• 대한화학회지
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• 제66권3호
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• pp.209-217
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• 2022

본 연구그룹에서는 투명 전도성 기판이 필요 없는 광감응형 전기변색 소자를 개발하였다. 이전의 연구에서 백금 촉매 적용에 의한 빠른 착색 및 탈색을 확인하였고, 저온소성형 WO₃졸과 TiO₂ 졸을 적용하여 플렉시블 필름형 소자를 구현하였으나, 이러한 소자가 4~5 시간 동안 태양광에 노출될 경우 과착색 되어 암막상태에서도 탈색이 되지 않는 현상을 확인하였다. 본 연구에서는 이러한 과착색 현상을 해결하기 위하여 광감응형 전기변색 소자의 전해질에(4-Hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPOL)을 첨가하였다. TEMPOL을 첨가제로 사용한 광감응형 전기변색 소자의 경우 4시간 이상 햇빛에 노출되어도 과착색이 되지 않고, 가역성이 크게 향상되는 것을 확인하였다. 다양한 농도의 TEMPOL을 적용하여 가시광 투과율 변화 및 착/탈색 속도를 비교하였고, 에너지 레벨 관점에서 가능한 TEMPOL의 과착색 방지 메커니즘을 제시하였다.

• 한국수산과학회지
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• 제23권4호
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• pp.280-288
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• 1990

마른 김의 배소(焙燒) 및 배소김의 저장중에 일어나는 색소(chlorophyll a, carotenoid 및 biliprotein). Trypsin Tndigestible Substrate(TIS) 및 dietary fiber 등 성분들의 변화를 측정하고 색소단백, TIS 및 소화율과의 관계를 고찰한 결과를 요약하면 다음과 같다 1. 마른김을 $50,\;70,\;90,\;100,\;120^{\circ}C$ 에서 각각 1시간 가열처리하였을 때 chlorophyll a와 carotenoid는 비교적 안정하여 $120^{\circ}C$ 에서도 $85\%$이상의 잔존량을 보였다. 그러나 biliprotein은 매우 불안정하여 $70^{\circ}C$에서 $60\%$ $100\~120^{\circ}C$에서는 $20\~10\%$의 잔존량에 불과하였다. Chlorophyll a는 carotenoid보다 다소 안정하였고 biliprotein 색소중에서는 phycoerythrin보다 phycocyanin이 더 불안정하였다. 2. TIS는 열에 대하여 비교적 안정하였는데 $100^{\circ}C$ 이상에서 $10\%$감소하였고 소화율은 대조시료가 $80\%,\;100^{\circ}C$ 처리시료에서는 $85\%$로 증가하였다. TIS의 감소와 소화율의 증가는 색소 단백의 감소와 상관관계를 보였다. 3. 열처리중에 insoluble dietary fiber(IDF)가 다소 감소하는 경향을 보였으나 온도별 영향은 크지 않은 반면에 soluble dietary fiber(SDF)는 열처리 온도가 높을수록 다소 증가하는 경향을 보였다. 4. 배소김을 실온에서 20주간 저장하였을 때 chalorophyll a는 aw 0.65의 경우 약 $20\%$ aw 0.1에서는 $75\%$이상, carotenoid의 경우 aw 0.1일때 $40\%$, aw 0.65일 때 $2\%$ 정도와 잔존량을 보여 저장중 크게 감소하는 반면, biliprotein 색소는 안정하였다. 5. 저장중 TIS는 aw 0.65일 때 $15\%$ 정도가 감소하였고 같은 조건에서 소화율은 $92\%$로 증가하여 TIS와 소화율과의 관계를 나타내었고 SDF는 점차 증가하여 12주 경부터 상당한 변화를 보였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.287.1-287.1
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• 2016

Three-dimensional (3-D) semiconductor nanoarchitectures, including nano- and micro- rods, pyramids, and disks, are emerging as one of the most promising elements for future optoelectronic devices. Since these 3-D semiconductor nanoarchitectures have many interesting unconventional properties, including the use of large light-emitting surface area and semipolar/nonpolar nano- or micro-facets, numerous studies reported on novel device applications of these 3-D nanoarchitectures. In particular, 3-D nanoarchitecture devices can have noticeably different current spreading characteristics compared with conventional thin film devices, due to their elaborate 3-D geometry. Utilizing this feature in a highly controlled manner, color-tunable light-emitting diodes (LEDs) were demonstrated by controlling the spatial distribution of current density over the multifaceted GaN LEDs. Meanwhile, for the fabrication of high brightness, single color emitting LEDs or laser diodes, uniform and high density of electrical current must be injected into the entire active layers of the nanoarchitecture devices. Here, we report on a new device structure to inject uniform and high density of electrical current through the 3-D semiconductor nanoarchitecture LEDs using metal core inside microtube LEDs. In this work, we report the fabrications and characteristics of metal-cored coaxial $GaN/In_xGa_{1-x}N$ microtube LEDs. For the fabrication of metal-cored microtube LEDs, $GaN/In_xGa_{1-x}N/ZnO$ coaxial microtube LED arrays grown on an n-GaN/c-Al2O3 substrate were lifted-off from the substrate by wet chemical etching of sacrificial ZnO microtubes and $SiO_2$ layer. The chemically lifted-off layer of LEDs were then stamped upside down on another supporting substrates. Subsequently, Ti/Au and indium tin oxide were deposited on the inner shells of microtubes, forming n-type electrodes of the metal-cored LEDs. The device characteristics were investigated measuring electroluminescence and current-voltage characteristic curves and analyzed by computational modeling of current spreading characteristics.

• 한국식품영양과학회지
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• 제14권1호
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• pp.1-12
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• 1985

가열 및 동결저장이 오징어, 굴, 새우 및 명태의 in vitro 소화율과 trypsin indigestible substrate (TIS) 함량 변화에 미치는 영향을 실험한 결과는 다음과 같다. Boiling 했을 때 최고의 운 in vitro 소화율을 나타내는 시간은 오징어 1분, 내장을 제거한 굴 0.5분, 내장을 제거하지 않은 굴은 1분이었고, 명태는 5분 이었으며, 오징어와 굴은 부위에 따라 소화율은 다르게 나타났다. 최고의 in vitro 소화율을 나타내는 steaming 조건은 오징어는 $100^{\circ}C$에서 1분, 굴은 $88^{\circ}C$에서 1분이었으며, 명태는 $100^{\circ}C$에서 $1{\sim}2.5$분이었다. TIS는 진시료에서 in vitro 소화율과 역상관관계를 가지며 변화하였다. 동결건조한 시료가 다른 건조품보다 현저하게 높은 in vitro 소화율을 보였으나, 내장을 제거했거나 지방함량이 낮은 시료를 천일건조했을 때도 동결건조시료에 버금가는 in vitro 소화율을 나타내었다. 동결저장은 지방함량이 낮은 시료의 in vitro 소화율의 저하 및 TIS함량 증가에 효과적이었으나, 지방함량이 높아 산패가 심하게 진행된 시료에는 현저한 효과를 볼 수 없었다. 지방함량은 수산식품단백질을 가열처리했거나 저장했을 때의 소화율 변화에 결정적인 영향을 미침을 알 수 있었으며, 4가지의 효소를 이용한 multi-enzyme digestion technique은 수산식품단백질의 소화율 변화를 측정함에 있어 아주 민감하고 유용한 방법으로 판명되었다.

• Progress in Superconductivity
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• 제5권1호
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• pp.50-54
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• 2003

We have fabricated $∂^2$$B_{z}$ /$∂x^2$ type planar gradiometers and studied their properties in operation under various field conditions. $YBa_2$$Cu_3$$O_{7}$ film was deposited on $SrTiO_3$ (100) substrate by a pulsed laser deposition (PLD) system and patterned into a device by the photolithography with ion milling technique. The device consists of 3 pickup loops designed symmetrically Inner dimension and the width of the square side loops are 3.6 mm and 1.2 mm, respectively, and the corresponding dimensions of the center loop are 2.0 mm and 1.13 mm. The length of baseline gradiometer is 5.8 mm. Step-edge junction width is 3.0 $\mu\textrm{m}$ and the hole size of the SQUID loop is 3 $\mu\textrm{m}$ ${\times}$ 52 $\mu\textrm{m}$. The SQUID inductance is estimated to be 35 pH. The device was formed on a 20 mm ${\times}$ 10 mm substrate. We have tested the behavior of the device in various field conditions. The unshielded gradiometer was stable under extremely hostile conditions on a laboratory bench. Noise level 0.45 pT/$\textrm{cm}^2$/(equation omitted)Hz and 0.84 pT/$\textrm{cm}^2$/(equation omitted)Hz at 1 Hz for the shielded and the unshielded cases, which correspond to equivalent field noises of 150 fT/(equation omitted)Hz and 280 fT/(equation omitted)Hz, respectively. In spite of the short baseline of 5.8 mm, the high common-mode-rejection-ratio of the gradiometer, $10^3$, allowed us to successfully record magnetocardiogram of a human subject, which demonstrates the feasibility of the design in biomagnetic studies.

• Korean Chemical Engineering Research
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• 제54권2호
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• pp.157-162
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• 2016

다공성 $Co(OH)_2$ 나노플레이크 박막은 전위제어 전착법을 이용하여 티타늄 메쉬에 여러 전착전위(-0.75, -1.0, -1.2 및 -1.4 V)에서 전착하여 슈퍼커패시터에 이용하였다. 티타늄 메쉬에 전착된 $Co(OH)_2$ 나노플레이크 박막의 두께 및 전착량은 전착전위의 제어에 의해 결정되었고 -1.4 V에서 전착한 $Co(OH)_2$ 나노플레이크 박막의 두께는 약 $34{\mu}m$로 가장 두껍게 전착되었으며 전착량은 17.2 g이다. 전착전위 -0.75, -1.0, -1.2 및 -1.4 V에서 전착한 경우 초기 방전용량은 각각 226, 370, 720 그리고 $1,008mF\;cm^{-2}$으로 나타났고 1,000 사이클 후 각각 206, 349, 586 그리고 $866mF\;cm^{-2}$으로 나타났다. 또한 이들의 용량유지율은 각각 91, 94, 81 및 86%로 나타났다.

• 센서학회지
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• 제23권6호
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• pp.420-424
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• 2014

Aluminum-scandium nitride ($Al_{1-x}Sc_xN$) thin films with a TiN buffer layer have been fabricated on SUS430 substrate by RF reactive magnetron sputtering at room temperature under 50% $N_2$/Ar. The effect of Sc-doping on the structure and piezoelectric properties of AlN films has been investigated using SEM, XRD, surface profiler and pressure-voltage measurements. The as-deposited AlN films showed polycrystalline phase, and the Sc-doped AlN film, the peak of AlN (002) plane and the crystallinity became very strong. With Sc-doping, the crystal size of AlN film was grown from ~20 nm to ~100 nm. The output signal voltage of AlN sensor showed a linear behavior between 15~65 mV, and output signal voltage of Sc-doped AlN sensor was increased over 7 times. The pressure-sensing sensitivity of AlN film was calculated about 10.6mV/MPa, and $Al_{0.88}Sc_{0.12}N$ film was calculated about 76 mV/MPa.

• 한국재료학회지
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• 제19권11호
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• pp.601-606
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• 2009

$BiFeO_3$ (BFO) thin films were prepared on $Pt/TiO_2/Si$ substrate by r.f. magnetron sputtering. The effects of deposition pressure on electrical properties were investigated using measurement of dielectric properties, leakage current and polarization. When BFO targets were prepared, Fe atoms were substituted with Mn 0.05% to increase electrical resistivity of films. (Fe+Mn)/Bi ratio of BFO thin films increases with increasing partial pressure of $O_2$ gas. The deposited films showed the only BFO phase at 10 mTorr, the coexistence of BFO and $Bi_2O_3$ phase at 30-50 mTorr, and the only $Bi_2O_3$ phase at 70 mTorr. The crystallinity of BFO films was reduced due to the higher Bi contents and the decrease of surface mobility of atoms at high temperature. The porosity and surface roughness of films increased with the increase of the deposition pressure. The films deposited at high pressure showed low dielectric constant and high leakage current. The dielectric constant of films deposited at various deposition pressures was 84${\sim}$153 at 1 kHz. The leakage current density of the films deposited at 10${\sim}$70 mTorr was about $7{\times}10.6{\sim}1.5{\times}10.2A/cm^2$ at 100 kV/cm. The leakage current was found to be closely related to the morphology and composition of the BFO films. BFO films showed poor P-E hysteresis loops due to high leakage current.

• 한국대기환경학회지
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• 제13권6호
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• pp.487-495
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• 1997

The most desirable diesel oxidation catalyst (DOC) should have the properties of oxidizing CO, HC and SOF effectively at low exhaust gas temperature while minimizing the formation of sulfate at high exhaust gas temperature. Precious metals such as platinum and palladium have been known to be sufficiently active for oxidizing SOF and also to have high activity for the oxidation of sulfur dioxide $(SO_2)$ to sulfur trioxide $(SO_3)$. There is a need to develop a highly selective catalyst which can promote the oxidation SOF efficiently, on the other hand, suppress the oxidation of $SO_2$. In this study, a Pt-V catalyst was prepared by impregnating platinum and vanadium onto a Ti-Si wash coated ceramic monolith substrate. A prepared Pt-V catalytic converter was installed on a heavy duty diesel engine and the effect of fuel sulfur on particulate matter (PM) of heavy duty diesel engine was measured. The effect of fuel sulfur on PM of Pt-V was also compared with that of a commercialized Pt catalyst currently being used in some of the heavy duty diesel engines in advanced countries. Only 1 $\sim$ 3% of sulfur in the diesel fuel was converted to sulfate in PM for the engine without catalyst, but almost 100% of sulfur conversion was achieved for the engine with Pt catalyst at maximum loading condition. In the case of Pt-V catalyst, there was no big difference in conversion with the base engine even at maximum loading condition. The reason of SOF increase according to the increase of suflate emission was identified as the washing off effect of bound water in sulfate.

• 한국세라믹학회지
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• 제43권2호
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• pp.106-113
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• 2006

PMN-PZT films with thickness of $5\;{\mu}m$ were deposited on $Pt/Ti/SiO_2/Si$ substrate at room temperature using aerosol deposition process. The films showed fairly dense microstructure without any crack. XRD and TEM analysis revealed that the films consisted of randomly oriented nanocrystalline and amorphous phases. Post-annealing process was employed to induce crystallization and grain growth of the as-deposited films and to improve the electrical properties. The annealed film showed markedly improved electrical properties in comparison with as-deposited film. The film after annealing at $700^{\circ}C$ for 1h exhibited the best electrical properties. Dielectric constant $(\varepsilon_r)$, remanent polarization $(P_r)$ and piezoelectric constant $(d_{33})$ were 1050, $13\;{\mu}C/cm^2$ and 120 pC/N, respectively.