initial HQ concentration ($C_o:20-100mg/L$), pH (4-8), oxidant dose ($C_{H2O2}:0.4-1.6mL/L$) and catalyst dose (m: 0.5-1.5 g/L) have been optimized using Taguchi experimental design matrix. Maximum HQ removal efficiency of 83.56% was obtained at optimum condition of $C_o=100mg/L$, pH = 6, $C_{H2O2}=0.4mL/L,$ and m = 1 g/L. Overall use of Fe-GAC during catalytic oxidation seems to be a better as compared to its use an adsorbent for treatment of HQ bearing wastewater.

Relationship between saliva and blood cortisol in handled cows

  • Dzviti, Melody;Mapfumo, Lizwell;Muchenje, Voster
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.5
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    • pp.734-741
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    • 2019
  • Objective: The objective of the study was to determine the relationship between plasma and salivary cortisol concentrations in beef cattle that were subjected to handling prior to sampling. Methods: Twenty-one Nguni cows of three age categories; 5 to 7 yr (n = 7), 8 to 10 yr (n = 6), and 11 to 13 yr (n = 8) were handled for five consecutive weeks. In the pen, a human avoidance test was performed and cattle responses to restraint in the chute and crush were observed. In addition, rectal temperature readings were taken and, faecal samples were collected and analysed for glucocorticoid metabolites. Through the handling and restraint process, excretory and vocalisation behaviour, as a sign of stress were observed and recorded. Thereafter, six cows were randomly selected and subjected to an adrenocorticotropic hormone (ACTH) challenge. Blood and saliva samples were extracted to determine cortisol concentrations. Results: Repeated handling affected (p<0.05) faecal glucocorticoid metabolites, rectal temperatures, avoidance distance, crush scores as well as urination and defaecation behaviour. Acclimation to handling was variable based on each respective parameter. Saliva cortisol concentrations increased and decreased significantly (p<0.001). A peak value of $136.78{\pm}15.869nmol/L$ was observed 30min after administration of ACTH, from a baseline value of $8.75{\pm}15.869nmol/L$. Plasma cortisol concentrations did not differ (p>0.05) across the time of sampling. A low and insignificant correlation (r = 0.0131, p>0.05) between plasma and saliva cortisol was therefore observed. Conclusion: We conclude that if beef cows are subjected to handling prior to sampling, a weak relationship exists between plasma and salivary cortisol levels.

A quasi 3D solution for thermodynamic response of FG sandwich plates lying on variable elastic foundation with arbitrary boundary conditions

  • Bouiadjra, Rabbab Bachir;Mahmoudi, Abdelkader;Sekkal, Mohamed;Benyoucef, Samir;Selim, Mahmoud M.;Tounsi, Abdelouahed;Hussain, Muzamal
    • Steel and Composite Structures
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    • v.41 no.6
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    • pp.873-886
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    • 2021
  • In this paper, an analytical solution for thermodynamic response of functionally graded (FG) sandwich plates resting on variable elastic foundation is performed by using a quasi 3D shear deformation plate theory. The displacement field used in the present study contains undetermined integral terms and involves only four unknown functions with including stretching effect. The FG sandwich plate is considered to be subject to a time harmonic sinusoidal temperature field across its thickness with any combined boundary conditions. Equations of motion are derived from Hamilton's principle. The numerical results are compared with the existing results of quasi-3D shear deformation theories and an excellent agreement is observed. Several numerical examples for fundamental frequency, deflection, stress and variable elastic foundation parameter's analysis of FG sandwich plates are presented and discussed considering different material gradients, layer thickness ratios, thickness-to-length ratios and boundary conditions. The results of the present study reveal that the nature of the elastic foundation, the boundary conditions and the thermodynamic loading affect the response of the FG plate especially in the case of a thick plate.

Comparison of Ventral Midline and Right Flank Approaches of Ovariohysterectomy in Bitches

  • Ishwor Dhakal;Bharata Regmi;Bablu Thakur;Ishwari Tiwari;Shraddha Tiwari;Yeonsu Oh;Manoj K. Shah
    • Journal of Veterinary Clinics
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    • v.40 no.1
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    • pp.25-30
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    • 2023
  • The ventral midline approach (VMA) and right flank approach (RFA) are common procedures for the sterilization of bitches. This study compared the different parameters viz. total duration of surgery, recovery time, and length of the incision as well as body temperature, heart rate, respiration rate, and SpO2 in each approach. Twenty (20) bitches were divided randomly for the RFA and VMA. Meloxicam (0.2 mg/kg) was administered subcutaneously half an hour before the induction to provide preemptive analgesia. Diazepam and ketamine were administered intravenously at dose rates of 0.25 mg/kg and 2.5 mg/kg, and 0.17 mg/kg and 3.33 mg/kg, respectively to produce and maintain anesthesia. Each parameter was recorded at the pre-operative, operative and post-operative times. The average duration of surgery and length of incision of RFA (16.1 ± 5.13 min and 2.44 ± 0.83 cm) were significantly lower (p < 0.05) than the VMA (21.3 ± 5.48 min and 3.53 ± 0.7 cm). The operated bitches showed hypothermia (p < 0.05) at 1 hour compared to baseline and 24 hours of surgery. Heart and respiration rates increased significantly (p < 0.05) during traction and severing of ovarian ligaments in bitches within the RFA group, but there was no significant difference within VMA approaches. The sedation score was significantly higher (p < 0.05) at 1 hour after surgery in both approaches. Based on the duration of surgery and length of incision RFA approach was quick and minimal skin wound. Further studies on bitches considering molecular investigations of surgical stress are imperative.

Hydrogen Embrittlement Properties of SA-723 steel via controlling Gaseous Hydrogen Pre-charging Condition (가스 수소 장입 조건 제어를 통한 SA-723 강의 수소 취화 특성 평가)

  • Kangjin Lee;Jeonghwan Kim;Hwayoung Lee;Dohoon Kim;Soonjik Hong;Gian Song
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.6
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    • pp.382-388
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    • 2023
  • In this study, hydrogen embrittlement (HE) behavior of a SA-723 steel via controlling gaseous hydrogen pre-charging condition has been analyzed. The gaseous hydrogen charging of the SA-723 steel was performed under a constant pressure of 20 MPa of gaseous H2 at 150℃ and 300℃ for 2 and 6h, and TDS, SSRT and Charpy tests were conducted to analyze the hydrogen embrittlement (HE) behavior of the SA-723 steel. Furthermore, prior to commencing the test, these specimens were coated with Zn to prevent hydrogen from diffusing out of a specimen during the tests. The TDS results showed that the 300℃-6h and 150℃-6h charged steels contain larger amounts of hydrogen than 300℃-2h and 150℃-2h charged steel. The SSRT and Charpy test results also showed the similar trends that the mechanical properties of the steels deteriorate as the amount of hydrogen charged in the steel increases. Therefore, this study suggests that, for SA-723 steel, the charging time parameter is more effective to charge more amount of hydrogen into SA-723 steel, rather than the charging temperature.

High purity C3A synthesis method and effect of CaCO3 on C3A initial hydration reaction (고순도 C3A 합성 방법 및 CaCO3가 C3A 초기 수화 반응에 미치는 영향)

  • Hye-Jin Yu;Woo Sung Yum
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.6
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    • pp.244-249
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    • 2023
  • In this study, various experimental parameters were investigated for high-purity C3A synthesis. As a results of experiment, it was verified that the calcined temperature was the most important parameter for the synthesis of high-purity C3A. In addition, more synthesis time was needed when large amount of C3A synthesis to achieve high-purity. Meanwhile, the C3A blended with CaCO3 showed different reaction products compared to normal cement because C15 and C30 had monocarbocaluminate as a reaction product at early stage of hydration. Furthermore, the production amount and formation rate of monocarboaluminate formation was different varying with the CaCO3 a mounts.