• 제목/요약/키워드: TiO2-CeO2

검색결과 146건 처리시간 0.027초

$Nd_2O_3$ 함유 유리의 X-선조사에 따른 변색에 관한 연구 (A Study on the Coloration of the $Nd_2O_3$ Containing Glass by X-ray Irradiation)

  • 박용원;강원호
    • 한국세라믹학회지
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    • 제21권4호
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    • pp.373-381
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    • 1984
  • The coloration of the $Nd_2O_3$ contained $R_2O-BaO-SrO-ZrO_2-SiO_2$ glass added the various amount of $CeO_2$ $MnO_2$, $Fe_2O_3$ and $As_2O_3$ alone or together by the irradiation of X-ray irradiation,. The glasses added $CeO_2$ in proportion to amount were more effective on preventing coloration by X-ray irradiation but the addition of $MnO_2$ produced different color according to the amount of addition. The addition of the $Fe_2O_3$, $TiO_2$ and $As_2O_3$ did not give much effects to the transmission changes of $Nd_2O_3$ contained glass by X-ray irradiation but the glass added $CeO_2$ , $Fe_2O_3$, $TiO_2$ together was most effective to prevent coloration and transmisson changes.

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$Pt/Bi_{3.25}La_{0.75}Ti_3O_{12}/CeO_2/Si$ 구조를 이용한 MFISFET의 구조 및 전기적 특성 (Structural and electrical properties of MFISFET using a $Pt/Bi_{3.25}La_{0.75}Ti_3O_{12}/CeO_2/Si$ structure)

  • 김경태;김창일;이철인;김태형
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.183-186
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    • 2004
  • The metal-ferroelectric-insulator-semiconductor(MFIS) capacitors were fabricated using a metalorganic decomposition (MOD)method. The $CeO_2$ thin films were deposited as a buffer layer on Si substrate and $Bi_{3.25}La_{0.75}Ti_3O_{12}$ (BLT) thin films were used as a ferroelectric layer. The electrical and structural properties of the MFIS structure were investigated by varying the $CeO_2$ layer thickness. The width of the memory window in the capacitance-voltage (C-V)curves for the MFIS structure decreased with increasing thickness of the $CeO_2$ layer. Auger electron spectroscopy (AES) and transmission electron microscopy (TEM) show no interdiffusion by using the $CeO_2$ film as buffer layer between the BLT film and Si substrate. The experimental results show that the BLT-based MFIS structure is suitable for non-volatile memory field-effect-transistors (FETs) with large memory window.

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RF 마그네트론 스퍼터링법으로 성장시킨 0.5 % Ce-doped Ba($Zr_{0.2}Ti_{0.8}$)$O_3$(BCZT) 박막의 특성분석 (Characterization of 0.5 % Ce-doped Ba($Zr_{0.2}Ti_{0.8}$)$O_3$ Thin Films Grown by RF Magnetron Sputtering Method)

  • 최원석;박용섭;이준신;홍병유
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.301-304
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    • 2002
  • We investigated the structural and electrical properties of Ce-doped Ba($Zr_{0.2}Ti_{0.8}$)$O_3$(BCZT) thin films with a mole fraction of x=0.2 and a thickness about 100 nm. BCZT films were prepared on Pt/Ti/$SiO_2$/Si substrate by a RF magnetron sputtering system. We have measured the thickness profile with Ar/$O_2$ ratio and the surface roughness. It was observed that the oxygen gas, which introduced during the film deposition, have an influence on the roughness of the film and the film roughness was reduced by annealing from 2.33 nm to 2.02 m (RMS at $500^{\circ}C$, Ar:6 scrim, $O_2$:6 sccm). We have found that annealing procedure after top electrode deposit can reduce the dissipation factor.

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Pulsed laser deposition 방법으로 증착된 $(Bi,Ce)_4Ti_3O_{12}$ 박막의 강유전 특성 (Characteristic of ferroelectric properties of $(Bi,Ce)_4Ti_3O_{12}$ thin films deposited by pulsed laser deposition)

  • 오영남;성낙진;윤순길;전민구;우성일;김창수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.168-171
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    • 2003
  • Bismuth layered structure, Cerium-substituted $Bi_4Ti_3O_{12}$ ($(Bi,Ce)_4Ti_3O_{12}$) thin films were prepared on the $Pt/TiO_2/SiO_2/Si$ substrates by the pulsed laser deposition method. We investigated the Ce-subsitituted effect on the grain orientation and ferroelectric properties. $Ce^{3+}$ ion substitution for $Bi^{3+}$ ion in perovskite layers of BTO decreased the deeree of c-axis orientation and increased the remanent polariation (2Pr). The structure and morphology of the films were characterized using X-ray diffraction and atomic force microscopy. The $(Bi,Ce)_4Ti_3O_{12}$ (BCT) thin films, which were annealed $700^{\circ}C\;and\;800^{\circ}C$ for 10min and 30min, showed a perovskite phase and dense microstructure. As the thickness of the BCT film was decresed that the ferroelectric properties of the BCT thin films were good.

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RF 마그네트론 스퍼터링법으로 성장시킨 0.5% Ce-doped Ba(Zr0.2Ti0.8)O3 (BCZT) 박막의 열처리 특성분석 (Characterization of the Annealing Effect of 0.5 % Ce-doped Ba(Zr0.2Ti0.8)O3 Thin Films Grown by Rf Magnetron Sputtering Method)

  • 최원석;박용섭;이준신;홍병유
    • 한국전기전자재료학회논문지
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    • 제16권5호
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    • pp.361-364
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    • 2003
  • It was investigated that the structural and electrical Properties of Ce-doped Ba(Zr$_{x}$Ti$_{1-x}$ )O$_3$ (BCZT) thin films with a mole fraction of x=0.2 and a thickness about 100 nm. BCZT films were prepared on Pt/Ti/SiO$_2$/Si substrate by a RF magnetron sputtering system. We have measured the thickness profile with Ar/O$_2$ ratio and the surface roughness. It was observed that the oxygen gas, which introduced during the film deposition, have an influence on the roughness of the film and the film roughness was reduced by annealing from 2.33 nm to 2.02 nm (RMS at 500 $^{\circ}C$, Ar:6 sccm, $O_2$:6 sccm). It was found that annealing procedure after top electrode deposit can reduce the dissipation factor.

$MnO_2$ 첨가에 따른 (Pb)(La,Ce)$TiO_3$ 세라믹스의 미세구조특성 (Microstructural Properties of (Pb)(La,Ce)$TiO_3$ ceramics as a function of $MnO_2$ addition)

  • 오동언;민석규;윤광희;류주현;박창엽
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.442-445
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    • 2001
  • In this study, microstructural and dielectric properties of $Pb_{0.83}(La_{0.2}Ce_{0.8})_{0.08}TiO_3$(PCT) ceramics as a function of $MnO_2$ addition were investigated for 30MHz ceramic resonator application. Grain size was gradually increased according to the increase of $MnO_2$ addition amount and showed the highest value of $1.502{\mu}m$ at the 0.9wt% $MnO_2$. Moreover, density showed the highest value of $7.582 g/cm^3$ at the 0.7wt% $MnO_2$.All the composition ceramics,curie temperature was nearly constant around $330^{\circ}C$

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화염분무열분해법을 이용한 이산화세륨 나노분말 제조 (Preparation of CeO2 Nanoparticles using Flame Spray Pyrolysis)

  • 김선경;박수련;장한권;장희동
    • 한국입자에어로졸학회지
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    • 제12권2호
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    • pp.37-42
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    • 2016
  • $CeO_2$ nanoparticles were prepared by a flame spray pyrolysis from aqueous solution of cerium nitrate. The morphology, structure crystallinity and specific surface area of as-prepared nanoparticles were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and Brunauer-Emmett-Telle (BET). The $CeO_2$ nanoparticles about 5 nm in diameter showed a cubic fluorite structure and polyhedral morphology. The average particle size increased as the cerium nitrate concentration increased. UV absorption performance of the as-prepared nanoparticles was measured by UV-visible spectroscopy. UV absorption of $CeO_2$ nanoparticles was more effective than that of commercial $TiO_2$ nanoparticles. Effect of dopants such as Ti and Zn to $CeO_2$ nanoparticles on UV absorption properties was also investigated. In case of $Ti/CeO_2$, and $Zn/CeO_2$ nanoparticles, they showed a little higher UV absorption values compared with $CeO_2$ nanoparticles. The as-prepared nanoparticles can be promising materials with high UV absorption value.

Comparison of structural and electrical properties of PMN-PT/LSCO thin films deposited on different substrates by pulsed laser deposition

  • ;;윤순길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.214-214
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    • 2010
  • The 0.65Pb($Mg_{1/3}Nb_{2/3})O_3-0.35PbTiO_3$ (PMN-PT) thin films with $La_{0.5}Sr_{0.5}CoO_{3-\delta}$ (LSCO) bottom electrodes were grown on $CeO_2$/YSZ/Si(001), Pt/$TiO_2$/Si and $SrTiO_3$ (STO) substrates using conventional pulsed laser deposition (PLD) at a substrate temperature of $550^{\circ}C$. Since generally the crystallographic orientation of the bottom electrode induces the orientation of the films deposited on it, it allows us to observe the influence of the PMN-PT film orientation on the electrical properties. Phi scan done on PMN-PT/LSCO thin films shows epitaxial behavior of the films grown on sto substrates and $CeO_2$/YSZ buffered Si(001) substrates, and (110) texture on Pt/$TiO_2$/Si substrates. Polarization-electricfield (P-E) measurement shows good hysteresis behavior of PMN-PT films with remnant polarization of 18.2, 8.8, and $4.4{\mu}C/cm^2$ on $CeO_2$/YSZ/Si, Pt/TiO2/Si and STO substrates respectively.

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Cerium이 첨가된 $Bi_4Ti_3O_{12}$ 강유전체 박막의 구조적 특성 (The Structural Properties of $Bi_4Ti_3O_{12}$ Ferroelectric Thin Films doped with Cerium)

  • 한상욱;남성필;이성갑;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.236-237
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    • 2005
  • The structural properties of $(Bi,Ce)_4Ti_3O_{12}(BCT)$ thin films with post-annealing temperature were investigated. $(Bi,Ce)_4Ti_3O_{12}(BCT)$ thin films were deposited by RF sputtering method on Pt/Ti/$SiO_2$/Si substrates with optimum deposition condition. The $(Bi,Ce)_4Ti_3O_{12}(BCT)$ thin films was post-annealed at 600$^{\circ}C$, 650$^{\circ}C$, 700$^{\circ}C$, 750$^{\circ}C$, 800$^{\circ}C$ in furnace,respectively. Increasing the post-annealing temperature, the grain size, density and peak intensity of (117) and c-axis orientation were increased. The $(Bi,Ce)_4Ti_3O_{12}(BCT)$ thin films that annealed at 750$^{\circ}C$ exhibited well crystallized phase and had no vacancy and grain was uniform. but there are some secondary phases observed. At this time, the average thickness of $(Bi,Ce)_4Ti_3O_{12}(BCT)$ thin films was 2000 ${\AA}$.

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