• Title/Summary/Keyword: TMC

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Study on the hydrophobic modification of zirconia surface for organic-inorganic hybrid coatings (유-무기 하이브리드 코팅액 제조를 위한 지르코니아 표면의 소수화 개질 연구)

  • Lee, Soo;Moon, Sung Jin;Park, Jung Ju
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.260-270
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    • 2017
  • Zirconia has white color and physical, chemical stability, also using in high temperature materials and various industrial structural ceramics such as heat insulating materials and refractories due to their low thermal conductivity, excellent strength, toughness, and corrosion resistance. If hydrophobically modified zirconia is introduced into a hydrophobic acrylate coating solution, the hardness, chemical, electrical, and optical properties will be improved due to the better dispersibility of inorganic particle in organic coating media. Thus, we introduced $-CH_3$ group through silylation reaction using either trimethylchlorosilane(TMCS) or hexamethyldisilazane(HMDZ) on zirconia surface. The $Si-CH_3$ peaks derived from TMCS and HMDZ on hydrophobically modified zirconia surface was confirmed by FT-IR ATR spectroscopy, and introduction of silicon was confirmed by FE-SEM/EDS and ICP-AES. In addition, the sedimentation rate result in acrylate monomer of the modified zirconia showed the improved dispersibility. Comparison of the sizes of a pristine and the modified zirconia particles, which were clearly measured not by the normal microscope but by particle size analysis, provided a pulverizing was occurred by physical force during the silylation process. From the BET analysis data, the specific surface area of zirconia was approximately $18m^2/g$ and did not significantly change during modification process.

Effects of Injection of Red Wine on Physico-chemical Characteristics of Pork Loin Ham (레드와인 주입량에 따른 등심햄의 품질 특성)

  • Ha, So-Ra;Choi, Jung-Seok;Jin, Sang-Keun
    • Journal of Life Science
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    • v.25 no.10
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    • pp.1139-1147
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    • 2015
  • This study was conducted to evaluate the effects of injection of red wine on physico-chemical characteristics of pork loin ham during cold storage. The pork loin hams were manufactured by injection of red wine as Control (0%), T1 (3%), T2 (6%), T3 (9%), and were analyzed, while stored at 10±1℃ for 4 weeks, respectively. As a result of the injection of red wine, the pH values of pork loin ham were reduced, whereas WHC values were increased compared to the control (p<0.05). However, there was no significant difference in cooking loss. In meat color, as injection of red wine increased, the lightness values were reduced, and redness values were increased during 4 weeks. In texture profile analysis, values in shear force, brittleness, gumminess and adhesiveness were increased as red wine injection increased (p<0.05). But, injection of red wine reduced the VBN values until 2 weeks. Treatment groups with more than 3% red wine showed lower TMC values than control until 3 weeks (p<0.05), whereas Lactobacillus counts were significantly increased by injection of red wine since 2 weeks. In conclusion, red wines showed the effect of increasing the quality characteristics related to physical and storage in pork loin ham during cold storage, and proper injection level was 3% when pork loin ham processed.

The Prediction of the Expected Current Selection Coefficient of Single Nucleotide Polymorphism Associated with Holstein Milk Yield, Fat and Protein Contents

  • Lee, Young-Sup;Shin, Donghyun;Lee, Wonseok;Taye, Mengistie;Cho, Kwanghyun;Park, Kyoung-Do;Kim, Heebal
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.1
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    • pp.36-42
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    • 2016
  • Milk-related traits (milk yield, fat and protein) have been crucial to selection of Holstein. It is essential to find the current selection trends of Holstein. Despite this, uncovering the current trends of selection have been ignored in previous studies. We suggest a new formula to detect the current selection trends based on single nucleotide polymorphisms (SNP). This suggestion is based on the best linear unbiased prediction (BLUP) and the Fisher's fundamental theorem of natural selection both of which are trait-dependent. Fisher's theorem links the additive genetic variance to the selection coefficient. For Holstein milk production traits, we estimated the additive genetic variance using SNP effect from BLUP and selection coefficients based on genetic variance to search highly selective SNPs. Through these processes, we identified significantly selective SNPs. The number of genes containing highly selective SNPs with p-value <0.01 (nearly top 1% SNPs) in all traits and p-value <0.001 (nearly top 0.1%) in any traits was 14. They are phosphodiesterase 4B (PDE4B), serine/threonine kinase 40 (STK40), collagen, type XI, alpha 1 (COL11A1), ephrin-A1 (EFNA1), netrin 4 (NTN4), neuron specific gene family member 1 (NSG1), estrogen receptor 1 (ESR1), neurexin 3 (NRXN3), spectrin, beta, non-erythrocytic 1 (SPTBN1), ADP-ribosylation factor interacting protein 1 (ARFIP1), mutL homolog 1 (MLH1), transmembrane channel-like 7 (TMC7), carboxypeptidase X, member 2 (CPXM2) and ADAM metallopeptidase domain 12 (ADAM12). These genes may be important for future artificial selection trends. Also, we found that the SNP effect predicted from BLUP was the key factor to determine the expected current selection coefficient of SNP. Under Hardy-Weinberg equilibrium of SNP markers in current generation, the selection coefficient is equivalent to $2^*SNP$ effect.

Sequence Analysis and Expression of the VP7 Gene of G1 Rotavirus Isolated from an Infant in Korean (한국인 영아에서 분리된 G1 로타바이러스의 VP7 단백 유전자 염기서열 및 발현)

  • Kim, Won-Yong;Song, Mi-Ok;Park, Chul-Min;Im, Sung-Joon;Kim, Ki-Jung;Chung, Sang-In;Choi, Chul-Soon;Lim, In-Seok
    • The Journal of Korean Society of Virology
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    • v.28 no.3
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    • pp.247-265
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    • 1998
  • To determine the sequence and expression of the VP7 gene of Korean isolates (CAU-9), viral RNA was purified and used for cDNA amplification by RT-PCR. The VP7 cDNA was cloned, sequenced, and expressed using baculovirus expression system. The result showed that the sequence homologies CAU-9 compared with foreign isolated strains Wa, 417, TMC-II, 95B and SA11 were ranged from 74.0% to 95.1 % of nucleotide sequence and 35% to 43% of amino acid sequence, respectively. High homology of CAU-9 was observed in Japanease isolates 417 (nucleotide sequence homology was 95.1% and amino acid sequence homology was 43%). To express VP7 gene, the VP7 cDNA was cloned into pCR-Bac vector and inserted into the genome of baculovirus adjacent to the polyhedrin promoter by cotransfection of Spodoptera frugiperda (Sf9) insect cells with wild type baculovirus DNA. In antigenic analysis of Sf9 cells inoculated with the recombinant VP7, immunofluorescence assay revealed positive for viral antigens. In metabolic labeling of Sf9 cell lysates infected with recombinant baculoviruses, it was revealed that the protein of 34 kDa was expressed. The limited study of expressed VP7 protein inoculated with guinea pigs failed to elicit neutalizing antibody. As a results, the sequence analysis and expression of VP7 protein of rotavirus CAU-9 isolated from an infant in Korea could permit the conformation and development of virus like particles which may be useful in designing vaccine strategy.

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Simultaneous analysis of ethylene glycol and glycolic acid in bio-specimens by GC/MS (생체시료에서 GC/MS에 의한 에틸렌글리콜 및 대사체인 글리콜산 동시분석)

  • Lee, Joon-Bae;Park, Mee-Jung;Sung, Tae-Myung;Choi, Byung-Ha;You, Jae-Hoon;Shon, Shung-Kun;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.23 no.6
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    • pp.544-550
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    • 2010
  • Mistaking pink colored thermal oil for grape wine, a victim drank the oil to death which was analyzed to contain 39% of ethylene glycol. Thermal oil could be used for heat transfer to prevent the malfunction due to the high pressure in the boiler operated at high temperature when using water. Main component of thermal oil is known to be mineral oil or ethylene glycol. From the blood and other tissue of the victim from autopsy, ethylene glycol and its metabolite were simultaneously analyzed by GC/MS after extraction under acidic condition with acetonitrile followed by derivatization with BSTFA. About 0.2 g of the specimens were pretreated with 50 uL of 0.5 M HCl solution to keep acidic condition, then dehydrated with anhydrous sodium sulfate followed by concentration under nitrogen stream. Ethylene glycol and glycolic acid concentration in blood was measured to be $2,755\;{\mu}g/mL$ and $174\;{\mu}g/mL$ respectively. In other specimen, the concentration of ethylene glycol and glycolic acid was $860\;{\mu}g/g\sim1,290\;{\mu}g/g$ and $93\;{\mu}g/g\sim134\;{\mu}g/g$. Especially, crystal appeared in kidney which was supposed xalate from the metabolite of ethylene glycol.

Change Prediction for Potential Habitats of Warm-temperate Evergreen Broad-leaved Trees in Korea by Climate Change (기후변화에 따른 한반도 난온대 상록활엽수의 잠재 생육지 변화 예측)

  • Yun, Jong-Hak;Nakao, Katsuhiro;Park, Chan-Ho;Lee, Byoung-Yoon;Oh, Kyoung-Hee
    • Korean Journal of Environment and Ecology
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    • v.25 no.4
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    • pp.590-600
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    • 2011
  • The research was carried out for prediction of the potential habitats of warm-temperate evergreen broad-leaved trees under the current climate(1961~1990) and three climate change scenario(2081~2100) (CCCMA-A2, CSIRO-A2 and HADCM3-A2) using classification tree(CT) model. Presence/absence records of warm-temperate evergreen broad-leaved trees were extracted from actual distribution data as response variables, and four climatic variables (warmth index, WI; minimum temperature of the coldest month, TMC; summer precipitation, PRS; and winter precipitation, PRW) were used as predictor variables. Potential habitats(PH) was predicted 28,230$km^2$ under the current climate and 77,140~89,285$km^2$ under the three climate change scenarios. The PH masked by land use(PHLU) was predicted 8,274$km^2$ and the proportion of PHLU within PH was 29.3% under the current climate. The PH masked by land use(PHLU) was predicted 35,177~45,170$km^2$ and increased 26.9~36.9% under the three climate change scenarios. The expansion of warm-temperate evergreen broad-leaved trees by climate change progressed habitat fragmentation by restriction of land use. The habitats increase of warm-temperate evergreen broad-leaved trees had been expected competitive with warm-temperate deciduous broadleaf forest and suggested the expand and northward shift of warm-temperate evergreen broad-leaved forest zone.

Surface Modification of Ba0.6Sr0.4TiO3 by Trimethylsilyl Chloride as a Silylation Agent (Trimethylsilyl Chloride를 Silylation Agent로 사용한 Ba0.6Sr0.4TiO3 나노입자의 표면개질 연구)

  • Lee, Chan;Han, Wooje;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.4
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    • pp.127-132
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    • 2019
  • In this study, barium strontium titanate (BSTO) with high dielectric perovskite structure was synthesized by liquid-solid solution synthesis and the surface was modified using trimethylsilyl chloride (TMCS) as a silylation agent. Silylation surface modification is a method of reacting -OH ligand on the surface of BSTO nanoparticles with Cl in TMCS to generate HCl and replacing the ligand on the surface of nanoparticles with -Si, -CH3. Silylation was optimized by varying the concentration of TMCS, and the structure of the silicon network was confirmed by Fourier-transform infrared spectroscopy. In addition, the crystallinity of BSTO nanoparticles was confirmed by X-ray diffractometer and the size of the nanoparticles was calculated using Scherrer equation. The field emission scanning electron microscopic image observed the change of the surface-modified BSTO particle size, and the contact angle measurement confirmed the hydrophobic property of the contact angle of 120.9° in the optimized nanoparticles. Finally, the surface-modified BSTO dispersion experiment in de-ionized water confirmed the hydrophobic degree of the nanoparticles.

Development of Traffic Safety Monitoring Technique by Detection and Analysis of Hazardous Driving Events in V2X Environment (V2X 환경에서 위험운전이벤트 검지 및 분석을 통한 교통안전 모니터링기법 개발)

  • Jeong, Eunbi;Oh, Cheol;Kang, Kyeongpyo;Kang, Younsoo
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.11 no.6
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    • pp.1-14
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    • 2012
  • Traffic management centers (TMC) collect real-time traffic data from the field and have powerful databases for analysing, recording, and archiving the data. Recent advanced sensor and communication technologies have been widely applied to intelligent transportation systems (ITS). Regarding sensors, various in-vehicle sensors, in addition to global positioning system (GPS) receiver, are capable of providing high resolution data representing vehicle maneuverings. Regarding communication technologies, advanced wireless communication technologies including vehicle-to-vehicle (V2V) and vehicle-to-vehicle infrastructure (V2I), which are generally referred to as V2X, have been widely used for traffic information and operations (references). The V2X environment considers the transportation system as a network in which each element, such as the vehicles, infrastructure, and drivers, communicates and reacts systematically to acquire information without any time and/or place restrictions. This study is motivated by needs of exploiting aforementioned cutting-edge technologies for developing smarter transportation services. The proposed system has been implemented in the field and discussed in this study. The proposed system is expected to be used effectively to support the development of various traffic information control strategies for the purpose of enhancing traffic safety on highways.

Introduction of Acquisition System, Processing System and Distributing Service for Geostationary Ocean Color Imager (GOCI) Data (정지궤도 해색탑재체(GOCI) 데이터의 수신.처리 시스템과 배포 서비스)

  • Yang, Chan-Su;Bae, Sang-Soo;Han, Hee-Jeong;Ahn, Yu-Hwan;Ryu, Joo-Hyung;Han, Tai-Hyun;Yoo, Hong-Rhyong
    • Korean Journal of Remote Sensing
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    • v.26 no.2
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    • pp.263-275
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    • 2010
  • KOSC(Korea Ocean Satellite Center), the primary operational organization for GOCI(Geostationary Ocean Color Imager), was established in KORDI(Korea Ocean Research & Development Institute). For a stable distribution service of GOCI data, various systems were installed at KOSC as follows: GOCI Data Acquisition System, Image Pre-processing System, GOCI Data Processing System, GOCI Data Distribution System, Data Management System, Total Management & Control System and External Data Exchange System. KOSC distributes the GOCI data 8 times to user at 1-hour intervals during the daytime in near-real time according to the distribution policy. Finally, we introduce the KOSC website for users to search, request and download GOCI data.