• 제목/요약/키워드: Surface leakage

검색결과 776건 처리시간 0.03초

Properties Optimization for Perovskite Oxide Thin Films by Formation of Desired Microstructure

  • Liu, Xingzhao;Tao, Bowan;Wu, Chuangui;Zhang, Wanli;Li, Yanrong
    • 한국세라믹학회지
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    • 제43권11호
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    • pp.715-723
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    • 2006
  • Perovskite oxide materials are very important for the electronics industry, because they exhibit promising properties. With an interest in the obvious applications, significant effort has been invested in the growth of highly crystalline epitaxial perovskite oxide thin films in our laboratory. And the desired structure of films was formed to achieve excellent properties. $Y_1Ba_2Cu_3O_{7-x}$ (YBCO) superconducting thin films were simultaneously deposited on both sides of 3 inch wafer by inverted cylindrical sputtering. Values of microwave surface resistance R$_2$ (75 K, 145 GHz, 0 T) smaller than 100 m$\Omega$ were reached over the whole area of YBCO thin films by pre-seeded a self-template layer. For implementation of voltage tunable high-quality varactor, A tri-layer structured SrTiO$_3$ (STO) thin films with different tetragonal distortion degree was prepared in order to simultaneously achieve a large relative capacitance change and a small dielectric loss. Highly a-axis textured $Ba_{0.65}Sr_{0.35}TiO_3$ (BST65/35) thin films was grown on Pt/Ti/SiO$_2$/Si substrate for monolithic bolometers by introducing $Ba_{0.65}Sr_{0.35}RuO_3$ (BSR65/35) thin films as buffer layer. With the buffer layer, the leakage current density of BST65/35 thin films were greatly reduced, and the pyroelectric coefficient of $7.6\times10_{-7}$ C $cm^{-2}$ $K^{-1}$ was achieved at 6 V/$\mu$m bias and room temperature.

재생 냉각용 연소기의 최적 브레이징 조건 (Optimized Brazing Conditions of Regenerative Cooling Thrust Chambers)

  • 남대근;홍석호;한규석
    • 한국항공우주학회지
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    • 제31권7호
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    • pp.112-117
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    • 2003
  • 본 연구에서는 재생 냉각용 연소기에 적용되고 있는 동합금과 2상 스테인리스강의 최적 브레이징 조건을 구하였다. 모재는 C18200 동합금과 S31803 2상 스테인레스강을, 삽입금속으로 두께가 각각 50${\mu}m$, 80${\mu}m$인 AMS4764를 사용하였다. 브레이징한 시제에 대하여 X선 검사, 강도/기밀 및 파괴시험, 파단면 관찰을 한 결과 두께 50${\mu}m$인 삽입금속을 사용한 경우 강도특성과 접합면이 양호함을 확인하였다. 반면 두께 80${\mu}m$인 삽입금속을 사용한 경우는 강도특성은 양호하였으나 냉각유로의 막힘 현상과 유로 확대를 확인하였다.

DAAQ와 SPEEK를 이용한 전고상 슈퍼커패시터의 전기화학적 특성 (Electrochemical Characteristics of all solid supercapacitor based on DAAQ(1,5-diaminoanthraquinone) and SPEEK(sulfonated polyether ether ketone))

  • 김진용;김홍일;김한주;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.371-372
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    • 2005
  • Supercapacitors are promising devices for delivering high power density. Digital communications, electric vehicles and other devices that require electrical energy at high power levels in relatively short pulses have prompted considerable research on supercapacitors. In recent years, solid electrolytes have been investigated for supercapacitors. Solid electrolytes are advantageous over liquid electrolytes in respect of easy handling and reliability without electrolyte leakage. In this preliminary study, an electrochemical supercapacitor in all solid configuration has been fabricated using CNF-DAAQ and poly-vinylidenefluoride(PVdF). A new type of Supercapacitor was constructed by using carbon nanofibers(CNFs) and DAAQ(l,5-diaminoanthraquinone) monomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with $(NH_4)_2S_2O_8$ as oxidant in the 0.1M $H_2SO_4$. Dried SPEEK powder was mixed with N-methyl pyrrolidone to make 10 wt.% solution in an ultrasonic bath, the slurry was cast over a glass substrate heated to $70^{\circ}C$ for solvent evaporation. And then we used solid electrolyte of SPEEK. The unit cell consist of DAAQ-CNF/electrolyte/Pt. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry.

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압축공기 저장용 파일롯 터널에 설치된 콘크리트 플러그의 안정성 해석 (Stability Analysis of Concrete Plugs Installed in Pilot Tunnels for the Storage of Compressed Air)

  • 이연규;송원경;박철환;최병희
    • 터널과지하공간
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    • 제20권6호
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    • pp.446-454
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    • 2010
  • 압축공기를 활용한 가스터빈 발전방식(CAES-G/T)은 태양열이나 풍력과 같은 신재생 에너지의 출력 변동성을 조절하는 유력한 수단 중 하나로 고려되고 있다. 국내에서 CAES 발전이 실용화된다면 지질여건상 암반터널식이 채택될 가능성이 크다. 암반터널식 CAES 시설에서는 압축공기 저장공간을 밀폐시키기 위한 콘크리트 플러그의 설치가 필요하므로 플러그의 형상과 크기를 결정하는 것이 중요한 설계변수가 된다. 파괴에 대한 안전율 분포와 접촉부 접촉압력 분포 분석을 통해 2가지 형태의 콘크리트 플러그에 대한 안정성 평가를 수행하였다. 주어진 지질조건에서는 테이퍼형 플러그가 쐐기형 플러그에 비해 구조적으로 안정한 것으로 나타났다. 쐐기형 플러그의 경우 측면 접촉부에서 분리현상이 예측되었고 이러한 분리면에서 압축공기의 누출 가능성과 마찰저항의 감소가 발생할 수 있음을 보여주었다.

소듐 분위기에서 물누출에 의한 5Cr-1Mo Ferrite강 구멍의 막힘과 재개방 현상 (Plugging and Re-opening Phenomena of the 5Cr-1Mo Steel Leak Hole by Water Leakage in Sodium Atmosphere)

  • 정경채;김태준;최종현;박진호;황성태
    • 공업화학
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    • 제9권5호
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    • pp.674-679
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    • 1998
  • 액체금속로 증기발생기 전열관 재질로 사용이 예상되는 ferrite steel 시편을 사용해서 소듐분위기에서 미량의 물 누출 실험을 수행하였다. 누출경로는 소듐-물 반응생성물 및 부식생성물에 의한 self-plugging 현상과 열적인 transient 및 전열관의 vibration에 의한 re-opening 메카니즘으로 설명이 가능하였다. 실험결과, 600 Psig의 injection 압력으로 5 g $H_2O$를 소듐분위기 속의 시편으로 누출시킨 경우, 누출초기와 약 70분 경과 후에 약간의 누출 흔적이 보였으나, self-plugging되었던 누출경로는 129분이 경과되자 완전 re-opening된 것으로 확인되었다. 누출시편의 re-opening shape은 2중으로 되어 있었으며, 소듐부위에서 시편 표면에 나타난 re-opening size 약 2 mm의 직경을 나타내었다.

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Predictions of non-uniform tip clearance effects on the flow field in an axial compressor

  • Kang, Young-Seok;Kang, Shin-Hyoung
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.743-750
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    • 2008
  • Asymmetric tip clearance in an axial compressor induces pressure and velocity redistributions along the circumferential direction in an axial compressor. This paper presents the mechanism of the flow redistribution due to the asymmetric tip clearance with a simple numerical modeling. The flow field of a rotor of an axial compressor is predicted when an asymmetric tip clearance occurs along the circumferential direction. The modeling results are supported by CFD results not only to validate the present modeling but also to investigate more detailed flow fields. Asymmetric tip clearance makes local flow area and resultant axial velocity vary along the circumferential direction. This flow redistribution 'seed' results in a different flow patterns according to the flow coefficient. Flow field redistribution patterns are largely dependent on the local tip clearance performance at low flow coefficients. However, the contribution of the main flow region becomes dominant while the tip clearance effect becomes weak as the flow coefficient increases. The flow field redistribution pattern becomes noticeably strong if a blockage effect is involved when the flow coefficient increases. The relative flow angle at the small clearance region decreases which result in a negative incidence angle at the high flow coefficient. It causes a recirculation region at the blade pressure surface which results in the flow blockage. It promotes the strength of the flow field redistribution at the rotor outlet. These flow pattern changes have an effect on the blade loading perturbations. The integration of blade loading perturbation from control volume analysis of the circumferential momentum leads to well-known Alford's force. Alford's force is always negative when the flow blockage effects are excluded. However when the flow blockage effect is incorporated into the modeling, main flow effects on the flow redistribution is also reflected on the Alford's force at the high flow coefficient. Alford's force steeply increases as the flow coefficient increases, because of the tip leakage suppression and strong flow redistribution. The predicted results are well agreed to CFD results by Kang and Kang(2006).

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Investigation of morphological changes of HPS membrane caused by cecropin B through scanning electron microscopy and atomic force microscopy

  • Hu, Han;Jiang, Changsheng;Zhang, Binzhou;Guo, Nan;Li, Zhonghua;Guo, Xiaozhen;Wang, Yang;Liu, Binlei;He, Qigai
    • Journal of Veterinary Science
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    • 제22권5호
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    • pp.59.1-59.13
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    • 2021
  • Background: Antimicrobial peptides (AMPs) have been identified as promising compounds for consideration as novel antimicrobial agents. Objectives: This study analyzed the efficacy of cecropin B against Haemophilus parasuis isolates through scanning electron microscopy (SEM) and atomic force microscopy (AFM) experiments. Results: Cecropin B exhibited broad inhibition activity against 15 standard Haemophilus parasuis (HPS) strains and 5 of the clinical isolates had minimum inhibition concentrations (MICs) ranging from 2 to 16 ㎍/mL. Microelectrophoresis and hexadecane adsorption assays indicated that the more hydrophobic and the higher the isoelectric point (IEP) of the strain, the more sensitive it was to cecropin B. Through SEM, multiple blisters of various shapes and dents on the cell surface were observed. Protrusions and leakage were detected by AFM. Conclusions: Based on the results, cecropin B could inhibit HPS via a pore-forming mechanism by interacting with the cytoplasmic membrane of bacteria. Moreover, as cecropin B concentration increased, the bacteria membrane was more seriously damaged. Thus, cecropin B could be developed as an effective anti-HPS agent for use in clinical applications.

Konjac Glucomannan Derived Carbon Aerogels for Multifunctional Applications

  • Lian, Jie;Li, Jiwei;Wang, Liang;Cheng, Ru;Tian, Xiuquan;Li, Xue;Zhou, Jian;Duan, Tao;Zhu, Wenkun
    • Nano
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    • 제13권10호
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    • pp.1850113.1-1850113.11
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    • 2018
  • Environmental and energy issues have always been a hot topic of global research. Oil leakage has caused great damage to the environment, affecting a wide area and it is difficult to clean up. In most cases, carbon-based adsorbents are typically utilized to remove oil spills because of their economic benefits and high adsorbent efficiency. At the same time, its excellent material properties can also be used for the preparation of supercapacitors. In this paper, the carbon aerogels were prepared by the one-step method. The prepared materials endowed a 3D network structure with a huge number of micropores and mesoporous, and the material is light-weight, stable, hydrophobic and has affinity for oil (17.02 g/g) to the KGM carbon aerogel. Through the physicchemical characterization, the KGM carbon aerogel shows specific surface area is $689m^2/g$, high water contact angle ($136.64^{\circ}$) and excellent reusability (more than 15 cycle times). In addition, we also discussed the electrochemical properties of the material and obtained the specific electrical capacity of 139 F/g under the condition of 1 A/g.

고체 슈퍼캐퍼시터를 위한 폴리비닐알콜 고분자 전해질막 (Poly(vinyl alcohol)-based Polymer Electrolyte Membrane for Solid-state Supercapacitor)

  • 이재훈;박철훈;박민수;김종학
    • 멤브레인
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    • 제29권1호
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    • pp.30-36
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    • 2019
  • 본 연구에서는 titanium nitride (TiN) 나노 섬유와 poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS) 전도성 고분자로 이루어진 전극과 poly(vinyl alcohol) (PVA) 기반 고분자 전해질 분리막을 이용하여 슈퍼 캐퍼시터를 제조하였다. TiN 나노 섬유의 경우 높은 전기 전도도와 이차원적 구조로 인한 스케폴드 효과를 기대할 수 있다는 점에서 전극 물질로 사용되었다. PEDOT-PSS 전도성 고분자는 수소 이온과 산화-환원 반응을 통해 보다 높은 정전용량을 나타낼 수 있으며 용액상에 분산이 용이해 유무기 복합제를 형성하기에 적합하였다. PVA 기반의 고분자 전해질 분리막은 기존의 액상의 전해질의 문제인 외부 충격에 대한 안정성을 확보할 수 있으며 염으로 사용된 $H_3PO_4$의 경우 수소 이온은 빠른 확산으로 인해 캐퍼시터의 충방전 효율에 이점이 있다. 본 연구에서 보고된 PEDOT-PSS/TiN 슈퍼캐퍼시터의 정전용량은 약 75 F/g으로 기존의 탄소기반 캐퍼시터에 비해 큰 폭으로 증가한 값이다.

An approach to minimize reactivity penalty of Gd2O3 burnable absorber at the early stage of fuel burnup in Pressurized Water Reactor

  • Nabila, Umme Mahbuba;Sahadath, Md. Hossain;Hossain, Md. Towhid;Reza, Farshid
    • Nuclear Engineering and Technology
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    • 제54권9호
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    • pp.3516-3525
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    • 2022
  • The high capture cross-section (𝜎c) of Gadolinium (Gd-155 and Gd-157) causes reactivity penalty and swing at the initial stage of fuel burnup in Pressurized Water Reactor (PWR). The present study is concerned with the feasibility of the combination of mixed burnable poison with both low and high 𝜎c as an approach to minimize these effects. Two considered reference designs are fuel assemblies with 24 IBA rods of Gd2O3 and Er2O3 respectively. Models comprise nuclear fuel with a homogeneous mixture of Er2O3, AmO2, SmO2, and HfO2 with Gd2O3 as well as the coating of PaO2 and ZrB2 on the Gd2O3 pellet's outer surface. The infinite multiplication factor was determined and reactivity was calculated considering 3% neutron leakage rate. All models except Er2O3 and SmO2 showed expected results namely higher values of these parameters than the reference design of Gd2O3 at the early burnup period. The highest value was found for the model of PaO2 and Gd2O3 followed by ZrB2 and HfO2. The cycle burnup, discharge burnup, and cycle length for three batch refueling were calculated using Linear Reactivity Model (LRM). The pin power distribution, energy-dependent neutron flux and Fuel Temperature Coefficient (FTC) were also studied. An optimization of model 1 was carried out to investigate effects of different isotopic compositions of Gd2O3 and absorber coating thickness.